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β-环糊精强化二氧化钛光催化降解双酚F研究
引用本文:王光辉,李海丰,于荣,邓南圣.β-环糊精强化二氧化钛光催化降解双酚F研究[J].环境科学与技术,2007,30(9):95-97.
作者姓名:王光辉  李海丰  于荣  邓南圣
作者单位:1. 东华理工学院土木与环境工程系,抚州,344000
2. 武汉大学资源与环境学院,武汉,430079
摘    要:研究了双酚F在β-环糊精存在的TiO_2光催化体系中的光降解行为,结果表明:双酚F能与β-环糊精形成1:1稳定的包结物,其包结常数为6.33×10~3L/mol,β-环糊精可以使双酚F的光催化降解效率可以提高21%,同时研究了双酚F光降解的动力学规律及pH、β-环糊精浓度、双酚F初始浓度对双酚F的光催化降解的影响。β-环糊精对双酚F光催化降解的强化作用源于β-环糊精促进双酚F在TiO_2表面的吸附。

关 键 词:双酚F  β-环糊精  光催化降解  强化
文章编号:1003-6504(2007)09-0095-03
修稿时间:2006-12-07

Enhancement of β-cyclodextrin on Photocatalytic Degradation of Bisphenol F
WANG Guang-hui,LI Hai-feng,YU Rong,DENG Nan-sheng.Enhancement of β-cyclodextrin on Photocatalytic Degradation of Bisphenol F[J].Environmental Science and Technology,2007,30(9):95-97.
Authors:WANG Guang-hui  LI Hai-feng  YU Rong  DENG Nan-sheng
Abstract:TiO_2 photocatalytic degradation of bisphenol F(BPF)in the presence ofβ-cyclodextrin(β-CD)was investigated.Results showed that BPF can form 1:1 inclusion complex withβ-CD,with formation constant of 6.33×10~3L/mol.β-CD can increase photodegradation efficiency by about 21%.The effect of pH value,initial concentration of BPF and concentration ofβ-CD as well as kinetics analysis was studied, and the enhancement of photodegradation of BFP mainly resulted from the enhancement of adsorption of BPF on TiO_2 surface.
Keywords:bisphenol F(BPF)  β-cyclodextrin(β-CD)  photocatalytic degradation  enhancement
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