| 氯化十四烷基二甲基苄基铵盐水体系浮选铜 |
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| 引用本文： | 吴艳平,靳惠霞,赵春霞,李全民.氯化十四烷基二甲基苄基铵盐水体系浮选铜[J].环境科学与技术,2002,25(2):20-21,24. |
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| 作者姓名： | 吴艳平 靳惠霞 赵春霞 李全民 |
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| 作者单位： | 1. 河南省高等学校环境科学与工程重点开放实验室,新乡,453002
2. 河南师范大学化学与环境科学学院,新乡,453002 |
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| 摘 要： | 研究发现 ,在水溶液中Cu(Ⅱ )与硫氰酸铵、氯化十四烷基二甲基苄基铵形成不溶于水的三元缔合物 ,在少量氯化钠存在下此三元缔合物沉淀浮于水相上层并与水分成界面清晰的两相 ,分相过程中Cu(Ⅱ )被定量浮选。实现了Cu(Ⅱ )与Fe(Ⅲ )、Ni(Ⅱ )、Mn(Ⅱ )、Al(Ⅲ )等离子的分离 ,是一种无毒且更为简便、经济、快速的分离方法。
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| 关 键 词： | 硫氰酸铵 氯化十四烷基二甲基苄基铵 浮选分离 铜 |
| 文章编号： | 1003-6504(2002)02-0020-02 |
Floatation Process for Separation of Copper in a Sodium Chloride - Ammonium Thiocyanate-Tetradecyl-benzyl-dimethylammonium Chloride System |
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| WU Yan ping\,JIN Hui xia\,ZHAO Chun xia\,LI Quan min\\.Floatation Process for Separation of Copper in a Sodium Chloride - Ammonium Thiocyanate-Tetradecyl-benzyl-dimethylammonium Chloride System[J].Environmental Science and Technology,2002,25(2):20-21,24. |
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| Authors: | WU Yan ping\ JIN Hui xia\ ZHAO Chun xia\ LI Quan min\\ |
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| Institution: | WU Yan ping\+1,JIN Hui xia\+1,ZHAO Chun xia\+1,LI Quan min\+2\, |
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| Abstract: | In the aqueous solution, Cu(Ⅱ) precipitates with ammonium thiocyanate and tetradecyl benzyl dimethylammonium chloride. I n the presence of sodium chloride, the precipitates are floated out. It has been showed that Cu(Ⅱ) can be isolated from other metal ions such as Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Mn(Ⅱ) and Al(Ⅲ) by floatation. Compared with the traditional floatation that uses organic extracts, this process has the advantages of being simple, non toxic and economic. |
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| Keywords: | ammonium thiocyanate tetradecyl benzyl dimethylammonium chloride floatation separation copper |
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