| 二氧化硫与环己烷的光化学反应 |
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| 引用本文： | 杜尧国,郭海忱.二氧化硫与环己烷的光化学反应[J].环境化学,1994,13(6):530-535. |
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| 作者姓名： | 杜尧国 郭海忱 |
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| 作者单位： | 吉林大学环境科学系!长春130023 |
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| 摘 要： | 本文研究了ＳＯ２与环己烷在无氧及有氧体系中的光化学反应，观察到了白色烟雾有生成并凝聚，利用ＧＣ和ＧＣ／ＭＳ法确定了部分反应产物－环烯烃、醇、酮、二元酸酯、呋喃衍生物以及硫酸二甲酯等有机化合物，探讨了影响光化学反应的几种因素及反应机理。
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| 关 键 词： | 二氧化硫 环己烷 光化学反应 |
THE PHOTOCHEMICAL REACTION OF SULFUR DIOXIDE AND CYCLOHEXANE |
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| Du Yaoguo Guo Haichen Zhang Lianshe Xu Zili.THE PHOTOCHEMICAL REACTION OF SULFUR DIOXIDE AND CYCLOHEXANE[J].Environmental Chemistry,1994,13(6):530-535. |
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| Authors: | Du Yaoguo Guo Haichen Zhang Lianshe Xu Zili |
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| Abstract: | In this paper , the photochemical reactions of sulfur dioxide and cyclohexane were studied in the presence and absence of oxygen , respectively. The formation of aersol and a series of products such as cyclenes, alcohol, ketones , esters, furan derivations and organic sulfur compounds were found by using GC and GC/MS. According to the characteres of such compounds and the theory of chemical kinetics , the mechanisms of these photochemical reactions were suggested. |
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| Keywords: | sulfur dioxide cyclohexane photochemical reaction |
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