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Evidence against hydroxyl radical mechanism in photo-Fenton degradation of p-chlorophenol
作者姓名:CHEN Lin  ZHOU Ming-hu  LEI Le-cheng
作者单位:[1]Institute of Environmental Engineering, Zhejiang University, Hangzhou 310027, China [2]Institute of Environmental Engineering and Science, Hangzhou Dianzi University, Hangzhou 310018, China
摘    要:This paper provides evidence for the degradation of organic pollutant by the photo-Fenton complex mechanism. Both the complex oxidation and HO. oxidation mechanisms were verified by p-chlorophenol degradation, UV/Vis spectra anaylsis, and quantum yield. The hydroxyl radical involved in the photo-Fenton process can also be generated from the decomposition of H2O2, photolysis of Fe^3+ and degradation of hydrated Fe(Ⅵ)-complex, excepting the traditional Fenton reaction.

关 键 词:氧化工艺  废水处理  工艺流程  有机污染物
文章编号:1001-0742(2006)02-0388-04
收稿时间:2005-03-14
修稿时间:2005-09-14

Evidence against hydroxyl radical mechanism in photo-Fenton degradation of p-chlorophenol
CHEN Lin,ZHOU Ming-hu,LEI Le-cheng.Evidence against hydroxyl radical mechanism in photo-Fenton degradation of p-chlorophenol[J].Journal of Environmental Sciences,2006,18(2):388-391.
Authors:CHEN Lin  ZHOU Ming-hua and LEI Le-cheng
Institution:1. Institute of Environmental Engineering, Zhejiang University, Hangzhou 310027, China;Institute of Environmental Engineering and Science, Hangzhou Dianzi University, Hangzhou 310018, China
2. Institute of Environmental Engineering, Zhejiang University, Hangzhou 310027, China
Abstract:This paper provides evidence for the degradation of organic pollutant by the photo-Fenton complex mechanism. Both the complex oxidation and HO· oxida tion mechanisms were verified by p-chlorophenol degradation, UV/Vis spectra anay lsis, and quantum
Keywords:photo-Fenton  p-chlorophenol  mechanism
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