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超临界水氧化法处理酚水溶液初步研究
引用本文:鞠美庭,冯成武,赵朝成.超临界水氧化法处理酚水溶液初步研究[J].油气田环境保护,1999,9(1).
作者姓名:鞠美庭  冯成武  赵朝成
作者单位:石油大学炼制系
基金项目:中国石油天然气集团公司资助项目 
摘    要:为探讨在超临界状态下苯酚水溶液的氧化分解情况,应用了间歇式高压釜进行了实验。实验结果表明:停留时间增加,转化率提高;在超临界条件下,反应的温度和压力对苯酚的氧化分解影响不大;在氧气充足的情况下,苯酚浓度的增加不会对苯酚的分解转化率产生大的影响。

关 键 词:超临界水  氧化反应  苯酚  临界点  转化率

Primary Research on Processing Phenol Watery Solution by Supercritical Water Oxidation Method
Ju Meiting,Feng Chengwu,Zhao Chaocheng.Primary Research on Processing Phenol Watery Solution by Supercritical Water Oxidation Method[J].Environmental Protection of Oil & Gas Fields,1999,9(1).
Authors:Ju Meiting  Feng Chengwu  Zhao Chaocheng
Abstract:Batch autoclave was applied in the experiment to probe into the oxidation condition of phenol watery solution under supercritical condition.The result demonstrated three points.First,the more time stayed,the more degree converted.Second,the temperature and pressure of reaction had limited effect onto the oxidation of phenol under supercritical conditioin.Thirdly,the increase of phenol concentration didn't produce significant influence on the degree of decomposition and conversion of phenol.
Keywords:supercritical water    oxidation reaction    phenol    critical point    transformation ratio  
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