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双阳离子有机膨润土对菲的吸附性能及机理研究
引用本文:朱利中,马荻荻,陈宝梁.双阳离子有机膨润土对菲的吸附性能及机理研究[J].环境化学,2000,19(3):256-261.
作者姓名:朱利中  马荻荻  陈宝梁
作者单位:浙江大学环境科学系,杭州,310028
基金项目:中国科学院资助项目,29777005,
摘    要:用长碳链季铵盐溴化十六烷基三甲胺(CTMAB)与短碳链阳离子表面活性剂(TMAB)按不同配比改性膨润土。制得一系列双阳离子有机膨润土。研究了双阳离子有机膨润土吸附水中菲的适宜条件、性能及机理,结果表明,双阳离子有机膨润土的层间距、有机碳含晡对菲的吸附性能与改性时表面活性剂的加入量成正相关;菲等温吸附曲线呈线性,是菲在水-双阳离子有机膨润土之间分配作用的结果。

关 键 词:膨润土  表面活性剂    吸附  水处理  阳离子型

SORPTION PROPERTIES AND MECHANISMS OF PHENANTHRENE TO DUAL-CATION ORGANOBENTONITES
Zhu Lizhong,Ma Didi,Chen Baoliang.SORPTION PROPERTIES AND MECHANISMS OF PHENANTHRENE TO DUAL-CATION ORGANOBENTONITES[J].Environmental Chemistry,2000,19(3):256-261.
Authors:Zhu Lizhong  Ma Didi  Chen Baoliang
Abstract:A series of dual-cation organobentonites are synthesized by replacing the metal ions in bentonite with both cetyltrimethylammonium (CTMA) and tetramethylammonium cation (TMA). The optimal conditions, properties for dual-cation organobentonites to sorb phenanthrene from water are investigated. The interlayer spacing and organic carbons contents of organobentonites, and the sorp-tion of phenanthrene to organobentonites are relative to the amount and akly-length of organic cation exchanging into the bentonite. The sorption of phenanthrene to dual-cation organobentonites is also related to the properties of organic compound. The sorption isotherm of phenanthrene is linear, which is the result of phenanthrene partition into dual-cation organobentonites.
Keywords:bentonite  cation surfactants  phenanthrene  sorption  wastewater treatment  
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