Electrocoagulation of some reactive dyes: a statistical investigation of some electrochemical variables

In this study, the decolorization of strong colored solutions containing the reactive textile dyes by electrocoagulation was investigated. The experiments were statistically designed and carried out according to a 2(4) full factorial design with two replicate and four center points. This design was extended with eight additional axial points. Then, the non-linear regression was applied on the data by using MINITAB software. The variables chosen for this work are mixing rate, cell voltage, electrolysis time and current density. Results showed that the effective variables on decolorization process are cell voltage, electrolysis time and current density. In addition, to determine the effect of dye and electrode type on decolorization, the additional experiments were carried out. It was determined the dye and electrode type are important on the decolorization process.     

Open dumps in the Hellenic prefecture of Laconia: statistical analysis of characteristics and restoration prioritization on the basis of a field survey.

This study presents an assessment of the current status of open dumps in Laconia prefecture of Peloponnese in southern Greece, where all open dumps are targeted for closure by 2008. An extensive field survey was conducted in 2005 to register existing sites in the prefecture. The data collected included the site area and age, waste depth, type of disposed waste, distance from nearest populated area, local geographical features and observed practices of open burning and soil coverage. On the basis of the collected data, a GIS database was developed, and the above parameters were statistically analysed. Subsequently, a decision tool for the restoration of open dumps was implemented, which led to the prioritization of site restorations and specific decisions about appropriate restoration steps for each site. The sites requiring restoration were then further classified using Principal Component Analysis, in order to categorize them into groups suitable for similar restoration work, thus facilitating fund allocation and subsequent restoration project management.     

Assimilation of radar measured surface current fields into a numerical model for oil spill modelling

In summer 1996, surface current fields were measured in the central Strait of Georgia using the SeaSonde, a portable shore-based HF radar system. The objective of the study was to assess the feasibility of blending SeaSonde currents with numerical model fields to fill gaps in the measured fields and reduce noise. Our eventual goal is to assimilate the blended SeaSonde fields into a three-dimensional numerical model to improve short-range current forecasts.The first part of the study involved using the blended current fields as input to a set of auto-regressive moving-average (ARMA) statistical models. The blended fields were found to give forecasts comparable in terms of RMS error with forecasts using raw SeaSonde measurements. Moreover, the blended fields were smoother and more spatially complete than the raw data. The second part of the study examined the suitability of using the SeaSonde current fields to update the surface layer of Seaconsult's C3 hydrodynamic model. A simple nudging method is presented as an economical way to drive the model surface layer using operationally gathered SeaSonde information.     

Biomedical waste management in nursing homes and smaller hospitals in Delhi

The management of biomedical waste is a crucial issue in health and environmental management. Rules in India were promulgated in 1998, originally with a deadline of December 2000 and extended to December 2002; however, the actual situation remains far from satisfactory. A study conducted in 2001 by CEE, New Delhi; indicated an implementation deficit. To gauge the present situation, a survey was undertaken during 2005-2006. A systematic analysis of current biomedical waste management practices in smaller nursing homes and hospitals in Delhi was carried out. A total of 53 nursing homes, with bed strengths ranging from 20 to over 200, were included. The survey results show that there is a marked improvement in the segregation practices of biomedical waste in small private hospitals and nursing homes. The majority of nursing homes and hospitals were found to be using a service provider for the collection, management, and disposal of healthcare wastes. Data was collected through a questionnaire and field visits. This paper discusses the relevant data indicative of current practices of healthcare waste management in the nursing homes and small healthcare facilities in Delhi.     

A Novel Environmental Quality Criterion for Acidification in Swedish Lakes – An Application of Studies on the Relationship Between Biota and Water Chemistry

The recovery from acidification has led to the demand for more precise criteria for classification of acidification. The Swedish Environmental Protection Agency has revised Sweden’s Ecological Quality Criteria for acidification to improve the correlation between the chemical acidification criteria and biological effects. This paper summarises the most relevant findings from several of the studies commissioned for this revision. The studies included data on water chemistry in 74 reference lakes in southern Sweden with data on fish in 61 of the lakes, as well as data on littoral fauna in 48 lakes. We found that the acidity variable most strongly correlated to the biota was the median pH from the current year. Our results probably do not reflect the mechanisms behind the negative effects of acidity on the biota, but are fully relevant for evaluation of monitoring data. The biogeochemical models used for predicting acidification reference conditions generate a pre-industrial buffering capacity. In order to get an ecologically more relevant criteria for acidification based on pH, we transferred the estimated change in buffering capacity into a corresponding change in pH. A change of 0.4 units was defined as the threshold for acidification. With this criterion a considerably lower number of Swedish lakes were classified as acidified when compared with the present Ecological Quality Criteria.     

An Analysis of the Structure of the Simple Mass Balance Equation: Implications for Testing National Critical Loads Maps

The critical loads concept is used by the UN-ECEConvention on Long Range Transboundary Air Pollution(CLRTAP) for setting pollution reduction targets.Increasing numbers of countries are adopting the SimpleMass Balance equation (SMB) to calculate critical loads ofacidifying S and N for forest soils. The equation is madeup of a series of mass balances each of which is used tocalculate a leaching flux. The assumptions in the SMBequation were investigated by testing its ability topredict current sulphur load and by comparing each of thecalculated leaching fluxes to measured rates. It was notpossible to predict current sulphur load at our sites usingthe SMB equation. The leaching tests demonstrated that,primarily due to its steady state assumptions, the SMBequation generates critical loads that are theoretical longterm estimates of risk, and are untestable. Thesimplifying assumptions sometimes lead to illogicalresults. Some of these can be improved by adding a final,simple but dynamic, calculation step to determine theexpected time until effects are observed. Theacceptability of combining annual average data, which bestapproximates steady state, with a biological indicator isquestionable. It is not possible to test critical loadscalculated using the SMB equation when applied with all ofits assumptions but it is possible to test its fundamentalapproach using non steady state data.     

Centralization of dairy farming facilities for improved economics and environmental quality

In Japan, most farm animal excreta has been stored directly on farmland. Runoff from this storage has often caused water pollution. Biogasification is anticipated as an important technology to manage excreta properly, but complex problems hinder its introduction. Economic aspects of management have been especially difficult for dairy farmers. For this study, structural problems regarding introduction of biogasification into dairy farming were identified. Subsequently, a desirable system of dairy farming including biogasification was suggested, and an evaluation model of the financial balance was constructed. A case study using current financial balances of several systems of dairy farming was evaluated using the constructed model and actual data. The systems were based on several policy alternatives including the suggested system mentioned above. Results show that a farmer can obtain sufficient income from a system featuring centralization of dairy housing and biogasification facilities and coordinated management by over six farmers.     

Waste management options in southern Europe using field and experimental data

The applicability of the Waste Management Hierarchy concept that appeared to be an essential element in current national environmental policies was investigated in the case of a region in Southern Europe. The waste generation profile that determines the appropriateness of different waste management options was created after a 1-year municipal waste sampling investigation conducted in the Municipality of Pilea in Northern Greece. The paper describes the results of (1) the sampling method, which was conducted four times during 1 year (once per season) in selected areas of the city, (2) the qualitative analysis of the collected samples and (3) the waste treatment, which consisted of drying, grinding, calorific value measurement, incineration and chemical analysis of the collected samples. Comparative analysis between the above mentioned data and on past data derived from investigations conducted in other Greek regions with similar characteristics to those of Pilea were used to identify and discuss future trends in the composition of generated waste over time. An analysis of the current waste management status in Greece as well as the feasibility of implementing a comprehensive management approach is assessed taking into account guidelines set worldwide to promote renewable energy sources use. It is concluded that recycling, perhaps the most positively received of all waste management practices, is going to be an essential part of contemporary waste management strategies, composting can play an important role, while incineration seems to be a conditionally feasible solution.     

Projection of end-of-life vehicle (ELV) population at provincial level of China and analysis on the gap between the future requirements and the current situation of ELV treatment in China

The paper describes a model for projecting the ELV population in 31 province-level regions of China in 2015, 2017, and 2020 under three scenarios, and compares the projection results with the current distribution and capacity of qualified ELV processors in China. Historical data on the population, GDP and vehicle scrap rates are combined to model ELVs. The development in vehicle ownership is modeled by a dynamic Gompertz function. We acquire a model for the changing trend of the vehicle scrap rate as motorization improves, using Japanese historical data of over 60 years. We recalculate the parameters of the model using Chinese historical data collected over a decade when applying the model to China. The paper not only presents a baseline projection of the ELV population in province-level regions of China at different levels of motorization, but also identifies the gap between the future requirements and the current situation of ELV treatment in China.     

Practice review of five bioreactor/recirculation landfills

Five landfills were analyzed to provide a perspective of current practice and technical issues that differentiate bioreactor and recirculation landfills in North America from conventional landfills. The bioreactor and recirculation landfills were found to function in much the same manner as conventional landfills, with designs similar to established standards for waste containment facilities. Leachate generation rates, leachate depths and temperatures, and liner temperatures were similar for landfills operated in a bioreactor/recirculation or conventional mode. Gas production data indicate accelerated waste decomposition from leachate recirculation at one landfill. Ambiguities in gas production data precluded a definitive conclusion that leachate recirculation accelerated waste decomposition at the four other landfills. Analysis of leachate quality data showed that bioreactor and recirculation landfills generally produce stronger leachate than conventional landfills during the first two to three years of recirculation. Thereafter, leachate from conventional and bioreactor landfills is similar, at least in terms of conventional indicator variables (BOD, COD, pH). While the BOD and COD decreased, the pH remained around neutral and ammonia concentrations remained elevated. Settlement data collected from two of the landfills indicate that settlements are larger and occur much faster in landfills operated as bioreactors or with leachate recirculation. The analysis also indicated that more detailed data collection over longer time periods is needed to draw definitive conclusions regarding the effects of bioreactor and recirculation operations. For each of the sites in this study, some of the analyses were limited by sparseness or ambiguity in the data sets.     

Domestic waste management and recovery in Hong Kong

This article presents a review of the current municipal solid waste (MSW) and domestic waste generation and recovery situation in Hong Kong and identifies the factors affecting the waste generation rates. The results show that before 1997, MSW and domestic waste generation rates were driven by population growth and growth in the gross domestic product, with the latter having the larger effect. But recent waste generation data show poor correlation between waste generation rates and economic and population figures due to the increase in recycling efforts in the community. The results are also reported of a small-scale survey to explore the public attitude to waste recovery. The results show that most domestic householders have developed habits to carry out separation of waste at source for recycling, but the amount of recyclables recovered was low.     

A baseline study characterizing the municipal solid waste in the State of Kuwait

This paper provides a new reference line for municipal solid waste characterization in Kuwait. The baseline data were collected in accordance with the Standard Test Method for the Determination of the Composition of Unprocessed Municipal Solid Waste (ASTM). The results indicated that the average daily municipal waste generation level is 1.01 kg/person. Detailed waste stream surveys were conducted for more than 600 samples of municipal solid waste (MSW). The waste categories included paper, corrugated fibers, PET bottles, film, organic matter, wood, metal, glass, and others. The results indicated that organic waste dominated the characterization (44.4%), followed by film (11.2%) and then corrugated fibers (8.6%). Analysis of variance (ANOVA) was used to investigate the influence of season and governorate on waste composition. A significant seasonal variation was observed in almost all waste categories. In addition, significant differences in proportions between the current level and 1995 baseline were observed in most waste categories at the 95% confidence level.     

Research on the recycling industry development model for typical exterior plastic components of end-of-life passenger vehicle based on the SWOT method

In-depth studies on the recycling of typical automotive exterior plastic parts are significant and beneficial for environmental protection, energy conservation, and sustainable development of China. In the current study, several methods were used to analyze the recycling industry model for typical exterior parts of passenger vehicles in China. The strengths, weaknesses, opportunities, and challenges of the current recycling industry for typical exterior parts of passenger vehicles were analyzed comprehensively based on the SWOT method. The internal factor evaluation matrix and external factor evaluation matrix were used to evaluate the internal and external factors of the recycling industry. The recycling industry was found to respond well to all the factors and it was found to face good developing opportunities. Then, the cross-link strategies analysis for the typical exterior parts of the passenger car industry of China was conducted based on the SWOT analysis strategies and established SWOT matrix. Finally, based on the aforementioned research, the recycling industry model led by automobile manufacturers was promoted.     

Assessing computer waste generation in Chile using material flow analysis

The quantities of e-waste are expected to increase sharply in Chile. The purpose of this paper is to provide a quantitative data basis on generated e-waste quantities. A material flow analysis was carried out assessing the generation of e-waste from computer equipment (desktop and laptop PCs as well as CRT and LCD-monitors). Import and sales data were collected from the Chilean Customs database as well as from publications by the International Data Corporation. A survey was conducted to determine consumers’ choices with respect to storage, re-use and disposal of computer equipment. The generation of e-waste was assessed in a baseline as well as upper and lower scenarios until 2020.The results for the baseline scenario show that about 10,000 and 20,000 tons of computer waste may be generated in the years 2010 and 2020, respectively. The cumulative e-waste generation will be four to five times higher in the upcoming decade (2010–2019) than during the current decade (2000–2009). By 2020, the shares of LCD-monitors and laptops will increase more rapidly replacing other e-waste including the CRT-monitors. The model also shows the principal flows of computer equipment from production and sale to recycling and disposal. The re-use of computer equipment plays an important role in Chile. An appropriate recycling scheme will have to be introduced to provide adequate solutions for the growing rate of e-waste generation.     

Combined MODFLOW‐FRACTRAN Application to Assess Chlorinated Solvent Transport and Remediation in Fractured Sedimentary Rock

Detailed field investigations and numerical modeling were conducted to evaluate transport and fate of chlorinated solvent contamination in a fractured sedimentary bedrock aquifer (sandstone/siltstone/mudstone) at a Superfund site in central New Jersey. Field investigations provided information on the fractured rock system hydrogeology, including hydraulic gradients, bulk hydraulic conductivity, fracture network, and rock matrix, and on depth discrete contaminant distribution in fractures (via groundwater sampling) and matrix (via detailed subsampling of continuous cores). The numerical modeling endeavor involved application of both an equivalent porous media (EPM) model for flow and a discrete fracture network (DFN) model for transport. This combination of complementary models, informed by appropriate field data, allowed a quantitative representation of the conceptual site model (CSM) to assess relative importance of various processes, and to examine efficacy of remedial alternatives. Modeling progressed in two stages: first a large‐scale (20 km x 25 km domain) 3‐D EPM flow model (MODFLOW) was used to evaluate the bulk groundwater flow system and contaminant transport pathways under historic and current aquifer stress conditions and current stresses. Then, results of the flow model informed a 2‐D DFN transport model (FRACTRAN) to evaluate transport along a 1,000‐m flowpath from the source represented as a 2‐D vertical cross‐section. The combined model results were used to interpret and estimate the current and potential future extent of rock matrix and aqueous‐phase contaminant conditions and evaluate remedial strategies. Results of this study show strong effects of matrix diffusion and other processes on attenuating the plume such that future impacts on downgradient well fields under the hydraulic stresses modeled should be negligible. Results also showed futility of source remediation efforts in the fractured rock, and supported a technical impracticability (TI) waiver for the site. © 2013 Wiley Periodicals, Inc.     

Real time oil spill forecasting during an experimental oil spill in the arctic ice

The oil spill trajectory and weathering model OILMAP was used to forecast spill trajectories for an experimental oil spill in the Barents Sea marginal ice zone. The model includes capabilities to enter graphically and display environmental data governing oil behavior: ice fields, tidal and background current fields, and wind time series, as well as geographical map information. Forecasts can also be updated from observations such as airplane overflights. The model performed well when wind was ‘off-ice’ and speeds were relatively low (3–7 m s⁻¹), with ice cover between 60 and 90%. Errors in forecasting the trajectory could be directly attributed to errors in the wind forecasts. Appropriate drift parameters for oil and ice were about 25% of the wind speed, with an Ekman veering angle of 35° to the right. Ice sheets were typically 1 m thick. When the wind became ‘on-ice’, wind speeds increased to about 10 m s⁻¹ and trajectory simulations began to diverge from the observations, with observed drift parameters being 1.5% of the wind speed, with a 60° veering angle. Although simple assumptions for the large scale movement of oil in dense ice fields appear appropriate, the importance of good wind forecasts as a basis for reliable trajectory prognoses cannot be overstated.     

采用优化生产调度进行印染废水源头控制的研究进展

总结了当前国内外印染企业运用优化生产调度实现废水排放源头控制的研究现状。介绍了优化生产调度系统的工作过程。从实际生产应用的角度出发,分析了不同优化算法进行生产调度存在的问题,提出了改进意见,同时对如何建立基于大数据采集的优化生产调度系统进行了阐述。对印染企业如何运用大数据采集系统进行优化生产调度并结合水资源综合利用实现全行业的清洁生产进行了展望。     

Remote sensing of ocean surface currents with the Seasonde HF radar

The SeaSonde high-frequency radar is a portable, shore-based system for measuring ocean surface currents in real time over coverage areas exceeding 1000 km². It utilizes compact antennas and direction finding methods to extract information on currents from the sea echo signals. Experiments with the radar in sheltered coastal waters in Canada and oceanic conditions in the Pacific Ocean have shown reasonable agreement with drifters and current meters. Forecasting methods have been developed that provide estimates of the slowly varying flows produced by tide, wind and buoyancy, and estimates of the spatially varying eddy diffusivity, based on a few days of measurements. These current data are suitable for use in oil spill models.     

双极膜电渗析技术处理稀土钠皂化废水回收液

采用双极膜电渗析（BMED）技术处理稀土钠皂化废水回收液,使回收液中的氯化钠转化为氢氧化钠溶液（简称碱）和盐酸（简称酸）而回用。考察了电流和初始酸碱浓度对膜对电压、回收的酸和碱的浓度、电流效率和能耗的影响。实验结果表明,随电流的增大,膜对电压升高,回收的酸和碱的浓度也明显增加,电流效率和能耗均提高;随初始酸碱浓度的增加,膜对电压、电流效率和能耗均下降,回收的酸和碱的浓度逐渐增加;综合考虑各方面因素并侧重考虑回收的酸和碱的浓度,本实验适宜的工艺条件为：电流25 A、初始酸碱浓度0.3 mol/L。在此条件下反应150 min,回收酸的浓度为1.24 mol/L,回收碱的浓度为1.55 mol/L。