| 微乳液中2,4—二硝基氯苯水解反应的研究 |
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| 引用本文： | 柴金岭,肖利华.微乳液中2,4—二硝基氯苯水解反应的研究[J].环境化学,1999,18(4):349-353. |
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| 作者姓名： | 柴金岭 肖利华 |
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| 作者单位： | 山东师范大学化学系!济南250014 |
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| 摘 要： | 研究了２，４－硝基氯苯在十二烷基磺酸钠／油／醇／水组成的Ｏ／Ｗ型微乳液中的水解反应。考察了烃，醇与表面活性剂的种类及用量，ＯＨ＾－浓度和温度等对Ｏ／Ｗ型微乳液中２，４－二硝基氯苯水解反应的影响。
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| 关 键 词： | 二硝基氯苯 微乳液 水解反应 十二烷基磺酸钠 |
HYDROLYSIS STUDY OF 2,4-DINITROCHLOROBENZENE IN MICROEMULSIONS |
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| Chai Jinling Xiao Lihua.HYDROLYSIS STUDY OF 2,4-DINITROCHLOROBENZENE IN MICROEMULSIONS[J].Environmental Chemistry,1999,18(4):349-353. |
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| Authors: | Chai Jinling Xiao Lihua |
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| Abstract: | The hydrolysis of 2,4-dinitrochlorobenzene in microemulsions was studied. The results show that the hydrolysis mechanism is the same in microemulsions as in water solution. The hydrocarbon and cosurfactant orders of the hydrolysis rate constants of DNCB are: hexane > benzene > chloroform; t-butyl alcohol > n-propyl alcohol > n-butyl alcohol. The rate constants increase with the decrease of hexane content and with the increase of both the content of sodium dodecyle sulfonate and temperature, but decrease with both the increase and decrease of the alcohol content. The effects of various experimental factors on the hydrolysis of DNCB in microemulsions have been discussed. |
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| Keywords: | microemulsion 2 4-dinitrochlorobenzene sodium dodecyle sulfonate hydrolysis kinetics |
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