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Removal of phenol by activated alumina bed in pulsed high-voltage electric field
作者姓名:ZHU Li-nan  MA Jun  YANG Shi-dong
作者单位:School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China
摘    要:A new process for removing the pollutants in aqueous solution-activated alumina bed in pulsed high-voltage electric field was investigated for the removal of phenol under different conditions. The experimental results indicated the increase in removal rate with increasing applied voltage, increasing pH value of the solution, aeration, and adding Fe^2+. The removal rate of phenol could reach 72.1% when air aeration flow rate was 1200 ml/min, and 88.2% when 0.05 mmol/L Fe^2+ was added into the solution under the conditions of applied voltage 25 kV, initial phenol concentration of 5 mg/L, and initial pH value 5.5. The addition of sodium carbonate reduced the phenol removal rate. In the pulsed high-voltage electric field, local discharge occurred at the surface of activated alumina, which promoted phenol degradation in the thin water film. At the same time, the space-time distribution of gas-liquid phases was more uniform and the contact areas of the activated species generated from the discharge and the pollutant molecules were much wider due to the effect of the activated alumina bed. The synthetical effects of the pulsed high-voltage electric field and the activated alumina particles accelerated phenol degradation.

关 键 词:活性氧化铝床  脉冲高压电场  苯酚  脱除  水处理
收稿时间:2006-05-22
修稿时间:2006-09-11

Removal of phenol by activated alumina bed in pulsed high-voltage electric field
ZHU Li-nan,MA Jun,YANG Shi-dong.Removal of phenol by activated alumina bed in pulsed high-voltage electric field[J].Journal of Environmental Sciences,2007,19(4):409-415.
Authors:ZHU Li-nan  MA Jun and YANG Shi-dong
Institution:School of Municipal and Environmental Engineering,Harbin Institute of Technology,Harbin 150090,China
Abstract:A new process for removing the pollutants in aqueous solution-activated alumina bed in pulsed high-voltage electric field was investigated for the removal of phenol under different conditions. The experimental results indicated the increase in removal rate with increasing applied voltage, increasing pH value of the solution, aeration, and adding Fe2 . The removal rate of phenol could reach 72.1 % when air aeration flow rate was 1200 ml/min, and 88.2 % when 0.05 mmol/L Fe2 was added into the solution under the conditions of applied voltage 25 kV, initial phenol concentration of 5 mg/L, and initial pH value 5.5. The addition of sodium carbonate reduced the phenol removal rate. In the pulsed high-voltage electric field, local discharge occurred at the surface of activated alumina, which promoted phenol degradation in the thin water film. At the same time, the space-time distribution of gas-liquid phases was more uniform and the contact areas of the activated species generated from the discharge and the pollutant molecules were much wider due to the effect of the activated alumina bed. The synthetical effects of the pulsed high-voltage electric field and the activated alumina particles accelerated phenol degradation.
Keywords:pulsed high-voltage electric field  hybrid gas-liquid electrical discharge  activated alumina  phenol  Fenton's reaction  water treatment  electric field  activated alumina  phenol degradation  effects  particles  distribution  contact  species  pollutant  time  thin  water film  local  discharge  surface  addition  sodium carbonate  initial  concentration  flow rate
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