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多频率组合平行正交超声场降解氯苯的研究
引用本文:邹华生,林岗,肖磊.多频率组合平行正交超声场降解氯苯的研究[J].环境科学与技术,2008,31(2):16-19.
作者姓名:邹华生  林岗  肖磊
作者单位:华南理工大学化工与能源学院,广东广州,510640
基金项目:广东省科技攻关计划 , 广东省广州市科技攻关项目
摘    要:文章研究了不同频率以及频率组合下正交和平行超声场降解氯苯溶液的效果,并对氯苯超声降解的动力学进行了分析。实验结果证明:其他条件相同的情况下,采用多频率组合超声场能有效的提高氯苯的降解效果;正交超声场降解效果优于平行超声场;多频超声场中氯苯降解过程符合虚拟一级反应特征,同时给出了3种频率及其频率组合条件下氯苯的超声降解动力学特征方程。

关 键 词:正交和平行超声场  降解  氯苯  一级反应
文章编号:1003-6504(2008)02-0016-04
收稿时间:2007-06-01
修稿时间:2007-12-30

Sonolysis of Chlorobenzene in Parallel or Orthorhombic Ultrasonic Fields of Multifrequency Combination
ZOU Hua-sheng,LIN Gang,XIAO Lei.Sonolysis of Chlorobenzene in Parallel or Orthorhombic Ultrasonic Fields of Multifrequency Combination[J].Environmental Science and Technology,2008,31(2):16-19.
Authors:ZOU Hua-sheng  LIN Gang  XIAO Lei
Abstract:Sonolysis of chlorobenzene in orthogonal or parallel ultrasonic field of different single frequency or combined frequencies were studied, and the kinetic rate of sonolysis of chlorobenzene was discussed. Results showed that the degradation efficiency of chlorobenzene at given time was improved by combined frequencies effectively, with the effect better in orthogonal ultrasonic field than in parallel ultrasonic field and the rate of degradation following a pseudo-first-order kinetic law. Furthermore, the kinetic equations for sonolysis of chlorobenzene at different single frequency and combined frequencies were also described.
Keywords:orthogonal or parallel ultrasonic field  sonolysis  chlorobenzene  a pseudo-first-order kinetics
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