醋酸纤维素吸附剂的制备及其性能表征

研究开发了1种球形醋酸纤维素吸附剂,对其制备方法、形态结构及其对水中4种有机氯农药的吸附性能进行了研究.扫描电镜结果表明,所制备醋酸纤维素吸附剂的外表面是一层致密的醋酸纤维素膜,内部为网状结构;对水中狄氏剂、艾氏剂、异狄氏剂、七氯4种有机氯农药有较强的吸附能力,12h后去除率均达到85%以上;并且对正辛醇-水分配系数(lgK_ow)较大的有机物具有更快的吸附速度,对七氯、艾氏剂的去除率在0·5h后可达99%.说明该吸附剂对水中亲脂性的有机物具有较高的吸附效能.

Preparation and Characterization of a Novel Adsorbent Made by Cellulose Acetate

A novel adsorbent made by cellulose acetate was developed. Preparation method, structure, and adsorbing characterization of the adsorbent were discussed. SEM results showed that the surface of round adsorbent was stable membrane of cellulose acetate, free from obvious cracks, holes, or other defects; while the cross section of the adsorbent was meshy and a lot of cavities were found. The adsorption results of 4 organochlorinated pesticides, such as Dieldrin, Aldrin, Endrin and Heptachlor, show that the adsorbent has higher efficient for organic pollutants, the adsorption rate is about 85% after 12 h. The adsorption rate is faster with the higher lgK_ow,and the removal efficiency of Heptachlor and Aldrin is up to 99% after 0.5h. The adsorbent can be used to remove persistent organic pollutants effectively.