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复合功能树脂吸附对苯二酚的热力学研究
引用本文:孙越,陈金龙,李爱民,张全兴.复合功能树脂吸附对苯二酚的热力学研究[J].环境科学与技术,2005,28(6):7-8,11.
作者姓名:孙越  陈金龙  李爱民  张全兴
作者单位:污染控制与资源化研究国家重点实验室南京大学环境工程系,南京,210093
基金项目:国家自然科学基金资助项目(20274017);江苏省自然科学基金资助项目(BK2000016)
摘    要:研究了复合功能超高交联树脂对水溶液中对苯二酚的静态吸附热力学特征,结果表明:超高交联树脂上引入适量的胺基,可明显地提高树脂的吸附容量。该类树脂对对苯二酚的吸附为自发的放热过程,属于物理吸附过程。

关 键 词:复合功能树脂  对苯二酚  氢键  吸附热力学
文章编号:1003-6504(2005)06-0007-03
收稿时间:2004-08-16
修稿时间:2004-08-162004-10-28

Thermodynamic Study on Adsorption of Hydroquinone from Aqueous Solution on Bi-functional Polymeric Adsorbents
SUN Yue,CHEN Jin-long,LI Ai-min,ZHANG Quan-xing.Thermodynamic Study on Adsorption of Hydroquinone from Aqueous Solution on Bi-functional Polymeric Adsorbents[J].Environmental Science and Technology,2005,28(6):7-8,11.
Authors:SUN Yue  CHEN Jin-long  LI Ai-min  ZHANG Quan-xing
Abstract:Three hypercrosslinked polymeric adsorbents AH-1,AH-2 and AH-3,which were chemically modified by amination with dimethylamine,were employed to remove hydroquinone from aqueous solution through static experiments.A comparison of adsorption behaviors against the three functional resins,the hypercrosslinked polymeric adsorbent NDA-100 with no tertiary amino groups was made.It was found that the adsorption capacities of hydroquinone increased notablely on the hypercrosslinked resins after amination.The adsorptions of hydroqinone on the four hypercrosslinked resins were all spontaneous exothermic processes with physical characters.
Keywords:bi-functional polymeric adsorbent  hydroqinone  hydrogen-bonding interaction  adsorption thermodynamics  
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