| Seasonal,diurnal and nocturnal variations of carbonyl compounds in the semi-urban environment of Orléans,France |
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| 摘 要： | Atmospheric carbonyls were measured at a semi-urban site in Orléans, France, from October 2010to July2011. Formaldehyde, acetaldehyde and acetone were found to be the most abundant carbonyls, with average concentrations of 3.1, 1.0, 2.0 ppb, respectively in summer, 2.3, 0.7, 2.2 ppb, respectively in autumn, 2.2, 1.0, 2.1 ppb, respectively in spring,and 1.5, 0.7, 1.1 ppb, respectively in winter. Photo-oxidation of volatile organic compounds(VOCs) was found to make a remarkable contribution to atmospheric carbonyls in the semi-urban site based on the distinct seasonal and diurnal variations of the carbonyls, as well as the significantly positive correlations between the carbonyls and ozone. The significantly negative correlations between NO x and O_3 as well as the carbonyls and the positive correlations between wind speed and O_3 as well as the carbonyls implied that the carbonyls and O_3 at the semi-urban site were probably formed during air mass transport from neighboring cities.
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| 收稿时间： | 2015/4/27 0:00:00 |
| 修稿时间： | 2015/9/19 0:00:00 |
Seasonal, diurnal and nocturnal variations of carbonyl compounds in the semi-urban environment of Orléans, France |
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| Authors: | Zhaohui Jiang Benoît Grosselin Véronique Daële Abdelwahid Mellouki Yujing Mu |
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| Institution: | 1 Institut de Combustion, Aerothermique, Reactivité Environnement (ICARE), CNRS/OSUC 1C Avenue de la Recherche Scientifique, 45071 Orléans Cedex 02, France;2 College of Chemical and Biological Engineering, Changsha University of Science and Technology, Changsha 410004, China;3 Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China |
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| Abstract: | Atmospheric carbonyls were measured at a semi-urban site in Orléans, France, from October 2010 to July 2011. Formaldehyde, acetaldehyde and acetone were found to be the most abundant carbonyls, with average concentrations of 3.1, 1.0, 2.0 ppb, respectively in summer, 2.3, 0.7, 2.2 ppb, respectively in autumn, 2.2, 1.0, 2.1 ppb, respectively in spring, and 1.5, 0.7, 1.1 ppb, respectively in winter. Photo-oxidation of volatile organic compounds (VOCs) was found to make a remarkable contribution to atmospheric carbonyls in the semi-urban site based on the distinct seasonal and diurnal variations of the carbonyls, as well as the significantly positive correlations between the carbonyls and ozone. The significantly negative correlations between NOx and O3 as well as the carbonyls and the positive correlations between wind speed and O3 as well as the carbonyls implied that the carbonyls and O3 at the semi-urban site were probably formed during air mass transport from neighboring cities. |
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| Keywords: | Carbonyls Measurements Semi-urban |
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