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Fenton试剂与染料溶液的反应
引用本文:徐向荣,王文华,李华斌.Fenton试剂与染料溶液的反应[J].环境科学,1999,20(3):72-74.
作者姓名:徐向荣  王文华  李华斌
作者单位:中国科学院生态环境研究中心环境水化学国家重点实验室
摘    要:Fenton试剂与酸性、活性、直接、阳离子、分散和还原6类18种染料反应进,前4类染料在180min内完全脱色,TOC浓度均显著下降。后2类染料的脱色率很低,TOC浓度降低不多,研究了不同金属离子与此外光的催化下,T2O2对染料罗丹明B溶液的氧化反应。催化的结果为:Fe^2/UV〉Cu^2+/UV〉Fe^2+〉Cu^2+〉Mu^2+/UV〉Ag^+/UV〉Mn^2+〉Ag^+,通过与还原蓝RSN溶

关 键 词:Fenton试剂  UV体系  染料废水  废水处理
收稿时间:1998/10/27 0:00:00

The Reaction of Fentons Reagent and Dye Solution
Xu Xiangrong,Wang Wenhua and Li Huabing.The Reaction of Fentons Reagent and Dye Solution[J].Chinese Journal of Environmental Science,1999,20(3):72-74.
Authors:Xu Xiangrong  Wang Wenhua and Li Huabing
Institution:State Key Laboratory of Environmental Aquatic Chemistry, Research Center forEcoEnvironmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;State Key Laboratory of Environmental Aquatic Chemistry, Research Center forEcoEnvironmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;State Key Laboratory of Environmental Aquatic Chemistry, Research Center forEcoEnvironmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
Abstract:kinds of dye solution, including 6 species of cationic, direct, reactive, acidic, reductive and disperse dye were reacted with Fentons reagent. The four formers were decolorized and the concentrations of TOC of them were decreased during 180 min.On the contrary the colority and the TOC of the two latters were reduced lightly. The catalytic function of different metal ions and UV light on the decomposite of Rodamine B was in the sequence of Fe2+/UV>Cu2+/UV>Fe2+>Cu2+>Mn2+/UV>Ag+/UV>Mn2+>Ag+.Vat Blue RSN dye solution was degradated by Fentons reagent, Fenton/UV and H2O2/UV. The oxidation by Fenton/UV was the strongest and even stronger than the arithmetic sum of the other two, which means the synergistic effect of UV and Fe2+ on the function of H2O2.
Keywords:Fentons reagent  Fenton/UV system  H2O2/UV system  dye wastewater  
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