Statistical evaluation of the attainment of interim cleanup standards at hazardous waste sites

Cleanup standards at hazardous waste sites include (i) numeric standards (often risk-based), (ii) background standards in which the remediated site is compared with data from a supposedly clean region, and (iii) interim standards in which the remediated site is compared with preremediation data from the same site. The latter are especially appropriate for verifying progress when an innovative, but unproven, technology is used for remediation. Standards of type (i) require one-sample statistical tests, while those of type (ii) and type (iii) call for two-sample tests. This paper considers two-sample tests with an emphasis upon the type (iii) scenario. Both parametric (likelihood ratio) and nonparametric (linear rank) protocols are examined. The methods are illustrated with preremediation data from a site on the National Priorities List. The results indicate that nonparametric procedures can be quite competitive (in terms of power) with distributional modelling provided a near optimal rank test is selected. Suggestions are given for identifying such rank tests. The results also confirm the importance of sound baseline sampling; no amount of post-remediation sampling can overcome baseline deficiencies.This paper has been prepared with partial support from the United States Environmental Protection Agency under a Cooperative Agreement Number CR-815273. The contents have not been subject to Agency review and therefore do not necessarily reflect the views or policies of the Agency and no official endorsement should be inferred.