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大型钢铁厂及其周边土壤多环芳烃污染现状调查、评价与源解析

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田靖, 朱媛媛, 杨洪彪, 吴国平, 魏复盛. 大型钢铁厂及其周边土壤多环芳烃污染现状调查、评价与源解析[J]. 环境化学, 2013, 32(6): 1002-1008. doi: 10.7524/j.issn.0254-6108.2013.06.013
引用本文: 田靖, 朱媛媛, 杨洪彪, 吴国平, 魏复盛. 大型钢铁厂及其周边土壤多环芳烃污染现状调查、评价与源解析[J]. 环境化学, 2013, 32(6): 1002-1008. doi: 10.7524/j.issn.0254-6108.2013.06.013
shu
TIAN Jing, ZHU Yuanyuan, YANG Hongbiao, WU Guoping, WEI Fusheng. Investigation, assessment and source analysis of polycyclic aromatic hydrocarbons (PAHs) pollution in soil from a larg iron and steel plant and its surrounding areas, in China[J]. Environmental Chemistry, 2013, 32(6): 1002-1008. doi: 10.7524/j.issn.0254-6108.2013.06.013
Citation: TIAN Jing, ZHU Yuanyuan, YANG Hongbiao, WU Guoping, WEI Fusheng. Investigation, assessment and source analysis of polycyclic aromatic hydrocarbons (PAHs) pollution in soil from a larg iron and steel plant and its surrounding areas, in China[J]. Environmental Chemistry, 2013, 32(6): 1002-1008. doi: 10.7524/j.issn.0254-6108.2013.06.013
shu

大型钢铁厂及其周边土壤多环芳烃污染现状调查、评价与源解析

  • 1.

    鞍山市环境监测中心站, 鞍山, 114004;

  • 2.

    北京科技大学土木与环境工程学院, 北京, 100083;

  • 3.

    中国环境监测总站, 北京, 100012

  • 基金项目:

    环境保护部全国土壤现状调查及污染防治项目资助.

Investigation, assessment and source analysis of polycyclic aromatic hydrocarbons (PAHs) pollution in soil from a larg iron and steel plant and its surrounding areas, in China

  • 1.

    Anshan Environmental Monitoring Center, Anshan, 114004, China;

  • 2.

    School of Civil and Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083, China;

  • 3.

    China National Environmental Monitoring Center, Beijing, 100012, China

  • Fund Project:

摘要

  • 摘要: 采用气相色谱-质谱联机方法(GC-MS)分析了东北某钢铁厂及周边居住区、风景区共11个采样点表层土壤样品16种多环芳烃(PAHs),结果表明,钢铁工业区16种PAHs(∑PAHs)浓度范围为3.39×103-1.54×105 ng·g-1,平均浓度3.21×104 ng·g-1;居住区∑PAHs浓度范围为587-6.70×103 ng·g-1, 平均浓度3.82×103 ng·g-1;风景区千山∑PAHs浓度385 ng·g-1.∑PAHs和Bap浓度均呈工业区>居住区>风景区趋势.与国内外其他研究结果相比,该钢铁工业区及其周边居住区土壤PAHs污染相对较为严重,11个采样点中有9个采样点土壤∑PAHs为严重污染,4个采样点苯并(a)芘(Bap)浓度超过加拿大土壤质量基准.利用特征比值法(Diagnostic Rate)和主成分分析法(Principal component analysis, PCA)对钢铁工业区及其周边地区土壤进行了源解析,结果表明,钢铁工业区土壤中PAHs主要来源于焦炉、燃煤、柴油燃烧等污染源,周边地区土壤除受工业污染源排放影响外,机动车汽油、柴油污染排放也有重要影响.
    Abstract: Sixteen polycyclic aromatic hydrocarbons (PAHs) in 11 surface soil samples from an iron and steel plant in northeast of China and its surrounding areas, including residential and scenic areas, were analyzed by GC-MS(Gas Chromatography- Mass Spectrometry). The concentrations of ∑PAHs were 3.39×103-1.54×105 ng·g-1 with a mean of 3.21×104 ng·g-1 in the iron and steel industrial park, 587-6.70×103 ng·g-1 with a mean of 3.82×103 ng·g-1 in the surrounding residential area, and 385 ng·g-1 in the scenic. The concentrations of ∑PAHs and Bap in the industrial areas were the highest, followed by the residential area. Compared with other studies, the soils in the iron and steel industrial plant and its surrounding residential area were heavily polluted by PAHs. Nine of total 11 soil samples showed serious contamination by PAHs. Moreover, Bap concentrations in 4 samples exceeded the limit of Canada Soil Quality standard. Source analysis was performed using Diagnostic Rate and Principal Component Analysis (PCA) methods. The results showed that coal and diesel combustion contributed to PAHs pollution in the iron and steel industrial park. Moreover, vehicle gasoline and diesel emission was another important source of PAHs pollution in the surrounding area along with industrial emission.
  • [1] 廖书林,郎印海,王延松. 辽河口湿地土壤多环芳烃的分布与生态风险评价[J]. 环境化学,2011,30(2):423-429
    [2]
    [3] 王学军,任丽然,戴永宁,等.天津市不同土地利用类型土壤中多环芳烃的含量特征[J].地理研究, 2003, 22(3): 360-366
    [4] Jones K C, Stratford J A, Waterhouse K S, et al. Increases in the polynuclear aromatic hydrocarbon content of an agricultural soil over the last century[J].Environmental Science and Technology,1989,23:95-101
    [5] Khalili N R, Scheff P A, Holsen T M. PAH source fingerprints for coke ovens, diesel and gasoline engines, highway tunnels, and wood combustion emissions[J]. Atmospheric Environment, 1995, 29:533-542
    [6] Viglianti C, Hanna K, de Brauer C, et al.Removal of polycyclic aromatic hydrocarbons from aged-contaminated soil using cyclodextrins: Experimental study, Environmental. Pollution, 2006, 140: 427-435
    [7] 葛成军,安琼,董元华.钢铁工业区周边农业土壤中多环芳烃(PAHs)残留及评价[J]. 农村生态环境, 2005, 21(2): 66-69

    , 73

    [8] Tao S, Cui Y H, Xu F L, et al. Polycyclic aromatic hydrocarbons (PAHs) in agricultural soil and vegetables from Tianjin[J]. Science of the total Environment, 2004, 320:11-24
    [9] Zuo Q, Duan Y H, Yang Y, et al. Source apportionment of polycyclic aromatic hydrocarbons in surface soil in Tianjin, China[J]. Environmental Pollution, 2007, 147:303-310
    [10] Chen L G, Ran Y, Xing B S, et al. Contents and sources of polycyclic aromatic hydrocarbons and organochlorine pesticides in vegetable soils of Guangzhou, China[J]. Chemosphere, 2005, 60:879-890
    [11] Chen B l, Xuan X D, Zhu L Z et al. Distributions of polycyclic aromatic hydrocarbons in surface waters, sediments and soils of Hangzhou City, China[J]. Water Research, 2004, 38:3558-3568
    [12] 章海波,骆永明,黄铭洪,等. 香港土壤研究-土壤中多环芳烃的含量及其来源初探[J]. 土壤学报,2005, 42(6):936-941
    [13] 林纪旺,倪进治,杨红玉,等.泉州市表层土中多环芳烃的含量、来源及其生态风险评价[J].环境科学,2011, 32(7):2074-2080
    [14] 倪进治,陈卫锋, 杨红玉,等. 福州市不同功能区土壤中多环芳烃的含量及其源解析[J].中国环境科学,2012, 32(5):921-926
    [15] 冯嫣,吕永龙,焦文涛,等. 北京市某废弃焦化厂不同车间土壤中多环芳烃(PAHs)的分布特征及风险评价[J].生态毒理学报,2009, 4(3):399-407
    [16] 焦文涛,吕永龙,王铁宇,等.化工区土壤中多环芳烃的污染特征及其来源分析[J]. 环境科学,2009,30(4):1166-1172
    [17] Nam J J, Song B H, Eom K C,etal. Distribution of polycyclic aromatic hydrocarbons in agricultural soils in South Korea [J]. Chemosphere, 2003,50;1281-1289
    [18] Thomas D B, Franziska B, Andre D, et al. Polycyclic aromatic hydrocarbons, black carbon,and molecular markers in soils of Switzerland [J]. Chemosphere, 2004, 56:1061-1076
    [19] Ee Von Lau, Suyin Gan Hoon Kiat Ng. Distribution and source apportionment of polycyclic aromatic hydrocarbons (PAHs) in surface soils from five different locations in Klang Valley, Malaysia [J]. Bulletin of Environmental Contamination and Toxicology, 2012, 88(2):741-746
    [20] Wang G D, Howard W M, Van Quach, et al. Determination of polycyclic aromatic hydrocarbons and trace metals in New Orleans soils and sediments[J]. Soil & Sediment Contamination, 2004, 13(3):313-327
    [21] Maliszewska-Kordybach B, Smreczak B, Klimkowicz-Pawlas A, et al. Monitoring of the total content of polycyclic aromatic hydrocarbons (PAHs) inarable soils in Poland [J]. Chemosphere, 2008, 73:1284-1291
    [22] Jiang Y F, Wang X T, Wu M H, et al. Contamination, source identification, and risk assessment of polycyclic aromatic hydrocarbons in agricultural soil of Shanghai, China [J].Environment Monitoring and Assessment, 2011:139-150
    [23] Maliszewska-Kordybach B. Polycyclic aromatic hydrocarbons in agricultural soils in Poland:Preliminary proposals for criteria to evaluate the level of soil contamination [J]. Applied Geochemistry,1996,11(1 /2): 121-127
    [24] 晁雷. 污染土壤修复基准建立的方法体系、案例研究与评价[D].北京: 中国科学院研究生院博士学位论文,2007
    [25] Readman J W,Fillmann G,Tolosa I,et al. Petroleum and PAH contamination of the Black Sea [J]. Marine Pollution Bulletin,2002,44(1): 48-62
    [26] Tang N, Hattori T, Taga R,et al. Polycyclic aromatic hydrocarbons and nitro polycyclic aromatic hydrocarbons in urban air particulates and their relationship to emission sources in the Pane Japan Sea countries [J]. Atmospheric Environment,2005, 39: 5817-5826
    [27] Kong S F, Ding X, Bai Z P, et al. A seasonal study of polycyclic aromatic hydrocarbons in PM2.5 and PM2.5-10 in five typical cities of Liaoning Province, China [J]. Journal of Hazardous Materials, 2010,183: 70-80
    [28] 张天彬,万洪富,周健民等. 深圳表层土壤中多环芳烃的污染特征及来源[J]. 生态环境, 2008, 17(3): 1032-1036
    [29] Yunker M B, Macdonald R W, Vingarzan R, et al. PAHs in the Fraster River basin: A critical appraisal of PAH ratios as indicators of PAH source and composition[J]. Organic Geochemistry, 2002, 33:489-515
    [30] Simcik M F, Eisenreich S J, Lioy P J. Source apportionment and source/sink relationships of PAHs in the coastal atmosphere of Chicago and Lake Michigan [J]. Atmospheric Environment, 1999, 33(30): 5071-5079
    [31] Harrison R M, Smith D J T, Luhana L. Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, UK [J]. Environmental Science and Technology, 1996,30(3): 825-832
    [32] Mastral A M, Callen M, Murillo R. Assessment of PAH emissions as a function of coal combustion variables [J]. Fuel, 1996, 75(13): 1533-1536
    [33] Li C K, Kamens R M. The use of polycyclic aromatic hydrocarbons as source signatures in receptor modeling [J]. Atmospheric Environment, 1993,27A:523-532
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  • 收稿日期:  2012-09-03
田靖, 朱媛媛, 杨洪彪, 吴国平, 魏复盛. 大型钢铁厂及其周边土壤多环芳烃污染现状调查、评价与源解析[J]. 环境化学, 2013, 32(6): 1002-1008. doi: 10.7524/j.issn.0254-6108.2013.06.013
引用本文: 田靖, 朱媛媛, 杨洪彪, 吴国平, 魏复盛. 大型钢铁厂及其周边土壤多环芳烃污染现状调查、评价与源解析[J]. 环境化学, 2013, 32(6): 1002-1008. doi: 10.7524/j.issn.0254-6108.2013.06.013
shu
TIAN Jing, ZHU Yuanyuan, YANG Hongbiao, WU Guoping, WEI Fusheng. Investigation, assessment and source analysis of polycyclic aromatic hydrocarbons (PAHs) pollution in soil from a larg iron and steel plant and its surrounding areas, in China[J]. Environmental Chemistry, 2013, 32(6): 1002-1008. doi: 10.7524/j.issn.0254-6108.2013.06.013
Citation: TIAN Jing, ZHU Yuanyuan, YANG Hongbiao, WU Guoping, WEI Fusheng. Investigation, assessment and source analysis of polycyclic aromatic hydrocarbons (PAHs) pollution in soil from a larg iron and steel plant and its surrounding areas, in China[J]. Environmental Chemistry, 2013, 32(6): 1002-1008. doi: 10.7524/j.issn.0254-6108.2013.06.013
shu

大型钢铁厂及其周边土壤多环芳烃污染现状调查、评价与源解析

  • 1.  鞍山市环境监测中心站, 鞍山, 114004;
  • 2.  北京科技大学土木与环境工程学院, 北京, 100083;
  • 3.  中国环境监测总站, 北京, 100012
  • 收稿日期:  2012-09-03
基金项目:

环境保护部全国土壤现状调查及污染防治项目资助.

摘要: 采用气相色谱-质谱联机方法(GC-MS)分析了东北某钢铁厂及周边居住区、风景区共11个采样点表层土壤样品16种多环芳烃(PAHs),结果表明,钢铁工业区16种PAHs(∑PAHs)浓度范围为3.39×103-1.54×105 ng·g-1,平均浓度3.21×104 ng·g-1;居住区∑PAHs浓度范围为587-6.70×103 ng·g-1, 平均浓度3.82×103 ng·g-1;风景区千山∑PAHs浓度385 ng·g-1.∑PAHs和Bap浓度均呈工业区>居住区>风景区趋势.与国内外其他研究结果相比,该钢铁工业区及其周边居住区土壤PAHs污染相对较为严重,11个采样点中有9个采样点土壤∑PAHs为严重污染,4个采样点苯并(a)芘(Bap)浓度超过加拿大土壤质量基准.利用特征比值法(Diagnostic Rate)和主成分分析法(Principal component analysis, PCA)对钢铁工业区及其周边地区土壤进行了源解析,结果表明,钢铁工业区土壤中PAHs主要来源于焦炉、燃煤、柴油燃烧等污染源,周边地区土壤除受工业污染源排放影响外,机动车汽油、柴油污染排放也有重要影响.

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