Global monitoring at the United States baseline stations with emphasis on precipitation chemistry measurements

The National Oceanic and Atmospheric Administration Geophysical Monitoring for Climatic Change program has operated four remote precipitation chemistry stations at two polar and two tropical Pacific locations for over a decade. Station geography and meteorology is discussed and a summary of the hydrogen, sulfate, and nitrate ion data collected since 1980 is presented. Results show that at all four locations, the ions which have major anthropogenic sources were far less concentrated than in samples collected in heavily industrialized areas in the northeastern United States and Europe. Concentrations at American Samoa and the South Pole showed little variability over the year whereas concentrations at Point Barrow, Alaska and Mauna Loa, Hawaii were highly variable.Contribution from Fourth World Wilderness Congress-Acid Rain Symposium, Denver (Estes Park), Colorado, September 11–18, 1987.     

Foliar concentrations of volunteer willows growing on polluted sediment-derived sites versus sites with baseline contamination levels

Many alluvial soils along navigable waterways are affected by disposal of dredged sediments or overbank sedimentation and contain metal concentrations that are elevated compared to baseline levels. Uptake patterns for metals and other elements by several volunteer Salix species growing on these sites were determined during a growing season in field plots and compared with the same species growing on soils with baseline contamination levels. For Cd and Zn, foliar concentrations were clearly higher on dredged sediment landfills. Uptake patterns differed significantly between species. A high uptake of Mn and low uptake of Cu, K and S in S. cinerea was attributed to wetland soil chemistry. Site effects on metal uptake were evaluated in more detail for Salix cinerea and S. alba growing on different sediment-derived sites under field conditions. Foliar Cd concentrations were higher in S. cinerea than in S. alba. This appeared to be a genetic feature not influenced by soil chemical properties, as it was observed both on clean sites and polluted sediment-derived sites. For S. cinerea, soil chemistry was reflected in foliar concentrations, while foliar Cd concentrations and bioavailability were found to be independent of the thickness of the polluted horizon. Dredged sediment landfills and freshwater tidal marshes with comparable Cd soil pollution had significantly different foliar Cd concentrations.     

Sample size for monitoring of toxic chemical sites

The problem of determining sample size for environmental monitoring and assessment is considered. Hypothesis testing is discussed in general terms and in terms of monitoring toxic chemical sites. Competing risks of misclassification of sites are examined within the framework of statistics. Alpha and beta, the probability of making Type I and Type II errors, respectively, are illustrated in the context of environmental monitoring.Sample size formulas and tables are provided for comparing a mean to a standard mean, comparing two means, comparing a proportion to a standard proportion, and comparing two proportions. The formulas and tables consider the size of differences to be detected as well as the probability of Type I and Type II errors.Although the research described in this article has been funded wholly or in part by the United States Environmental Protection Agency through Cooperative Agreement No. CR 810550 to the University of Nevada, Las Vegas, it has not been subjected to the Agency review and therefore does not necessarily reflect the views of the Agency and no official endorsement should be inferred.     

Ecology and the problems of World Ocean integrated global monitoring

Modern ecological state of the World Oceans is analysed, stressing the need for organization and development of a scientific basis for global ocean monitoring. The tasks and basic principles of integrated global ocean monitoring are described.Complex of natural processes determines the assimilative capacity of marine ecosystems, which can serve as a basis for the study of ecological reserves of the World Oceans and ecological rationing of the anthropogenic impact.     

A proposal for a long-term baseline phytobenthos monitoring programme for the Finnish Baltic coastal waters: monitoring submerged rocky shore vegetation

Several local surveys on the submerged vegetation have been conducted in past decades along the Finnish Baltic coastal areas. Surveys have been carried out by using various methods,which make the temporal comparisons of the results difficult.The need of a joint programme for coastal phytobenthic monitoringis emphasised by the Nordic Council of Ministers and HELCOM. TheFinnish coastal phytobenthic monitoring programme complements theBaltic HELCOM monitoring programme (COMBINE). It is primarily designed to reveal the effects of eutrophication. The programmeincludes general principles for selection of monitoring areas aswell as a proposal for monitored habitats, communities and species. The need of evaluated and tested field methods, datacollecting, interpretation and data storage are addressed in theQuality Assurance part. The cost-efficiency is secured by integrating the phytobenthos programme with the coastal water monitoring for obtaining the supporting data such like salinity,temperature and nutrients. In the design of the monitoring programme a special interest is paid on areas with high protection values such as Natura 2000 or HELCOM's BSPA (Baltic Sea Protected Areas) or on aspects that would support the implementation of the EU Water Framework Directive.     

B-P网络应用于地下水水质监测点优选

以地下水水质评价分级标准作为训练样本,构造B-P网络模型对其进行训练,用训练好的B-P网络对某地的地下水水质监测点进行评判、优选。并与其它方法的结果进行比较,结果表明,B-P网络用于环境测点优选不仅原理直观,而且具有较好的客观性和实用性。     

Problems of correlation of global and local monitoring of air pollution

1. The Air Polluttion Monitoring System has got a significant development of late, which is in direct relation with a considerable extention and improvement of the observation network in cities and industrial areas, with creation of a new network for assessing regional and global background of the atmosphere pollution, as well as with the wide involvement of meteorologists to monitoring organization.
2. While developing a new global monitoring system, it is necessary to take into account its relationship with the local monitoring within the region of air pollution sources, i.e. at the \lsimpact\rs level. The need in such an account is dictated first of all by the physics of pollutant spreading that states: changes in air pollution over large territories must be in a certain agreement with greater changes in the vicinity of emission sources. Methods applied in the global and local monitoring have also a number of common peculiarities. White organizing regional network for observations of the background pollution of the atmosphere twin stations (one of the pair of stations located outside the city boundaries in a small community, and the other, in the nearest city with the population of 200–400 thousand inhabitants) were established in the U.S.S.R. and in a number of socialist countries in Europe.
3. Implementation of the twin-station principles in the U.S.S.R. has contributed to data interpretation and representativity assessment as well as to correction of the station location. Observation results from the Soviet background stations and those abroad have been compared by now according to a number of indices.
4. The correlation of monitoring systems of various scales tells positively both on mutual improvement and completion of observational methods. The methods of obtaining integral characteristics of air pollution were used for the global monitoring, in particular spectral actinometric observations and chemical analysis of the precipitation composition. Now they find still wider employment. Thus methods of spectral actinometric measurements and data processing were used to estimate the degree of aerosol pollution of a number of industrial centres. The theory of solar radiation spreading and aerosol contents determination in urban atmosphere has also been developed. It is a generalization of an earlier developed theory, used to estimate global atmosphere pollution basing on actinometric data. The organization of precipitation collection and analysis on a network of stations around Leningrad and in Donbass area enables us to compare the admixture content in precipitations falling in industrial and agricultural areas.
5. A considerable increase of possibilities to measure microconcentrations of sulphur dioxide, nitrogen oxides and of a number of other pollutants is connected with the use of solid solvents for sampling. Their use will allow to avoid establishment of special laboratories at background stations and only send samples by post for their analysis in centralized laboratories.

They will also allow to considerably increase precision and accuracy of measurements. The international comparisons of methods of air pollution measurements on the background level allow to judge about the effiency of these methods.     

The global environment monitoring system (GEMS): Some recent developments

GEMS is an established, operational fact, a fact that has been with us for ten years. In 1975, following the instructions of the UN Conference on the Human Environment, UNEP moved into the field of environmental monitoring by establishing at its Nairobi Headquaters a Programme Activity Centre for GEMS. The role given to this Programme Activity Centre is to co-ordinate the disparate international monitoring activities that are conducted thoughout the world, particulary within the UN system, and to advise the Environment Fund of UNEP on how best to support and stimulate the initiation of new activities or the expansion of ongoing ones through the allocation of financial resources to these activities.The data gathered within the GEMS networks are used for assessment of the state of the environment and its trends, for better, more rational management of the environment and its natural resources. Ten years after it began the United Nations GEMS effort can be seen to be both fully operational and global in scope.     

Risk assessment near uncontrolled hazardous waste sites: Role of monitoring data

The traditional approach of coupling estimates of human exposures to individual chemicals with laboratory studies of the toxicity of the chemicals as the basis for quantitative assessments of risk is not adequate when considering problems near hazardous waste sites. For example, there are (a) too many chemicals and mixtures involved, (b) containment uncertainties, and (c) future exposure problems associated with groundwater and soil contamination. Among the items to be considered in expanding the dimensions of risk assessment methodologies of the past are (a) identification of chemical groups or of dominant toxic chemicals of principal concern and the likely man-made as well as natural pathways for environmental migration, (b) the role of biological monitoring in addition to traditional monitoring approaches, and (c) the coupling of monitoring data with past, current, and future population activity patterns and with epidemiological and other health data.Monitoring data is a key in risk assessments since there is little likelihood that materials balances or modelling will provide authoritative information concerning exposure levels. The use of monitoring data from control areas and from nationwide baseline surveys in developing comparative risk assessments is particularly important. Finally, recent experience provides us with a number of practical guidelines for designing and carrying out monitoring programs that will provide authoritative and useful data. *** DIRECT SUPPORT *** AZ802019 00002     

Molecular-level methods for monitoring soil organic matter responses to global climate change

Soil organic matter (SOM) is one of the most complex natural mixtures on earth. It plays a critical role in many ecosystem functions and is directly responsible for sustaining life on our planet. However, due to its chemical heterogeneity, SOM composition at molecular-level is still not completely clear. Consequently, the response of SOM to global climate change is difficult to predict. Here we highlight applications of two complementary molecular-level methods (biomarkers and nuclear magnetic resonance (NMR)) for ascertaining SOM responses to various environmental changes. Biomarker methods that measure highly specific molecules determine the source and decomposition stage of SOM components. However, biomarkers only make up a small fraction of SOM components because much of SOM is non-extractable. By comparison, (13)C solid-state NMR allows measurement of SOM in its entirety with little or no pretreatment but suffers from poor resolution (due to overlapping of SOM components) and insensitivity, and thus subtle changes in SOM composition may not always be detected. Alternatively, (1)H solution-state NMR methods offer an added benefit of improved resolution and sensitivity but can only analyze SOM components that are fully soluble (humic type molecules) in an NMR compatible solvent. We discuss how these complementary methods have been employed to monitor SOM responses to: soil warming in a temperate forest, elevated atmospheric CO(2) and nitrogen fertilization in a temperate forest, and permafrost thawing in the Canadian High Arctic. These molecular-level methods allow some novel and important observations of soil dynamics and ecosystem function in a changing climate.     

Monoc programme: Scientific substantiation of the integrated global ocean ecological monitoring system

Man's exploitation of the World Ocean continues to increase both productively, i.e., utilization of fisheries and natural resources, and counterproductively, i.e., increased pollutant loading. This paper presents a scientific rationale for a global ecological monitoring programme which will address open as well as coastal waters.     

Environmental Specimen Bank in Ehime University (es-BANK), Japan for global monitoring

During the last 40 years, The Center for Marine Environmental Studies (CMES), Ehime University collected a variety of environmental and biological material comprising about 1000 species and 100,000 samples from many developing and developed countries and also open seas and oceans all over the world. They were categorically archived, catalogued and stocked in our Environment Specimen Bank (es-BANK) facility equipped with a -25 degrees C cold room. We have already exchanged specimens with many scientific institutions and are also eager to widen our collaboration with other specimen banks. In our survey using the air, water, wildlife and human samples, we found that the major emission sources for the industrial chemicals like polychlorinated biphenyls (PCBs) are in the developed nations while those of organochlorine (OC) pesticides like dichlorodiphenyltrichloroethane and its metabolites (DDTs), hexachlorocyclohexane isomers (HCHs), etc. are located in developing countries. However, significant emission of modern environmental contaminants such as polybrominated diphenyl ethers (PBDEs) also seems to occur predominantly in countries with high economic growth rates. Apart from the modern incinerators and other industrial installations in developed nations, the compounds, like dioxins and related compounds (DRCs), were also found to be released in significant levels from the municipal solid waste dumping sites of developing countries. By evaluating the distribution patterns of various persistent toxic substances (PTSs) in our studies, we could conclude that DRCs and DDTs are regional contaminants, while PCBs, PBDEs, HCHs and hexachlorobenzene (HCB) are global contaminants. We also found that the pollution by PBDEs has been increasing in the last two decades while that of the legacy OCs has been decreasing.     

EPA's monitoring program at Love Canal 1980

Summary As stated at the beginning of this paper conclusions reached thus far cannot be discussed in this paper. However, a great deal of information is available for examination.EPA displayed its ability to coordinate widely separated laboratories, both Federal and private, into a smooth working team in a very short period of time. A very comprehensive study plan was also developed and implemented quickly. EPA was fortunate to have already had GCA under contract when the emergency arose. In no small part the success of the field effort was due to the managerial and technical abilities of the GCA team.Within a period of 6 weeks a plan was developed, a prime contractor retained, subcontractors hired, and field activities begun. Within a period of 3 months in excess of 8600 field samples were collected and over 12,000 field and QC samples were analyzed. During this same period 2 major data systems were developed, debugged, and placed into operation.In short this EPA project was probably the most comprehensive multimedia field project ever attempted by EPA and certainly the data is being subjected to the most strenuous quality control measures ever imposed by this Agency. The entire program is presently under peer review and the results are being prepared for publication by EPA Headquarters.Note. Originally intended to be published as part of the special issue on Exposure Monitoring: An International Workshop (Las Vegas, Nevada, October 19–22, 1981).     

Prioritizing GM crop monitoring sites in the dynamics of cultivation systems and their environment

EU legislation stipulates that GM crops have to be monitored for potential adverse environmental effects. Monitoring preferably should take place in the most exposed areas-the cultivated fields and their neighbouring environment. Current monitoring designs do not give detailed consideration to the different exposure intensities in agricultural practice. At the same time, the selection of specific, more exposed sites is difficult considering the dynamic and diversity of crop cultivation and rotation systems and their environments. We developed an approach for prioritising the monitoring of on-farm and neighbouring sites based on differing exposure levels using a minimum dataset of cultivation and land use information. Applying a Bt-maize cultivation scenario to Brandenburg, Germany, where presently no GM crops are cultivated, we systemised and categorised areas with different spatio-temporal exposure intensities including 50 m, 200 m and 1000 m buffers. These categories correspond to different suitabilities to serve as monitoring sites. Sites are prioritised using a sequential scheme. This yields an improved and objective spatial monitoring design providing detailed exposure information. This methodology is flexible and transferable to any agricultural setting, therefore enabling superior statistical comparisons between locations and regions and thus enhancing monitoring data quality.     

序贯数论优化法和侧影图进行河流优化布点

运用序贯数论优化法(SNTO)对监测点进行分类,同时根据分类结果,基于样本之间的相似性和差异性,构造一Rousseuw定义的函数并做侧影图,以确定各属类的最佳代表点,从而遴选出优化了的点位.     

Multimedia environmental monitoring: 50 years at Hanford

Environmental monitoring has been an ongoing activity on the U.S. Department of Energy's Hanford Site in southeastern Washington for almost 50 years. Objectives are to detect and assess potential impacts of Site operations on air, surface and ground waters, foodstuffs, fish, wildlife, soil and vegetation. Data from monitoring effects are used to calculate the overall radiological dose to humans working onsite or residing in nearby communities. In 1989, measured Hanford Site perimeter concentrations of airborne radionuclides were below applicable guidelines. Concentrations of radionuclides and nonradiological water quality in the Columbia River were in compliance with applicable standards. Foodstuffs irrigated with river water taken downstream of the Site showed radionuclide levels that were similar to those found in foodstuffs from control areas. Low levels of ¹³⁷Cs and ⁹⁰Sr in most onsite wildlife samples and concentrations of radionuclides in soils and vegetation from on- and offsite locations were typical of those attributable to worldwide fallout. The calculated dose potentially received by a maximally exposed individual (i.e., based on hypothetical, worst-case assumptions for all routes of exposure) in 1989 (0.05 mrem/yr) was similar to those calculated for 1985 through 1988.In addition to monitoring radioactivity in fish and wildlife, population numbers of key species are determined. Chinook salmon (Oncorhynchus tshawytscha) spawning in the Columbia River at Hanford has increased in recent years with a concomitant increase in winter roosting activity of bald eagles (Haliaeetus leucocephalus). An elk (Cervus elaphus) herd, established by immigration in 1972, is also increasing. The Hanford Site currently serves as a refuge for Canada goose (Branta canadensis), great blue heron (Ardea herodias), and various plants and other animals, e.g., mule deer (Odocoileus hemionus), and coyotes (Canis latrans).     

河流重油泄漏事故的应急监测

介绍了河流重油泄漏事故的应急监测,包括监测方案制定、监测点位设置、分析对象确定、跟踪监测、数据分析等。重油污染可通过监测水体中的石油类进行。监测结果表明,重油泄漏事故在短期内对水环境造成了严重影响,清除完全后,水体可逐步恢复正常。重油污染具有一定的持久性,在事发后需要对水体进行长期的跟踪监测。