Characterization of submicron aerosols in the urban outflow of the central Pearl River Delta region of China |
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Authors: | Zhaoheng Gong Zijuan Lan Lian Xue Liwu Zeng Lingyan He Xiaofeng Huang |
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Institution: | 1. Key Laboratory for Urban Habitat Environmental Science and Technology, School of Environment and Energy, Peking University Shenzhen Graduate School, Shenzhen 518055, China; 2. Qingdao Environmental Monitoring Center, Qingdao 266003, China; 3. Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, School of Environmental Sciences and Engineering, Nanjing University of Information Sciences and Engineering, Nanjing 210044, China |
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Abstract: | Submicron aerosol particles (with aerodynamic diameters less than 1 μm, PM1) were sampled and measured in Heshan, an urban outflow site of Guangzhou megacity in Pearl River Delta in South China, using an Aerodyne High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) in November 2010 during 2010 Guangzhou Asian Games. The mean PM1 mass concentration measured was 47.9±17.0 μg·m-3 during the campaign, with organic aerosol (OA) and sulfate being the two dominant species, accounting for 36.3% and 20.9% of the total mass, respectively, followed by black carbon (17.1%, measured by an aethalometer), nitrate (12.9%), ammonium (9.6%) and chloride (3.1%). The average size distributions of the species (except black carbon) were dominated by an accumulation mode peaking at ~550 nm. Calculations based on high-resolution organic mass spectrum showed that, C, H, O and N on average contributed 58.1%, 7.3%, 30.7%, and 3.9% to the total organic mass, respectively. The average ratio of organic mass over organic carbon mass (OM/OC) was 1.73±0.08. Four components of OA were identified by the Positive Matrix Factorization (PMF) analysis, including a hydrocarbon-like (HOA), a biomass burning (BBOA) and two oxygenated (SV-OOA and LV-OOA) organic aerosol components, which on average accounted for 18.0%, 14.3%, 28.8% and 38.9% of the total organic mass, respectively. |
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Keywords: | organic aerosol high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) positive matrix factorization |
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