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Hg2+离子的光催化还原的研究
引用本文:吴光辉,周韦,钟劲茅,杨莉.Hg2+离子的光催化还原的研究[J].环境科学与技术,2005,28(2):15-16.
作者姓名:吴光辉  周韦  钟劲茅  杨莉
作者单位:南昌航空工业学院环境与化学工程系,南昌,330034;南昌航空工业学院环境与化学工程系,南昌,330034;南昌航空工业学院环境与化学工程系,南昌,330034;南昌航空工业学院环境与化学工程系,南昌,330034
摘    要:研究了反应时间、pH值、d 半乳糖对锐钛型TiO2 光催化还原Hg2+离子(HgCl2 水溶液)影响,结果表明: 反应20min时,还原率达到最高,随后略下降;还原率随着pH值的降低而降低;d 半乳糖能有效促进 Hg2+离子的光催化还原,还原率一直上升, 不会出现最高点;加入量超过一定值(16mmol/L)后,促进效果几乎相同,反应90min时,还原率达100%。

关 键 词:锐钛型TiO2  光催化还原  Hg+2离子
文章编号:1003-6504(2005)02-0015-02
修稿时间:2003年10月10

Study on Photocatalytic Reduction of Hg2+ Cation
WU Guang-hui,ZHOU Wei,ZHONG Jin-mao,YANG Li.Study on Photocatalytic Reduction of Hg2+ Cation[J].Environmental Science and Technology,2005,28(2):15-16.
Authors:WU Guang-hui  ZHOU Wei  ZHONG Jin-mao  YANG Li
Abstract:The photocatalytic reduction of Hg~(2+) cation (aqueous solution of mercury chloride) using anatase TiO_2 was studied as a function of irradiation time, pH of the solution, d-galactose. Results showed that photoreduction efficiency of Hg~(2+) cation reached the highest value in 20min illumination, and then decreased a little; the photoreduction decreased with the decrease of pH value. Adding d-galactose enhanced photoreduction of Hg~(2+\} cation and made photoreduction efficiency increased continuously, after adding amount of d-galactose exceeded 16mmol/L, different adding amount had similar effective results, they all led to a complete photoreduction in about 90min illumination.
Keywords:anatase TiO_2  photocatalytic reduction  Hg~(2+) cation
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