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Production of soybean ethanol-based biodiesel using CaO heterogeneous catalysts promoted by Zn,K and Mg
Authors:Fabiano A N Fernandes  Ronier M Lopes  Marina P Mercado  Evne S Siqueira
Institution:Departamento de Engenharia Quimica, Universidade Federal do Ceara, Fortaleza, Ceara, Brazil
Abstract:This article focuses on the optimization of the production of fatty acid ethyl esters from soybean oil using CaO-based heterogeneous catalysts. Three different catalytic promoters were evaluated: Magnesium, zinc, and potassium. The reaction has evaluated the promoter content (promoter to calcium molar ratio), catalyst load, alcohol to oil molar ratio, and temperature. Response surface methodology (RSM) was used to evaluate the influence of each variable on the yield of biodiesel. The addition of K2O or MgO in the catalyst has enhanced the yield in fatty acid ethyl esters, while the use of ZnO as a promoter was not successful.
Keywords:Biodiesel  soybean oil  transesterification  ethyl esters  heterogeneous catalyst
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