Ultrasound-assisted emulsification solidified floating organic drop microextraction for the determination of trace amounts of copper in water samples |
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Authors: | Qingyun Chang Jingwen Zhang Xin Du Jingjun Ma and Jingci Li |
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Institution: | (1) Hebei Key Laboratory of Bioinorganic Chemistry, College of Sciences, Agricultural University of Hebei, Baoding, 071001, Hebei Province, People’s Republic of China; |
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Abstract: | A simple and efficient liquid-phase microextraction (LPME) technique was developed using ultrasound-assisted emulsification
solidified floating organic drop microextraction (USAE-SFODME) combined with flame atomic absorption spectrometry, for the
extraction and determination of trace copper in water samples. 1-(2-Pyridylazo)-2-naphthol (PAN) was used as chelating agent.
Microextraction efficiency factors (including extraction solvent type, extraction volume, time, temperature, and pH), the
amount of the chelating agent, and salt effect were investigated and optimized. Under the optimum extraction conditions, figures
of merit of the proposed method were evaluated. The calibration graph was linear in the range of 20–600 μg·L−1 with a detection limit of 0.76 μg·L−1. The relative standard deviation (R.S.D) for ten replicate measurements of 20 and 400 μg·L−1 of copper was 3.83% and 2.65%, respectively. Finally, the proposed method was applied to tap water, river water, and sea
water, and accuracy was assessed through the analysis of certified reference water or recovery experiments. |
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