| 固氮酶单,双钼铁钼辅基的制备和特性 |
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| 引用本文： | 黄河清,林庆梅.固氮酶单,双钼铁钼辅基的制备和特性[J].应用与环境生物学报,1997,3(3):258-262. |
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| 作者姓名： | 黄河清 林庆梅 |
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| 基金项目： | 国家自然科学基金，国家教委回国留学人员基金 |
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| 摘 要： | 固氮酶单、双钼铁钼辅基的制备与N-甲基甲酰胺碱度有关．质子激发X射线发射光谱和电感耦合等离子体发射光谱分析技术测定单、双钼铁钼辅基的钼铁流元素组成比值均为1∶6∶6．在紫外可见光谱区内，单、双钼铁钼辅基均无特征吸收峰，不含高柠檬酸盐。
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| 关 键 词： | 固氮酶 铁钼辅基 单、双钼铁硫簇 光谱分析 |
PREPARATION AND CHARACTERIZATION OF FeMo COFACTORS CONTAINING SINGLE AND DOUBLE Mo FROM NITROGENASE |
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| Abstract: | Preparation of FeMo cofactors containing single and double Mo was related with basicity of N-methylformamide. The mininal elemental composition of FeMo cofactor containing single and double Mo was found to be Mo: 6Fe: 6S by using inductively coupled plasma and proton induced X-ray emission analytical technique. F6Mo cofsctors containing single and double Mo showed featureless absorbence peak in the ultraviolet and visible spectral range and did not contain homocitrate. |
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| Keywords: | Nitrogenase FeMo cofactor Fe-S clusters containing single and double Mo spectral analysis |
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