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石墨炉原子吸收分光光度法测定生活垃圾堆肥中镉
引用本文:曹杰山.石墨炉原子吸收分光光度法测定生活垃圾堆肥中镉[J].环境科学与技术,2008,31(6).
作者姓名:曹杰山
作者单位:中国环境监测总站,北京,100029
基金项目:国家环保总局国家标准编制计划
摘    要:通过试验研究,建立了硝酸-氢氟酸-高氯酸消解、石墨炉原子吸收分光光度法测定生活垃圾堆肥产品中的镉。该方法的检出限为0.01mg/kg(按称取0.5g试样消解定容至50mL计算),用于不同地域堆肥样品中镉的测定,其相对标准偏差(RSD)在5.78%~11.9%之间,加标回收率介于88.0%~106.0%之间,可作为一种较理想的检验堆肥产品质量的方法。

关 键 词:石墨炉原子吸收分光光度法    生活垃圾  堆肥产品

Determination of Cadmium in Composting Products of Domestic Waste by GF-AAS
CAO Jie-shan.Determination of Cadmium in Composting Products of Domestic Waste by GF-AAS[J].Environmental Science and Technology,2008,31(6).
Authors:CAO Jie-shan
Abstract:On the basis of experiment,a determination method of cadmium in composting products of household waste was developed by graphite furnace atomic absorption spectrophotometry(GF-AAS) and sample digestion with HNO3-HF-HClO4.The method was applied to the determination of cadmium in composting products of various regions,with relative standard deviation between 5.78%~11.9% and recovery rate of 88.0%~106.0%.The determination limit was 0.01mg.kg as calculated by weighing 0.5g sample,digesting and diluting with water to 50mL volume.The method is reliable to examine the quality of composting products.
Keywords:graphite furnace atomic absorption spectrophotometry(GF-AAS)  cadmium  domestic waste  composting product
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