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等离子体烟气脱硫技术现状与关键问题讨论
引用本文:刘书海.等离子体烟气脱硫技术现状与关键问题讨论[J].环境科学,1996,17(2):86-89.
作者姓名:刘书海
作者单位:大连理工大学化学系
基金项目:国家自然科学基金,国家“八五”科技攻关资助
摘    要:介绍了SO2的3条去除路径,高能电子的解离还原路径;自由基的氧化路径;以及与氨的热化学反应路径。提出SO2浓度测试要先去氨及NOX测试先去SO2的方案。分析了温度、氨量、烟气组分及供电情况对SO2去除的影响。认为NO2及硫酸气溶胶的存在促进SO2去除的作用和脱硫与除法结合问题。最后提出利用氨与等离子体的协同作用,以热化学反庆为主路径,以等离子体活化反应为补充的脱硫思路。

关 键 词:烟气  脱硫  等离子体  燃煤电站
收稿时间:1995/7/28 0:00:00

Discussions on Key Problems or plasma-Catalysis Flue Gas Desulfurization
Liu Shuhai.Discussions on Key Problems or plasma-Catalysis Flue Gas Desulfurization[J].Chinese Journal of Environmental Science,1996,17(2):86-89.
Authors:Liu Shuhai
Institution:Institute of Electrostatics, Dalian University of technology, Dalian 116024
Abstract:hree approaches for so, removal were summarized: high energic electron bombardment induced direct dissociation,oxidation by free radicals generated in corona, and thermo-chemical reaction with ammonia. A new way put forward by the author is discussed here of removing ammonia for SO2 analysis. The performance of this method for flue gas is compared with that for simulated model gas. The differences resulted from gas comPOSition were stressed. Other factors such as temperature, dose of ammonia,puled energization conditions were also discussed which affect the Performance the most. Some incorrect conclutions in preciously published papers from different authors were examined. Some existing key problems which have to be solved for the commertial aPPlication also disscussed, including energy consumption, ammonia slip and production collection. Feasibility Of combination with ESP was also concerned too. It was concluded that the key problem of this method is how to oxidize ammonia sulfite effectively by utilization Of oxidizing environment generated by corona discharge with aims to solve simultaneously both problems of high energy consumption and ammonia slip.
Keywords:flue gas desulfurizaiton  plasma catalysis  free radicals  high energic electron bombarment  thermochemical  
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