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世博会期间上海市大气挥发性有机物排放强度及污染来源研究
引用本文:王红丽,陈长虹,黄海英,王倩,陈宜然,黄成,李莉,张钢锋,陈明华,楼晟荣,乔利平.世博会期间上海市大气挥发性有机物排放强度及污染来源研究[J].环境科学,2012,33(12):4151-4158.
作者姓名:王红丽  陈长虹  黄海英  王倩  陈宜然  黄成  李莉  张钢锋  陈明华  楼晟荣  乔利平
作者单位:1. 上海市环境科学研究院,上海,200233
2. 上海市环境科学研究院,上海200233 华东理工大学资源与环境工程学院,上海200237
基金项目:环境模拟与污染控制国家重点联合实验室专项经费资助项目(11K05ESPCP); 环境保护公益性行业科研专项项目(201009001); 上海市科委资助项目(10231203802, 11231200500)
摘    要:基于VOCs在线观测数据,对世博会期间(2010年5月1日~10月31日)上海大气VOCs的排放进行了估算;采用后向轨迹模型和聚类分析法,研究了不同大气污染输送通道下上海市空气质量和观测站点VOCs的变化;基于受体模型对上海市城区大气VOCs进行了污染来源解析.结果表明,世博会期间,上海市每小时排放的VOCs导致大气中VOCs浓度的增加量为(5.98±3.18)×10-9,该值比2009年同期低1×10-9左右.世博会期间,上海大气主要受偏东方向气流的影响,所占比例超过40%;其次是偏西风(25%);偏南和偏北风共占约20%.受同一大气输送通道影响,观测点VOCs浓度与上海API值呈正相关,R2=0.599.受西北方向大气输送通道影响,本市空气质量最差,API值在70左右;其次是西南方向大气输送通道,API值在60以上;当本市大气受东面海洋上空输送气团的影响时,API〈50,空气质量为优.世博会期间,与机动车有关的排放最大,包括尾气和油气挥发,对上海大气VOCs的贡献约40%;其次是生产工艺和燃煤等工业排放,占30%~40%;溶剂涂料使用导致的排放约20%;夏季天然源排放的贡献在6%左右,也不容忽视.

关 键 词:挥发性有机物  排放强度  后向轨迹  聚类分析  来源解析
收稿时间:2012/2/17 0:00:00
修稿时间:5/8/2012 12:00:00 AM

Emission Strength and Source Apportionment of Volatile Organic Compounds in Shanghai During 2010 EXPO
WANG Hong-li,CHEN Chang-hong,HUANG Hai-ying,WANG Qian,CHEN Yi-ran,HUANG Cheng,LI Li,ZHANG Gang-feng,CHEN Ming-hu,LOU Sheng-rong and QIAO Li-ping.Emission Strength and Source Apportionment of Volatile Organic Compounds in Shanghai During 2010 EXPO[J].Chinese Journal of Environmental Science,2012,33(12):4151-4158.
Authors:WANG Hong-li  CHEN Chang-hong  HUANG Hai-ying  WANG Qian  CHEN Yi-ran  HUANG Cheng  LI Li  ZHANG Gang-feng  CHEN Ming-hu  LOU Sheng-rong and QIAO Li-ping
Institution:Shanghai Academy of Environmental Sciences, Shanghai 200233, China;Shanghai Academy of Environmental Sciences, Shanghai 200233, China;Shanghai Academy of Environmental Sciences, Shanghai 200233, China;Shanghai Academy of Environmental Sciences, Shanghai 200233, China;School of Resources and Environmental Engineering, East China University of Science and Technology, Shanghai 200237, China;Shanghai Academy of Environmental Sciences, Shanghai 200233, China;Shanghai Academy of Environmental Sciences, Shanghai 200233, China;Shanghai Academy of Environmental Sciences, Shanghai 200233, China;Shanghai Academy of Environmental Sciences, Shanghai 200233, China;Shanghai Academy of Environmental Sciences, Shanghai 200233, China;Shanghai Academy of Environmental Sciences, Shanghai 200233, China;Shanghai Academy of Environmental Sciences, Shanghai 200233, China
Abstract:The emission strength of VOCs was estimated in the study, based on the volatile organic compounds (VOCs) measurement results. Air mass backward trajectories were computed and cluster analysis was done combining with the corresponding air pollution indexes and VOCs concentrations. Source apportionment of VOCs was studied using receptor model. According to this study, VOCs emission in Shanghai per hour resulted in the VOCs concentration increment of (5.98±3.18)×10-9 during 2010 EXPO (from 1st May to 31st October in 2010), which was decreased by about 1×10-9 compared to that in the same period of 2009. Under the control of the air masses roughly from the east (40%), the API was lower than 50.Influenced by the air masses from the northwest, the air quality was the worst with the average API higher than 70.The air masses from the southwest also resulted in bad air quality, with API higher than 60.The air masses originated from the west accounted for 25%, followed by the south and north air mass (20%). The VOCs concentrations were positively related to API in the same air mass, R2=0.599. During the 2010 EXPO, the emission related to vehicles including exhaust and gasoline evaporation contributed the largest amount of VOCs, approximately about ~40%, followed by industry including industrial processes and coal combustion (30%-40%), and solvent use and painting (20%). The biogenic emission was also considerable and accounted for 6% of VOCs in summer.
Keywords:volatile organic compounds  emission strength  back trajectories  cluster analysis  source apportionment
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