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城市污泥中痕量Cd活性形态的分析
引用本文:田冬梅,李延升,宋学君,武士威,臧树良.城市污泥中痕量Cd活性形态的分析[J].环境科学与技术,2005,28(6):14-15,18.
作者姓名:田冬梅  李延升  宋学君  武士威  臧树良
作者单位:华东师范大学化学系,上海,200062;沈阳师范大学化学与生命科学学院,沈阳,110034;辽宁大学化学科学与工程学院,沈阳,110036;沈阳师范大学化学与生命科学学院,沈阳,110034
基金项目:辽宁省科委自然科学基金资助项目(972088)
摘    要:选择水、醋酸和不同有机溶剂对沈阳北部污水处理厂污泥进行浸提,采用方波阳极溶出伏安法和石墨炉原子吸收光谱法测定其中痕量Cd的几种活性形态。分析结果表明:酸溶态提取量较高,电化学活性态和离子交换态含量则较低,三者随时间和温度条件的变化呈一致的规律性。不同有机溶剂对Cd的提取能力与溶剂极性大小呈正相关性,有机态Cd提取量随浸提时间的增加而增高。

关 键 词:城市污泥  Cd  活性形态
文章编号:1003-6504(2005)06-0014-03
收稿时间:2005-05-23
修稿时间:2005-05-232005-08-08

Trace Cadmium Mobility Analysis as a Consequence of Sewage Sludge Disposal
TIAN Dong-mei,LI Yan-sheng,SONG Xue-jun,WU Shi-wei,ZANG Shu-liang.Trace Cadmium Mobility Analysis as a Consequence of Sewage Sludge Disposal[J].Environmental Science and Technology,2005,28(6):14-15,18.
Authors:TIAN Dong-mei  LI Yan-sheng  SONG Xue-jun  WU Shi-wei  ZANG Shu-liang
Institution:TIAN Dong-mei~
Abstract:Sludge from a wastewater treatment plant in north of Shenyang was extracted by various organic solvents,and methods of anode V-I determination and granite GC were adopted to analyze mobility of Cd.Results showed that the content of electrochemical activity and ion-exchange was lower while the extracting content of acid solvent was high,all of which varied with time and temperature.The extract capability of Cd by different solvents was in positive correlation with solvent polarity and Cd extraction increased with time.
Keywords:urban sludge  Cd  mobility
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