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Degradation of nitrobenzene in wastewater by γ-ray irradiation
作者姓名:ZHANG Shu juan  FENG Shao hong  YU Han qing  LI Qian rong
作者单位:[1]DepartmentofChemistry,UniversityofScience&TechnologyofChina,Hefei230026,China [2]ResearchCenterforPhysics&Chemistry,UniversityofScience&TechnologyofChina.Hefei230026,China
基金项目:TheHundred TalentsProgrammeoftheChineseAcademyofSciences
摘    要:The degradation of nitrobenzene(NB) by γ-ray irradiation was studied. The influences of dose rate and initial NB concentration were investigated in details. At a dose rate of 55 Gy/min, the degradation kinetics was pseudo-first-order at NB concentrations from 0.2 mmol/L to 4.0 mmol/L. At an initial NB concentration of 0.8 mmol/L, the degradation of NB at various dose rates also followed pseudo-first-order kinetics. Dissolved oxygen was found to have a positive effect on NB degradation. The degradation products were identified as nitrophenol,nitrosobenzene, and hydroquinone, and so on. Based on the product analysis, possible degradation pathways of nitrobenzene were proposed.

关 键 词:硝基苯  废水处理技术  γ射线技术  环境污染  环境保护
收稿时间:2003/3/17 0:00:00
修稿时间:2003/5/30 0:00:00

Degradation of nitrobenzene in wastewater by gamma-ray irradiation
ZHANG Shu juan,FENG Shao hong,YU Han qing,LI Qian rong.Degradation of nitrobenzene in wastewater by gamma-ray irradiation[J].Journal of Environmental Sciences,2004,16(3):364-366.
Authors:Zhang Shu-juan  Feng Shao-hong  Yu Han-qing  Li Qian-rong
Institution:ZHANG Shu juan 1,FENG Shao hong 1,YU Han qing 1,*,LI Qian rong 2
Abstract:The degradation of nitrobenzene (NB) by gamma-ray irradiation was studied. The influences of dose rate and initial NB concentration were investigated in details. At a dose rate of 55 Gy/min, the degradation kinetics was pseudo-first-order at NB concentrations from 0.2 mmol/L to 4.0 mmol/L. At an initial NB concentration of 0.8 mmol/L, the degradation of NB at various dose rates also followed pseudo-first-order kinetics. Dissolved oxygen was found to have a positive effect on NB degradation. The degradation products were identified as nitrophenol, nitrosobenzene, and hydroquinone, and so on. Based on the product analysis, possible degradation pathways of nitrobenzene were proposed.
Keywords:degradation  irradiation  nitrobenzene(NB)  kinetics
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