| 上海滴水湖周边土壤和沉积物对磷的吸附特征 |
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| 引用本文： | 诸葛祥真,毕春娟,陈振楼,张焕焕,倪玮怡.上海滴水湖周边土壤和沉积物对磷的吸附特征[J].环境科学,2014,35(4):1531-1539. |
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| 作者姓名： | 诸葛祥真 毕春娟 陈振楼 张焕焕 倪玮怡 |
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| 作者单位： | 华东师范大学资源与环境科学学院,地理信息科学教育部重点实验室,上海 200241;华东师范大学资源与环境科学学院,地理信息科学教育部重点实验室,上海 200241;华东师范大学资源与环境科学学院,地理信息科学教育部重点实验室,上海 200241;华东师范大学资源与环境科学学院,地理信息科学教育部重点实验室,上海 200241;华东师范大学资源与环境科学学院,地理信息科学教育部重点实验室,上海 200241 |
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| 基金项目： | 上海市自然科学基金项目（12ZR1409000）；国家自然科学基金项目（41271472）；上海市科委社会发展重点项目（12231201900）；公益性行业（农业）科研专项（200903056） |
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| 摘 要： | 采集滴水湖沉积物及其引水河与排水河沉积物、湿地沉积物以及周边农田土壤进行磷的等温吸附实验,探讨不同来源物质对磷吸附特性的差异.结果表明,滴水湖沉积物的吸附/解吸平衡质量浓度(EPC0值)为0.11~0.63 mg·L-1,高于其他来源土壤和沉积物,更容易向上覆水体释放磷.Langmuir模型和Freundlich模型对磷的等温吸附都有较高的拟合程度.由Langmuir模型计算的最大吸附量(Qm)表明,不同来源土壤和沉积物对磷的吸附能力由高到低为河流沉积物(1 003.05~2 977.65 mg·kg-1)>滴水湖沉积物(669.77~1 717.94 mg·kg-1)>湿地沉积物(368.60~1 145.51 mg·kg-1)>农田土壤(441.36~702.30 mg·kg-1).这表明农田土壤对磷的吸附能力最弱,当过量使用化肥时,农田会成为滴水湖磷的源.
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| 关 键 词： | 滴水湖 土壤 沉积物 磷 吸附特征 |
| 收稿时间： | 2013/8/12 0:00:00 |
| 修稿时间： | 2013/9/18 0:00:00 |
Phosphorus Adsorption Characteristics of Soils and Sediments Surrounding Dishui Lake in Shanghai |
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| ZHUGE Xiang-zhen,BI Chun-juan,CHEN Zhen-lou,ZHANG Huan-huan and NI Wei-yi.Phosphorus Adsorption Characteristics of Soils and Sediments Surrounding Dishui Lake in Shanghai[J].Chinese Journal of Environmental Science,2014,35(4):1531-1539. |
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| Authors: | ZHUGE Xiang-zhen BI Chun-juan CHEN Zhen-lou ZHANG Huan-huan and NI Wei-yi |
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| Institution: | Key Laboratory of Geographic Information Science of the Ministry of Education, School of Resources and Environment Science, East China Normal University, Shanghai 200241, China;Key Laboratory of Geographic Information Science of the Ministry of Education, School of Resources and Environment Science, East China Normal University, Shanghai 200241, China;Key Laboratory of Geographic Information Science of the Ministry of Education, School of Resources and Environment Science, East China Normal University, Shanghai 200241, China;Key Laboratory of Geographic Information Science of the Ministry of Education, School of Resources and Environment Science, East China Normal University, Shanghai 200241, China;Key Laboratory of Geographic Information Science of the Ministry of Education, School of Resources and Environment Science, East China Normal University, Shanghai 200241, China |
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| Abstract: | Soils and sediments of different origins were collected, which included the cropland soils surrounding Dishui Lake, the sediments from rivers, the sediments of wetland and the sediments in Dishui Lake. These samples were used for the experiment of phosphorus isothermal adsorption. The results of this experiment were analyzed and fitted. It shows that, the adsorption-desorption equilibrium mass concentration(EPC0 value) of the sediments in Dishui Lake (0.11-0.63mg·L-1) is higher than that of the soils and sediments from other sources, which indicates that it is easier to release phosphorus to overlying water. Both the Langmuir model and Freundlich model have a high fitting degree to the isothermal adsorption of phosphorus. The maximum adsorption capacity (Qm) calculated by Langmuir model demonstrate that the adsorption capacity of soils and sediments from different sources follows the order: sediments from rivers (1003.05-2977.65 mg·kg-1)>sediments in Dishui Lake (669.77-1717.94 mg·kg-1)>sediments of wetland (368.60-1145.51 mg·kg-1)>cropland soils(441.36-702.30 mg·kg-1).It shows that the adsorption capacity of cropland soils is the weakest. Cropland soils can be a source of phosphorus in Dishui Lake when extra fertilizer is used. |
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| Keywords: | Dishui Lake soil sediment phosphorus adsorption characteristics |
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