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几种水合金属氧化物的磷酸根吸附性能
引用本文:郭会超,李文军,王环颖,张经华,刘洋,周悦.几种水合金属氧化物的磷酸根吸附性能[J].环境科学与技术,2011,34(3):15-18.
作者姓名:郭会超  李文军  王环颖  张经华  刘洋  周悦
作者单位:1. 北京科技大学冶金与生态工程学院,北京,100083
2. 北京科技大学应用科学学院,北京,100083
3. 北京市理化分析测试中心,北京,100089
基金项目:国家自然科学基金资助项目
摘    要:利用简单的碱沉淀法制备不同的水合金属氧化物,并对所得七种水合金属氧化物的磷酸根吸附等温线进行了系统的探讨比较.研究表明,25℃条件下,Al、Fe、Ni、Cu和Ce的水合金属氧化物对磷酸根的吸附最符合Langmuir线性吸附方程,而水合氧化锌和水合氧化钴吸附剂最符合线性等温线模型.所有这七种水合金属氧化物对磷酸根的吸附都...

关 键 词:水合金属氧化物  吸附等温线  比表面积  红外光谱

Phosphate Adsorption Ability of Several Hydrous Metal Oxides
GUO Hui-chao,LI Wen-jun,WANG Huan-ying,ZHANG Jing-hua,LIU Yang,ZHOU Yue.Phosphate Adsorption Ability of Several Hydrous Metal Oxides[J].Environmental Science and Technology,2011,34(3):15-18.
Authors:GUO Hui-chao  LI Wen-jun  WANG Huan-ying  ZHANG Jing-hua  LIU Yang  ZHOU Yue
Institution:GUO Hui-chao1,LI Wen-jun2,WANG Huan-ying1,ZHANG Jing-hua3,LIU Yang3,ZHOU Yue3(1.School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing 100083,China,2.School of Applied Science,3.Beijing Centre for Physical and Chemical Analysis,Beijing 100089,China)
Abstract:Adsorption isotherm of 7 hydrous metal oxides which were prepared by simple alkali precipitation method was discussed systematically and results showed that hydrous metal oxides of Al,Fe,Ni,Cu and Ce fit best with Langmuir linear adsorption equation,and hydrous zinc oxides and hydrous cobalt oxides with linear isotherm in the tested concentration range at 25 ℃.Adsorption data of all 7 hydrous metal oxides can be fit well with Freundlich isotherm.Phosphate adsorption capacity is not proportional to specific surface area among these oxide adsorbents.IR band changes before and after adsorption happen mainly in the range of 800~1 250 cm-1.The experiments prove that the hydrous metal oxides have potential to use as adsorbents for water treatment.
Keywords:hydrous metal oxides  adsorption isotherm  specific surface area  IR spectroscopy  
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