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改性壳聚糖复合凹凸棒土絮凝油漆废水
引用本文:周健, 董锐, 董悦, 付澎. 改性壳聚糖复合凹凸棒土絮凝油漆废水[J]. 环境工程学报, 2014, 8(11): 4674-4680.
作者姓名:周健  董锐  董悦  付澎
作者单位:1.南京工业大学理学院, 南京 210009; 2.盐城工学院化学与生物工程学院, 盐城 224051; 3.南京理工大学环境与生物工程学院, 南京 210009
基金项目:江苏省科技厅产学研联合创新基金资助项目(BY2013057-01);江苏省环保厅环保科研课题资助项目(2013024)
摘    要:
将壳聚糖、阳离子淀粉和二甲基二烯丙基氯化铵(DMDAAC)进行三元接枝共聚,制备了三元接枝改性壳聚糖(CTS-DMDAAC-CS),通过红外光谱和扫描电镜对其结构进行了表征.并且将三元接枝改性壳聚糖与凹凸棒土进行优化复配,对油漆废水进行了絮凝实验,得出了当pH=12,沉降时间为20 min,复合絮凝剂投加量为0.2 g,三元接枝共聚物:凹凸棒土=1:10时,该复合絮凝剂对油漆去除率最佳能够达到89.3%,并且絮凝效果好,是一种新型绿色环保的有机-无机复合絮凝剂.

关 键 词:壳聚糖   改性壳聚糖   凹凸棒土   絮凝   油漆废水
收稿时间:2013-12-22

Flocculation of paint wastewater by composite of modified chitosan and attapulgite
Zhou Jian, Dong Rui, Dong Yue, Fu Peng. Flocculation of paint wastewater by composite of modified chitosan and attapulgite[J]. Chinese Journal of Environmental Engineering, 2014, 8(11): 4674-4680.
Authors:Zhou Jian  Dong Rui  Dong Yue  Fu Peng
Affiliation:1.College of Sciences, Nanjing University of Technology, Nanjing 210009, China; 2.School of Chemical and Biological Engineering, Yancheng Institute of Technology, Yancheng 224051, China; 3.School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210009
Abstract:
The modified chitosan (CTS-DMDAAC-CS) was synthesized by chitosan, cationic starch and dimethyl diallyl ammonium chloride (DMDAAC). And it was characterized by scanning electro-microscope and infrared spectroscopy.The combination of modified chitosan and attapulgite for flocculation was investigated. The removal rate of the paint could achieve 89.3% with pH of 12, depositing time of 20 min, 1:10 CTS-DMDAAC-CS/attapulgite weight ratio, 0.2 g composited flocculant. The complex of modified chitosan and attapulgite was a novel and environment-friendly organic-inorganic flocculant.
Keywords:chitosan  modified chitosan  attapulgite  flocculation  paint wastewater
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