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Degradation of acid fuchsine by a modified electro-Fenton system with magnetic stirring as oxygen supplying
Authors:Yiping Sheng  Limin Zhen  Xiuli Wang  Ning Li and Qi Tong
Institution:College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei 066004, China.
Abstract:The current modified electro-Fenton system was designed to develop a more convenient and e cient undivided system for practical wastewater treatment. The system adopted a cathode portion that employed magnetic stirring instead of common oxygen gas di usion or gas sparging to supply oxygen gas for the electrolyte solution. Key factors influencing the cathode fabrication and activity were investigated. The degradation of acid fuchsine with a self-made graphite-polytetrafluorethylene cathode was studied using a spectrophotometer. It was found that the cathode generated hydrogen peroxide with high current e ciency and the hydrogen peroxide yield of the cathode did not decay after 10 times reuse. With the Pt anode at a ferrous ion concentration of 0.5 mmol/L, a pH of 3, and using magnetic stirring, dye decolorization could be rapidly accomplished but the destruction of benzene rings and intermediates was fairly di cult. With a Fe anode, dye degradation was more complete.
Keywords:electro-Fenton system  oxygen gas  magnetic stirring  acid fuchsine  degradation
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