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溴邻苯三酚红-交流示波极谱法测定天然水中铝形态
引用本文:干宁,毕树平,王先龙,魏宗波.溴邻苯三酚红-交流示波极谱法测定天然水中铝形态[J].环境化学,2003,22(3):271-274.
作者姓名:干宁  毕树平  王先龙  魏宗波
作者单位:污染控制与资源化国家重点实验室,南京大学化学系,南京,210093
基金项目:ThisprojectissupportedbyNSFC ( 2 0 0 75 0 1 1& 4983 1 0 0 5 )andtheResearchFundingfromtheStateEducationAdministra tionofChinaforYoungTeacher.
摘    要:1 IntroductionDeterminationofthealuminumspeciationisoneofthemostsignificanttasksofenvironmentalanalyticalresearchatpresent.Therefore ,developmentofthepowerfulanalyticalmethodstargetingatdirectdetermininginorganicmonomericAliandtotalmonomericAlawillbeveryimportant1 ].ThemostwidelyusedschemeforthefractionationofAlinnaturalwatersampleswasproposedbyDriscoll2 ]whichemployed 8 oxine MIBKextractioncoupledwithGF AAS .Howevertherearestillsomedrawbacksinpracticalanalysisusingthemethod :(1) 8 ox…

关 键 词:溴邻苯三酚红  交流示波极谱法  测定  天然水    形态分析

DETERMINATION OF FIVE ALUMINUM FRACTIONS IN NATURAL WATERS BY A.C.OSCILLOPOLAROGRAPHY USING BROMOPYROGALLOL RED
Abstract.DETERMINATION OF FIVE ALUMINUM FRACTIONS IN NATURAL WATERS BY A.C.OSCILLOPOLAROGRAPHY USING BROMOPYROGALLOL RED[J].Environmental Chemistry,2003,22(3):271-274.
Authors:Abstract
Abstract:A novel and simple method for electrochemical determination of five fractions of aluminum in natural waters by a.c oscillopolarography in the presence of bromopyrogallol red is presented in this paper.It is mainly based on the direct determination of inorganic monomeric Ali and total monomeric Ala under the conditions of acidic and alkaline buffer solutions respectively.The method has been employed to determine five Al fractions in 30 natural water samples.The results are in agreement with those obtained by Driscoll′s scheme.
Keywords:a  c  oscillopolarography  aluminum speciation  nature water  
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