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对硝基苯酚在阴-阳离子有机膨润土/水间的界面行为研究
引用本文:朱利中,陈宝梁,葛渊数,过春燕.对硝基苯酚在阴-阳离子有机膨润土/水间的界面行为研究[J].环境化学,2000,19(5):419-425.
作者姓名:朱利中  陈宝梁  葛渊数  过春燕
作者单位:浙江大学环境科学系,杭州,310028
基金项目:中国科学院资助项目,浙江省自然科学基金,中国科学院资助项目,29777005,,,,,
摘    要:用阴、阳离子表面活性剂改性制得一系列阴-阳离子有机膨润土,表征了有机膨润土的结构特征,研究了对硝基苯酚在阴-阳离子有机膨润土/水间的界面行为,并探讨了其吸附机理.结果表明:阴-阳离子有机膨润土的层间距和有机碳含量与改性时阴、阳离子表面活性剂的组成和配比有关;阴-阳离子表面活性剂在有机膨润土中形成了增溶(分配)作用较强的有机相,在一定配比下对水中有机污染物产生协同效应.

关 键 词:阴-阳离子有机膨润土  有机污染物  吸附  水处理

SORPTION PROPERTIES OF p-NITROPHENOL TO ANION-CATION ORGANOBENTONITES FROM WATER
Zhu Lizhong,Chen Baoliang,Ge Yuanshu,Guo Chunyan.SORPTION PROPERTIES OF p-NITROPHENOL TO ANION-CATION ORGANOBENTONITES FROM WATER[J].Environmental Chemistry,2000,19(5):419-425.
Authors:Zhu Lizhong  Chen Baoliang  Ge Yuanshu  Guo Chunyan
Abstract:A series of anion-cation organobentonites are synthesized by covering anion-cation mixed surfactants on the bentonite. The interlayer spacings and organic carbon contents of anion-cation organobentonites are analyzed. The interfacial behavior of p-nitrophenol betwwen anion-cation organobentonite and water are investigated. The sorption mechanisms are also discussed. The results indicate that the organic carbon contents of anion-cation organobentonites are proportional to the amounts of anion and cation surfactants exchanging onto bentonite. Partition mediums are excellently created in anion-cation organobentonites for organic pollutants in water. Removal rate of organic pollutants from water is improved by synergistic solubilization of anion and cation surfactant on the organobentonites.
Keywords:anion-cation organobentonite  p-nitrophenol  sorption  wastewater treatment  
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