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Ti/SnO2-Sb2O5/PbO2阳极电化学氧化降解苯甲酸研究
引用本文:蔡国君,沈钢,王波燕,黄成翔,范铮.Ti/SnO2-Sb2O5/PbO2阳极电化学氧化降解苯甲酸研究[J].环境科学与技术,2011,34(7):17-19.
作者姓名:蔡国君  沈钢  王波燕  黄成翔  范铮
作者单位:1. 台州市环境保护局,浙江台州,318020;浙江工业大学生物与环境工程学院,杭州,310032
2. 台州市环境保护局,浙江台州,318020
3. 舟山市固体废物管理中心,浙江舟山,316003
4. 浙江工业大学生物与环境工程学院,杭州,310032
基金项目:国家自然科学基金项目资助(20977086)
摘    要:文章研究了TI/SnO2-Sb2O5/Pbo2在两室电解池中氧化降解苯甲酸的性能,主要考察了电流密度、初始pH值、初始苯甲酸浓度和支持电解质这四个参数对TOC去除效率的影响。实验表明在电流密度为30 mA/cm2,初始苯甲酸浓度为0.5 mmol/L,支持电解质(Na2SO4)为0.1mol/L的条件下,经过6 h反应...

关 键 词:Ti/SnO2-Sb2O5/PbO2  阳极氢化  苯甲酸  高级氧化技术  电化学

Electrochemical Degradation of Benzoic Acid by Anodic Oxidation on Ti/SnO_2-Sb_2O_5/PbO_2 Electrodes
CAI Guo-jun,SHEN Gang,WANG Bo-yan,HUANG Cheng-xiang,FAN Zheng.Electrochemical Degradation of Benzoic Acid by Anodic Oxidation on Ti/SnO_2-Sb_2O_5/PbO_2 Electrodes[J].Environmental Science and Technology,2011,34(7):17-19.
Authors:CAI Guo-jun  SHEN Gang  WANG Bo-yan  HUANG Cheng-xiang  FAN Zheng
Institution:CAI Guo-jun1,3,SHEN Gang1,WANG Bo-yan2,HUANG Cheng-xiang3,FAN Zheng3(1.Taizhou Municipal Environmental Protection Bureau,Taizhou 318020,China,2.Zhoushan Municipal Solid Waste Management Centre,Zhoushan 316003,3.School of Biological and Environmental Engineering,Zhejiang University of Technology,Hangzhou 310032,China)
Abstract:Electrochemical performance of Ti/SnO2-Sb2O5/PbO2 electrodes in the oxidation of simulated wastewater containing benzoic acid using a two-compartment electrochemical system was investigated.Influence of operating variables on TOC removal efficiency was studied as a function of current density,initial pH,initial benzoic acid concentration and supporting electrolyte concentration.Under the conditions of a density current of 30 mA/cm2,initial benzoic acid concentration of 0.5 mmol/L,supporting electrolyte conc...
Keywords:Ti/SnO2-Sb2O5/PbO2  anodic oxidation  benzoic acid  advanced oxidation process  electrochemistry  
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