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不同化学还原体系下铬污染土壤的处理效率
引用本文:杨放, 陈倩, 毛志强, 郭淼, 熊振, 秦佳, 王建刚, 王兴润. 不同化学还原体系下铬污染土壤的处理效率[J]. 环境工程学报, 2017, 11(6): 3832-3838. doi: 10.12030/j.cjee.201604024
作者姓名:杨放  陈倩  毛志强  郭淼  熊振  秦佳  王建刚  王兴润
作者单位:1. 四川省地质工程勘察院, 成都 610072; 2. 四川省地矿局成都水文队, 成都 610072; 3. 中国环境科学研究院, 北京 100012
基金项目:国家环保公益性行业科研专项(201309020) 四川省土壤环境调查与评估体系研究项目(ZY20150490SC)
摘    要:以某场地两种典型铬污染土壤(Soil A和Soil B)为研究对象,探讨了不同药剂对土壤Cr6+的还原效果以及洗脱效果。结果表明,Na2S较FeSO4对土壤中Cr6+有更好的还原效果,还原率和总还原效率均可大于99%;具体工艺参数为:Na2S添加倍数5倍且pH值5~7。FeSO4和Na2S对Cr6+均有很好的洗脱效果,可将两种土壤洗脱液中Cr6+还原完全(未检出);具体工艺参数:FeSO4添加倍数5倍且pH值5~7或者Na2S添加倍数5倍且pH值5。综合考虑还原和洗脱效果,最优的工艺参数为Na2S添加倍数5倍且pH值5。通过经济性分析,处理1 t污染土壤Soil A和Soil B的药品费用分别为3.55元和59.52元。

关 键 词:六价铬   土壤修复   污染场地   还原稳定
收稿时间:2016-06-22

Remediation efficiency of chromium contaminated soil under different redox systems
YANG Fang, CHEN Qian, MAO Zhiqiang, GUO Miao, XIONG Zhen, QIN Jia, WANG Jiangang, WANG Xingrun. Remediation efficiency of chromium contaminated soil under different redox systems[J]. Chinese Journal of Environmental Engineering, 2017, 11(6): 3832-3838. doi: 10.12030/j.cjee.201604024
Authors:YANG Fang  CHEN Qian  MAO Zhiqiang  GUO Miao  XIONG Zhen  QIN Jia  WANG Jiangang  WANG Xingrun
Affiliation:1. Sichuan Institute of Geological Engineering Investigation, Chengdu 610072, China; 2. Chengdu Hydrogeological and Engineering Geological Team, Chengdu 610072, China; 3. Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Abstract:Two different types of chromium slag-contaminated soil (soil A and soil B treatments) were selected as test samples for the investigation of Cr6+ removal and the elution efficiencies of typical stabilization agents.The main findings are as follows:The hexavalent chromium reduction efficiency of Na2S was better than that of FeSO4.The Cr6+ removal rate and total reduction efficiency of Na2S exceeded 99% in both soil treatments.Meanwhile, the proper quantity of additional Na2S was five times the theoretical quantity, and the pH was 5~7.The elution efficiency was good for both Na2S and FeSO4.The Cr6+ of the eluent was almost completely reduced by both soil treatments (not detected).The proper quantity of additional FeSO4 was five times the theoretical quantity, and the pH was 5~7.Moreover, the proper quantity of Na2S was also five times the theoretical quantity, with a pH of 5.In terms of removal and elution efficiencies, the optimal parameter was an Na2S quantity five times that of the theoretical quantity, with a pH of 5~7.From an economic analysis, the costs of treatment for one ton of contaminated soils A and B were determined to be RMB 3.55 and 59.52 Yuan, respectively.
Keywords:hexavalent chromium  soil remediation  contaminated sites  reductive stabilization
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