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固固共混法制备聚合氯化铝混凝剂
引用本文:高宝玉,张子健,马建伟,曹先艳.固固共混法制备聚合氯化铝混凝剂[J].环境化学,2005,24(5):569-572.
作者姓名:高宝玉  张子健  马建伟  曹先艳
作者单位:山东大学环境科学与工程学院,济南,250100;山东大学环境科学与工程学院,济南,250100;山东大学环境科学与工程学院,济南,250100;山东大学环境科学与工程学院,济南,250100
基金项目:国家“十五”重大科技专项:“水污染控制技术与治理工程”(863).
摘    要:采用固固共混法,制备具有不同铝浓度和碱化度(B)的聚合氯化铝(PAC)混凝剂.实验结果表明,在高铝浓度下可制备出较高含量Alb的PAC,制备条件对PAC中Alb的含量影响很大.B值的升高可以提高PAC中Alb的含量,但铝浓度的提高和熟化时间的延长则会降低产品中Alb的含量.反应温度为80℃左右时可制备出高Alb含量的PAC.加药时间和熟化时间对制备的影响不大.

关 键 词:固固共混法  聚合氯化铝  Alb
收稿时间:2004-10-11
修稿时间:2004-10-11

SOLID-SOLID MIXED METHOD TO PREPARE POLYALUMINUM CHLORIDE
GAO Bao-yu,ZHANG Zi-jian,MA Jian-wei,CAO Xian-yan.SOLID-SOLID MIXED METHOD TO PREPARE POLYALUMINUM CHLORIDE[J].Environmental Chemistry,2005,24(5):569-572.
Authors:GAO Bao-yu  ZHANG Zi-jian  MA Jian-wei  CAO Xian-yan
Institution:School of Science and Engineering, Shandong University, Jinan, 250100
Abstract:A preparation method of polyaluminum chloride (PAC),which is called solid-solid mixed method, is introduced in this paper.PAC has different basicity (B) an d total aluminum concentration, was prepared by means of solid-solid mixed meth od. The experiment has proved that: The increasing B value can enhance the A l_b content, but the increasing concentration of PAC and the extending agin g time can reduce it. And this preparation reaction has a prime reaction tempera ture. The reaction time has less influence on the preparation. So different prep aration conditions have dramatic effect on the quality of the prepared product. The high concentration PAC with high content Al_b was prepared by this meth od. Comparing with traditional method, solid-solid mixed method has many advant ages, such as the simple process, the short preparation time and the high conten t Al_b.
Keywords:solid-solid mixed method  polyaluminum chloride  Alb  
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