| 噻吩在离子液体中的电化学聚合及其在模拟汽油脱硫中的应用 |
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| 引用本文： | 亓西敏,张爱健,张贵荣,薛腾,罗仪文,陆嘉星.噻吩在离子液体中的电化学聚合及其在模拟汽油脱硫中的应用[J].环境化学,2006,25(2):183-186. |
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| 作者姓名： | 亓西敏 张爱健 张贵荣 薛腾 罗仪文 陆嘉星 |
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| 作者单位： | 上海市绿色化学与化工过程绿色化重点实验室,华东师范大学化学系,上海,200062 |
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| 基金项目： | 上海市绿色化学与化工过程绿色化重点实验室基金 |
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| 摘 要： | 研究了噻吩在离子液体HMIM] BF4,BMIM] BF4和BMIM] PF6中的电化学聚合,实验证明,噻吩在三种离子液体中均能聚合.将噻吩在离子液体中的电化学聚合应用于模拟汽油脱硫.结果表明:在三种离子液体中都实现了电化学脱除模拟汽油样品中的含硫物质--噻吩.对于不同的离子液体而言,脱硫的最佳电流密度不同,但噻吩的脱除效果均能达到50%-90%.
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| 关 键 词： | 噻吩 离子液体 电化学 脱硫 |
THE POLYMERIZATION OF THIOPHENE IN IONIC LIQUID AND ITS APPLICATION IN DESULFURIZATION OF SIMULATIVE GAS OIL |
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| QI Xi-min,ZHANG Ai-jian,ZHANG Gui-rong,XUE Teng,LUO Yi-wen,LU Jia-xing.THE POLYMERIZATION OF THIOPHENE IN IONIC LIQUID AND ITS APPLICATION IN DESULFURIZATION OF SIMULATIVE GAS OIL[J].Environmental Chemistry,2006,25(2):183-186. |
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| Authors: | QI Xi-min ZHANG Ai-jian ZHANG Gui-rong XUE Teng LUO Yi-wen LU Jia-xing |
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| Institution: | Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Deparement of East China Normal University, Shanghai, 2130062, China |
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| Abstract: | Conductive polythiophene film was prepared by electrochemical method in ionic liquids (HMIM]BF4, BMIM] BF4 , BMIM] PF6) . This method was applied to the desulfurization experiment. The result showed us that the desulfurization of thiophene could be carried out successfully in three kinds of ionic liquids. Although each ionic liquids had its best desulfurization current density. All desulfurization results got to 50% -90%. |
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| Keywords: | thiophene ionic liquids electrochemistry desulfurization |
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