Recycling of banana pseudostem waste for economical production of quality banana

Banana pseudostem biomass, traditionally incinerated and wasted, has been conserved and recycled by solid state fermentation (SSF) into plant growth stimulating soil conditioner (SC). This SC alone or combined with biofertilizers showed reduced mortality (10 and 12%) of planted suckers, enhanced chlorophyll contents (593 and 661 μg g⁻¹), gave biomass (35.0 and 36.6 kg) at par and improved yield (54.2 and 55.0 MT ha⁻¹), with that of the control (23%, 312 μg g⁻¹, 36.3 kg and 49.4 MT ha⁻¹, respectively). This has afforded (i) saving of chemical fertilizers by 50%, (ii) reduction in quantum (40%) and frequency (15%) of irrigation and (iii) reduction in cost of electricity and labor without sacrificing quality and quantity of banana. Thus, a voluminous agro-waste is converted into an eco-friendly agro-input for sustainable productivity.     

Screening analysis of volatile organic contaminants in commercial inorganic coagulants used for drinking water treatment

A method for quality screening is suggested to detect volatile impurities in inorganic coagulants that are used for drinking water treatment. Static headspace gas chromatography with mass spectrometry detection (HS–GCMS) is sensitive and selective to detect volatiles in low concentrations. This study has discovered that volatile organic impurities are detectable in ferric and aluminium-based coagulants which are used for drinking water treatment. For ferric chloride, 2-propanol was detected at a level of 17–24 μg ml⁻¹, acetone at 0.7–1.7 μg ml⁻¹, 1,1,1-trichloroacetone at 0.02–0.04 μg ml⁻¹, trichloromethane at 0.01–0.02 μg ml⁻¹ and toluene at 0.01–0.12 μg ml⁻¹. For ferric chloride sulfate, acetone was detected at a level of 0.12 μg ml⁻¹, 1,1,1-trichloroacetone at 0.06–0.08 μg ml⁻¹, trichloromethane at 0.13–0.23 μg ml⁻¹, bromodichloromethane at 0.04–0.06 μg ml⁻¹ and dibromochloromethane at 0.04–0.05 μg ml⁻¹. For aluminium hydroxide chloride, only trichloromethane was detectable, but below the method detection limits (MDL). Although the concentrations of these impurities in commercial coagulants are low, this observation is important and should have impact on water industries for them to pay attention to the chemicals they are using for drinking water production.     

Three Egyptian industrial wastewater management programmes

A pre-treatment programme for wastewater from factories, representing three main industrial sectors in Egypt, has been developed. The first case study was a factory producing potato-chips. Wastewater discharged from this factory was characterized by high values of BOD, SS and oil and grease (6000 mgO₂ l^–1, 6577 mg l^–1 and 119 mg l^–1 respectively). Chemical treatment using lime and lime aided by polyelectrolyte achieved good results. Residual values of BOD and SS after treatment were 97 mg l^–1 and 49 mg l^–1, respectively. Oil and grease concentrations were reduced by 91 percent. Treatment via activated sludge at a detention time of 4 hrs produced good quality effluent. The second case study was an automobile company, representing the metal finishing industry. Analyses of wastewater samples from the degreasing, phosphating and painting departments, as well as the end-of-pipe effluent were conducted. The end-of-pipe effluent contained high concentrations of oil and grease (366 mg l^–1), phosphorous (111 mg l^–1) and zinc (81 mg l^–1). Chemical treatment of end-of-pipe wastewater using ferric chloride aided by lime, produced high quality effluent. The third sector was the chemical industry. For this purpose a paint factory was selected. Characteristics of raw wastewater varied widely according to the production rate. Average values of COD and BOD were 1950 mg l^–1 and 683 mg l^–1. Oil and grease ranged from 63 to 1624 mg l^–1. Chemical treatment using ferric chloride in combination with lime at the optimum operating conditions achieved good results. Residual values after treatment of COD, BOD and oil and grease reached 120, 36 and 8.6 mg l^–1, respectively. An engineering design for each case study has been prepared.     

A Daily Time Series Analysis of StreamWater Phosphorus Concentrations Along an Urban to Forest Gradient

During a 1-year period, we sampled stream water total phosphorus (TP) concentrations daily and soluble reactive phosphorus (SRP) concentrations weekly in four Seattle area streams spanning a gradient of forested to urban-dominated land cover. The objective of this study was to develop time series models describing stream water phosphorus concentration dependence on seasonal variation in stream base flows, short-term flow fluctuations, antecedent flow conditions, and rainfall. Stream water SRP concentrations varied on average by ±18% or ±5.7 μg/L from one week to another, whereas TP varied ±48% or ±32.5 μg/L from one week to another. On average, SRP constituted about 47% of TP. Stream water SRP concentrations followed a simple sine-wave annual cycle with high concentrations during the low-flow summer period and low concentrations during the high-flow winter period in three of the four study sites. These trends are probably due to seasonal variation in the relative contributions of groundwater and subsurface flows to stream flow. In forested Issaquah Creek, SRP concentrations were relatively constant throughout the year except during the fall, when a major salmon spawning run occurred in the stream and SRP concentrations increased markedly. Stream water SRP concentrations were statistically unrelated to short-term flow fluctuations, antecedent flow conditions, or rainfall in each of the study streams. Stream water TP concentrations are highly variable and strongly influenced by short-term flow fluctuations. Each of the processes assessed had statistically significant correlations with TP concentrations, with seasonal base flow being the strongest, followed by antecedent flow conditions, short-term flow fluctuations, and rainfall. Times series models for each individual stream were able to predict ∼70% of the variability in the SRP annual cycle in three of the four streams (r² = 0.57–0.81), whereas individual TP models explained ∼50% of the annual cycle in all streams (r² = 0.39–0.59). Overall, time series models for SRP and TP dynamics explained 82% and 76% of the variability for these variables, respectively. Our results indicate that SRP, the most biologically available and therefore most important phosphorus fraction, has simpler and easier-to-predict seasonal and weekly dynamics.     

Effects of spent engine oil on the growth parameters, chlorophyll and protein levels of Amaranthus hybridus L.

The susceptibility of Amaranthus hybridus L. seedlings to spent engine oil was investigated in soil supplemented with concentrations of oil ranging from 1–5 percent v/w. Parameters considered were relative growth rate (RGR), leaf area ratio (LAR), whole plant height, leaf area, leaf number, chlorophyll and protein levels. A relationship was found to exist between the inhibitory effects and the treatment concentrations. After seventy days growth in the treated soils, the mean height and leaf area of plants in soils treated with 5 percent spent engine oil were 27.0±1.25 cm and 5.63±0.36 cm². These were significantly different (at p=0.05) from the respective values of 41.4±0.8 cm and 13.44±0.22 cm² for the control plants. Levels of total chlorophyll (per gram fresh weight of leaves) and protein (per gram dry weight of whole plant) were higher in the control plants compared with those grown in oil treated soil. Results obtained from the growth analysis showed the inhibitory effects of spent engine oil on Amaranthus hybridus L.     

Growth and macronutrient removal of water hyacinth in a small secondary sewage treatment plant

Studies have been made of the growth characteristics of water hyacinth, Eichhornia crassipes (Mart.) Solms, and its ability to remove N, P and K, in a secondary settling pond of a small secondary sewage treatment plant serving both the academic and residential blocks of the Swire Marine Laboratory, University of Hong Kong. The treatment plant consists of, in series, a primary settling tank, a trickling filter compartment and a secondary settling pond from which part of the treated wastewater is recycled to the primary settling tank while the remaining effluent (1 to 2 m³ daily) mixes with and hence is diluted by the outflowing seawater from the aquarium system of the Swire Marine Laboratory before discharge to the sea. Samples of wastewater have been taken regularly from the primary sedimentation pond, the outflow of the trickling filter, the secondary settling pond and the effluent of the treatment plant (before mixing with aquarium outflow) since January, 1992. Physical, chemical and biological characteristics of the samples have been determined and are typical of secondary effluents, with a mean pH of about 7.5, total solids 1200 mg L⁻¹, suspended solids 45 mg L⁻¹, conductivity 2000 μS cm⁻¹, salinity 1 ppt, dissolved oxygen 2 mg L⁻¹, BOD₅ 45 mg L⁻¹, Kjeldahl-N 30 mg L⁻¹, NH₄,-N 25 mg L⁻¹, NO₃-N 4 mg L⁻¹, total P 10 mg L⁻¹, K 35 mg L⁻¹ and total coliforms of less than 10⁵ colonies 100 ml⁻¹.Water hyacinth plants have been stocked in the secondary settling pond as an integral part of the treatment plant so as to improve the quality of, as well as to retrieving and recycling nutrient elements from, the wastewater. The plants are periodically harvested to maintain an active growing crop. The growth rate, standing crop biomass, tissue nutrient composition, nutrient storage and accumulation rate of two growth cycles, one from February 25 to March 18 (mean temperature 17.6°C) and the other from 22 April to 12 May (24.8°C) are reported. The water hyacinth assumed a relatively high standing crop biomass of 10 kg m⁻² (5 to 6 t DM ha⁻¹), and growth rates of 48 and 225 g m⁻² day⁻¹, respectively, for the first and second growth period. Nutrient storage capacities were relatively high, at about 20, 7.5 and 16.5 g m⁻² for N, P and K, respectively. The nutrient composition was very high, reaching 5.42% for N, 1.97 for P, and 4.57 for K. Both the stem and lamina accumulated high levels of N, while the petiole had the highest level of P and K. Apart from nutrient removal, the water hyacinth also helped to decrease the suspended solids, BOD₅ value and total coliforms of the wastewater.It is concluded that water hyacinth improves the quality of wastewater in such small-scale sewage treatment plants and it is recommended that frequent harvests of water hyacinth would increase the treatment efficiency, especially during the active growing season with high temperatures coupled with intense solar radiation.     

The Water Quality of some Tropical Freshwater Bodies in Uyo (Nigeria) Receiving Municipal Effluents, Slaughter-House Washings and Agricultural Land Drainage

The water quality of some tropical fresh-water bodies in Uyo (Nigeria) was investigated for two years in relation to point and non-point source city effluents and slaughter-house washings discharged into them. Streams which received city effluents and slaughter-house washings were degraded in quality with acidic water (pH =5.26±0.83 to 6.20±0.56), low oxygenation (2.46±1.30 to 3.88±0.29 mgl^–1), high biochemical oxygen demand (4.96±0.66 to 8.20±0.82 mgl^–1) and chemical oxygen demand (88.60±3.50 to 146.36±9.86 mgl^–1) than non-effluent receiving streams. High acidity in streams is due mainly to the acidic nature of underground water which replenishes the streams. Nutrient levels were high indicating enrichment from highly fertilized farmlands and slaughter-house washings. The concentrations of most of the hydrochemical variables were significantly lower in non-effluent than effluent-receiving streams. Some of the hydrochemical variables (total alkalinity, dissolved oxygen, nitrate, phosphate and conductivity) exhibited pronounced seasonality regimes with significant correlations with rainfall indicating its influence on the chemical hydrology of the water bodies. Land use in the catchment influenced water quality through inflow of nutrients, organic and inorganic contaminants and siltation. Pollution in the impacted streams is attributed mainly to episodic events.     

Comparison of biosorbents with inorganic sorbents for removing copper(II) from aqueous solutions

In comparison with several other reported inorganic sorbents, Camellia tree leaf and primary sludge obtained from a settling tank as a pretreatment to the activated sludge system in a Hong Kong sewage treatment plant were evaluated for removing Cu(II) from aqueous solutions. Experimental data were modeled by the Langmuir isotherm equation to estimate the maximum sorption capacity (q_max). Results show that, at pH 5.6, biosorbents, Camellia tree leaf and primary sludge in particular, exert higher sorption capacities (q_max > 40 mg g⁻¹) than inorganic sorbents, Na-montmorillonite (q_max = 33.3 mg g⁻¹), fly ash (q_max = 18.8 mg g⁻¹), and goethite powder (10.3 mg g⁻¹). Furthermore, a pseudo second-order kinetic model was found to properly describe the experimental data for both bio- and inorganic sorbents. Sorption of Cu(II) on the Camellia tree leaf and primary sludge were much faster than that on the inorganic sorbents. In addition, desorption tests revealed that the desorption capacities of the two biomaterials are higher than the other selected materials; and much more Cu(II) can be retrieved from the Cu(II)-loaded biosorbents. Finally, increasing solution pH was found to greatly increase q_max and accelerate sorption processes.     

Utilization of waste product (tamarind seeds) for the removal of Cr(VI) from aqueous solutions: Equilibrium, kinetics, and regeneration studies

In the present study, an adsorbent was prepared from tamarind seeds and used after activation for the removal of Cr(VI) from aqueous solutions. The tamarind seeds were activated by treating them with concentrated sulfuric acid (98% w/w) at a temperature of 150 °C. The adsorption of Cr(VI) was found to be maximum at low values of initial pH in the range of 1–3. The adsorption process of Cr(VI) was tested with Langmuir, Freundlich, Redlich–Peterson, Koble–Corrigan, Tempkin, Dubinin–Radushkevich and Generalized isotherm models. Application of the Langmuir isotherm to the system yielded a maximum adsorption capacity of 29.7 mg/g at an equilibrium pH value ranging from 1.12 to 1.46. The adsorption process followed second-order kinetics and the corresponding rate constants obtained were 2.605 × 10⁻³, 0.818 × 10⁻³, 0.557 × 10⁻³ and 0.811 × 10⁻³ g/mg min⁻¹ for 50, 200, 300 and 400 mg/L of initial Cr(VI) concentration, respectively. The regenerated activated tamarind seeds showed more than 95% Cr(VI) removal of that obtained using the fresh activated tamarind seeds. A feasible solution is proposed for the disposal of the contaminants (acid and base solutions) containing high concentrations of Cr(VI) obtained during the regeneration (desorption) process.     

Role of Alternative Electron Acceptors (AEA) to control methane flux from waterlogged paddy fields: Case studies in the southern part of West Bengal, India

The rice fields, depleted of O₂, contain large amount of moisture and organic substrates to provide an ideal anaerobic environment for methanogenesis and are one of the principal anthropogenic sources of methane. In order to mitigate this emission Alternative Electron Acceptors (AEA) were altered in the soil. The experiments were carried out in four seasons at the site of Balarampur, near Baruipur, South 24 Parganas, West Bengal, namely September–December, 2005 (Cultivar: Sundari), February–May, 2006 (Cultivar: Sundari), September–December, 2006 and February–May, 2007 (Cultivar: Swarna-Pankaj). The seasonal average methane flux (Fe treated), for the cultivar type “Sundari” (season: September–December, 2005), is 4.41 t ha⁻¹, as compared to the value of 6.40 t ha⁻¹ for the untreated soil. Similarly for February–May, 2006, the seasonal average methane flux (Fe treated) is 5.52 t ha⁻¹, whereas the untreated flux is 5.69 t ha⁻¹. In the third and fourth seasons we had two treatments with Ammonium Thiosulphate and Ferric Hydroxide. The seasonal average methane flux (treatment: Ammonium Thiosulphate) is 4.35 t ha⁻¹ and 5.41 t ha⁻¹ respectively, whereas for the ferric hydroxide treated soil it is 4.35 t ha⁻¹ and 6.14 t ha⁻¹ respectively. The properties related to the nutrient quality of the harvested paddy seeds supplement these results.     

Cadmium in aquatic ecosystems in Western Australia: A legacy of nutrient-deficient soils

More than 273 tonnes of cadmium have been added to Western Australian ecosystems through the application of superphosphate fertilisers since 1982. Fifty percent of this is water soluble and therefore eventually leaches into waterbodies and accumulates in the sediments. From this source, it enters the food web through algae and benthic animals and may ultimately be passed to humans. This is reflected in the cadmium levels of the freshwater mussels (Westralunio carteri) that exceeded statutory Australia New Zealand Food Authority (ANZFA) guidelines for Maximum Permissible Concentrations (MPCs) with respect to human consumption. The cadmium levels bioaccumulated in freshwater mussels elevated with increasing catchment clearing, being highest in degraded catchments. The MPC for Cd in crustaceans have recently been removed, yet tissues within the freshwater crayfish (Cherax tenuimanus) frequently exceeded the old MPC (0·2 μCd g⁻¹wet weight). Marron are sometimes consumed in considerable quantities and the risk to human health posed by a high Cd intake is briefly summarised. Finally, a number of management options concerned with reducing the level of Cd from fertilisers passing to humans are reviewed.     

Recovery of phosphate from calcinated bone by dissolution in hydrochloric acid solutions

In this study, the optimum conditions of dissolution of calcinated bone in HCl solutions with different concentrations are investigated. Recovery of phosphate from calcinated bone by dissolution with hydrochloric acid solutions was investigated in a batch reactor, it was observed that a 32% hydrochloric acid solution can dissolve the calcinated bone effectively. Using the Taguchi fractional design method, it was found that the optimum process conditions, at which 67.2% P₂O₅ dissolution was reached, were as follows: Reaction temperature: 318 K, solid-to-liquid ratio: 1/5 (g ml⁻¹), acid concentrations:32 (% w/v), stirring speed:400 min⁻¹ and reaction time: 60 min.     

Mobility of oil and other sludge constituents during oily sludge treatment by landfarming

Five levels of oily sludge application were made to the surface layer of a desert sandy soil in Kuwait. The migration of the constituents of the sludge to subsurface soil layers was investigated at intervals over a period of 29 months. The data show very limited mobility to subsurface soil layer (40–70 cm depth) but not to 70–90 cm depth. The environmental impact of the added sludge is related to soil pH and to the Zn equivalent value of the sludge. Zn equivalent for the soil treated with oily sludge was 612 mg kg⁻¹, which is much lower than permissible limits. This soil can accept more than 1000 t ha⁻¹ from this type of sludge. However, due to the heterogeneous composition of sludge the Zn equivalent value should be calculated for each batch. Addition of oily sludge to the desert soil susceptible to wind erosion had a significant effect on minimizing soil loss under wind tunnel conditions. This effect is attributed to aggregation of the soil particles in the surface soil layers.     

Utilization of pulp and paper industrial wastes to remove heavy metals from metal finishing wastewater

Two pulp and paper industrial wastes, lime mud (LM) and recovery boiler ash (RB), have low moisture contents, low heavy metal contaminations and contain various carbonate compounds which contribute to a high pH. Metal finishing wastewater (MF-WW) has a low pH, high levels of TDS and high contaminations from Cr, Cu, Pb and Zn. The heavy metals from MF-WW were removed by sorption and precipitation mechanisms. LM gave better results in removing heavy metals from MF-WW than RB. At a reaction time of 45 min, the maximum removal efficiencies for Cr (93%) and Cu (99%) were obtained at 110 g L⁻¹ of LM, but at 80 g L⁻¹ for Pb (96%) and Zn (99%). Treatment with LM gives a higher sludge volume than with RB. However, the leachability of heavy metals from LM is lower. Leachability of heavy metals in the sediment for all selected treatment conditions is within government standards.     

Biosorption of Cu and Zn from aqueous solutions by dried marine green macroalga Chaetomorpha linum

The biosorption of the heavy metals Cu²⁺ and Zn²⁺ by dried marine green macroalga (Chaetomorpha linum) was investigated. The biosorption capacities of the dried alga for copper and zinc were studied at different solution pH values (2–6), different algal particle sizes (100–800 μm) and different initial metal solution concentrations (0.5–10 mM). An optimum pH value of 5 was found suitable for both metal ions biosorption for both metal ions. At the optimum particle size (100–315 μm), biosorbent dosage (20 g/l) and initial solution pH (pH 5), the dried alga produced maximum copper and zinc uptakes values (q_max) of 1.46 and 1.97 mmol/g respectively (according to the Langmuir model). The kinetic data obtained at different initial metal concentrations indicated that the biosorption rate was fast and most of the process was completed within 120 min. This study illustrated an alternative technique for the management of unwanted biological materials using processed algal material. C. linum is one of the fast-growing marine algae in the lake of Tunis and could be utilized as a biosorbent for the treatment of Cu²⁺ and Zn²⁺ contaminated wastewater streams.     

Composting of vinasse and cotton gin waste by using two different systems

Two composts were obtained by co-composting of a concentrated depotassified beet vinasse and cotton gin waste using two different aeration systems: static aerated pile (forced aeration provided by a blower whom operated in the positive mode) and windrow (turned pile). The composting mixtures were cotton gin trash (55%) and vinasse (45%) (dry weight). In static pile, the total amount of vinasse was added at the beginning of the process whereas, in windrow two additions of vinasse were performed. Differences in temperature changes between both composting systems were found: a faster increase of temperature in the windrow (54 °C at 7 days) than in the static pile (45 °C at 21 days) was observed. Probably in the static pile system, the compaction of the substrates made difficult the correct distribution of the air inside the pile. Moreover, after the second addition of vinasse a new thermophilic phase was started in windrow. The different aeration systems and the way of addition of vinasse could cause differences in organic matter (OM) degradation and in weight (22.6% for the static pile and 26.7% for the windrow) and gas losses during the process. Nevertheless, the composts obtained by the two systems had a high fertilizer value (25.1 g kg⁻¹ N; 3.2 g kg⁻¹ P₂O₅; 21.4 g kg⁻¹ K₂O; C/N8) for compost obtained in static pile and (16.2 g kg⁻¹ N; 3.4 g kg⁻¹ P₂O₅; 16.1 g kg⁻¹ K₂O; C/N 12) for compost obtained in the windrow). A high degree of stability was reached in the final composts. Composting of vinasse with cotton gin waste serves two objectives, disposal of wastes and recycling of waste components.     

Sewage sludge as organic ameliorant for revegetation of fine bauxite refining residue

The rise in aluminium demand in the world has significantly increased the generation of bauxite residue which occupies huge areas of land worldwide. Direct revegetation of residue storage areas has been unsuccessful because of the high alkalinity and salinity, and poor nutrient contents of the fine residue (red mud). This paper describes glasshouse and field experiments evaluating the potential use of sewage sludge as an organic ameliorant for gypsum amended red mud. The growth of Agropyron elongatum in red mud receiving gypsum (0 and 38.5 t ha⁻¹) and sewage sludge (0, 38.5 and 77 t ha⁻¹) amendment was assessed in a glasshouse study. Leachate and soil analyses revealed that gypsum was effective in reducing the pH, EC and ESP of red mud, while sewage sludge gave additional reductions in EC, Na and ESP. No evidence of any significant increases in heavy metal contents were observed in the leachates following sewage sludge amendment. However, soil Al contents were more available in red mud receiving only sewage sludge treatment. Sewage sludge amendment significantly increased dry weight yield and provided sufficient nutrients for plant growth except K which was marginal. No heavy metal accumulation was observed in Agropyron. Following that, a field experiment was performed having red mud amended with sewage sludge (38.5, 77 and 154 t ha⁻¹) and gypsum (38.5 and 77 t ha⁻¹) to evaluate their effects on soil physical properties of red mud. Sewage sludge significantly reduced soil bulk density (25%) and particle density (9%) and increased the total porosity of red mud (8%). Hydraulic conductivity also increased from 1.5 to 23 × 10⁻⁵ m s⁻¹. Plant cover percentage and dry weight yield of Agropyron increased with an increase in gypsum and sewage sludge amendment. The results confirm that sewage sludge is effective in improving both soil structure and nutrient status of gypsum amended red mud. The use of sewage sludge for red mud revegetation provides not just an option for sludge disposal, but also a cost effective revegetation strategy for bauxite refining industry.     

Vetiver (Vetiveria zizanioides) responses to fertilization and salinity under irrigation conditions

Vetiver (Vetiveria zizanioides) has not been widely introduced in arid and semi-arid regions where irrigation, fertilization, and salinity are important factors in plant growth. The main objective of this study was to determine the response of vetiver to fertilization (fertigation) and salinity and their interactions under irrigated conditions. The experiment was conducted in a greenhouse in 10-L pots. Combined effects of three nutrients concentrations and three salinity levels of electrical conductivity (EC) 1, 3 and 6 dS/m in the irrigation water on growth and transpiration of vetiver plants and the content of different elements in their foliage were studied. Similar contents of 3.7 g/kg Na, 5.77 g/kg Ca and 2.55 g/kg Mg were found in the foliage of all the plants irrigated with the different fertilizer and salinity levels. Concentrations of 59 mg/L N and 36.1 mg/L K in the irrigation water were sufficient for vetiver plants needs at the different salinity levels tested. The salinity threshold (the maximum EC in the soil solution that does not cause a significant yield reduction) for vetiver was between 3 and 6 dS/m. A concentration of 15.2 mg/L P in the irrigation water was the optimum value for vetiver growth in the three salinity levels, resulting in an average content of 5.95 g/kg P in plant foliage. It is suggested that vetiver is sensitive to excess P (>8.66 g/kg). Increasing EC in the irrigation water to 6 dS/m decreased plant foliage biomass mainly due to an increase in the osmotic potential of the irrigation water and high Cl⁻ concentration in the foliage.     

Decontamination of water polluted by heavy metals with Taro (Colocasia esculenta) cultured in a hydroponic NFT system

The toxicity and bioaccumulation of two heavy metals—lead (Pb) and cadmium (Cd)—in a semi-aquatic plant, Colocasia esculenta (L. Schott), from a synthetic heavy metal solution were studied. Young plants of equal size were grown hydroponically in shallow raceways containing Hoagland medium amended with 20, 40, and 60 mg l^?1 of Pb and 2, 4, and 6 mg l^?1 of Cd. The medium containing heavy metals was allowed to flow through the raceways with a change in influent heavy metal solution on every 5th day. The experiment was continued for 20 days. A set of control raceways—one comprised of nutrient medium with heavy metal supplements, devoid of plants, and another with the plants and nutrient medium having no metal supplement—was also simultaneously run. Chlorosis in the leaves was the prominent toxicity symptom observed due to Pb and Cd on the test plants. A significant decrease in the relative growth, biomass productivity, and total chlorophyll content were noticed in the plants with an increase in concentration of metal supplement in the solution and exposure time. Both metals accumulated to higher concentrations in the roots than in shoots, suggesting that the metals were bound to the root cells and their translocation to the leaves was limited. The results of the 20-day-long experiments indicate that from a phytoremediation perspective, C. esculenta is a promising plant species for remediation of wastewater polluted with lower concentrations of Pb and Cd.     

Unexpected difference in phenol sorption on PTMA- and BTMA-bentonite

The comparison of phenol sorption on phenyltrimethylammonium (PTMA)- and benzyltrimethylammonium (BTMA)-bentonite shows a clear difference as far as phenol sorption isotherms are concerned. For PTMA-bentonite the sorption isotherm is of a straight-line character which results from simple partitioning of phenol between the aqueous and organic phases sorbed on the bentonite surface. For BTMA-bentonite the isotherm has a convex shape, characteristic of physicochemical sorption.For the first time a three-parametric model, including the dissociation constant of phenol pK_a, distribution constant of phenol Kd_phen and phenolate anion Kd_phen⁻ between the aqueous phase and the bentonite phases is used for the evaluation of phenol sorption on organoclays with pH change. The model shows that the values of Kd_phen are higher than those of Kd_phen⁻ for all investigated initial phenol concentrations.The inspection of the FTIR spectrum of BTMA-bentonite loaded with phenol in the regions 1300–1600 and 1620–1680 cm⁻¹ shows the features of π–π electron interaction between the benzene rings of phenol and the BTMA cation together with the phenol–water hydrogen bond strengthened by this interaction.