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Kinetics of photoelectrocatalytic degradation of humic acid using B2O3·TiO2/Ti photoelectrode
作者姓名:JIANG Yan-li  LIU Hui-ling  LU Chun-mei
基金项目:The Scientific Research Foundation of Harbin Institute of Technology( No. HIT. 2001.56)
摘    要:An innovative photoelectrode, B2O3·TiO2/Ti electrode, was prepared by galvanostaticanodisation. The morphology and crystalline texture of the B2O3·TiO2 film on electrode were examined by acomic force microscopy (AFM) and X-ray diffraction respectively. The examination results indicated that the anatase was the dominant component. The kinetics of photoelectrocatalytic(PEC) degradation of humic acid(HA) was investigated; the results demonstrated that effects from strongness to weakness on the photoelectrocatalytic degraded rate of humic acid: power of UV-lamp, area of TiO2 film, bias, original concentration of humic acid solution. The optimum conditions were power of UV-lamp 125 W, area of TiO2 film 42.0 cm2 , bias 1.4 V, original concentration of humic acid solution 5 mg/L in this PEC reaction system.

关 键 词:TiO2    photoelectrocatalytic  degradation    humic  acid    kinetics
收稿时间:2004/5/25 0:00:00
修稿时间:2004/7/30 0:00:00

Kinetics of photoelectrocatalytic degradation of humic acid using B2O3.TiO2/Ti photoelectrode
JIANG Yan-li,LIU Hui-ling,LU Chun-mei.Kinetics of photoelectrocatalytic degradation of humic acid using B2O3.TiO2/Ti photoelectrode[J].Journal of Environmental Sciences,2005,17(2):208-211.
Authors:JIANG Yan-li  LIU Hui-ling and LU Chun-mei
Institution:1. Department of Environmental Engineering, Harbin Institute of Technology, Harbin 150001, China;School of Life Science and Chemistry, Harbin College, Harbin 150001, China
2. Department of Environmental Engineering, Harbin Institute of Technology, Harbin 150001, China
Abstract:An innovative photoelectrode, B2O3.TiO2/Ti electrode, was prepared by galvanostaticanodisation. The morphology and crystalline texture of the B2O3.TiO2 film on electrode were examined by atomic force microscopy (AFM) and X-ray diffraction respectively. The examination results indicated that the anatase was the dominant component. The kinetics of photoelectrocatalytic (PEC) degradation of humic acid(HA) was investigated; the results demonstrated that effects from strongness to weakness on the photoelectrocatalytic degraded rate of humic acid: power of UV-lamp, area of TiO2 film, bias, original concentration of humic acid solution. The optimum conditions were power of UV-lamp 125 W, area of TiO2 film 42.0 cm2, bias 1.4 V, original concentration of humic acid solution 5 mg/L in this PEC reaction system.
Keywords:TiO2  photoelectrocatalytic degradation  humic acid  kinetics
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