浙江温州北部地区白垩系地层划分与对比

本文根据温州北部地区的火山-沉积岩地层的剖面,进行了岩石地层、生物地层、年代地层的综合研究和区域对比,针对以往1: 25万、1: 20万和1: 5万区域地质调查的划分和归属提出了新的看法.浙东南下白垩统火山-沉积岩分为上、下两个岩系,下岩系称磨石山群,上岩系称永康群.研究认为,温州北部地区的火山-沉积岩系主体为下白垩统下岩系的磨石山群,并非均为上岩系的永康群馆头组;在永嘉枫林、澄田一带的火山-沉积岩地层分别属于磨石山群大爽组和茶湾组,而桥下一带的沉积岩地层则属于永康群馆头组.     

浙江丽水地区磨石山群火山岩时代归属

为查明浙江丽水地区中生代磨石山群火山岩的时代,在区域地质调查、火山机构划分的基础上,选择该群代表性火山岩进行锆石年龄测定。结果表明,大爽组底部流纹质晶屑熔结凝灰岩的SHRIMP锆石U-Pb年龄为154.9±5.5 Ma、LA-ICP-MS锆石U-Pb加权平均年龄为152.0±7.0 Ma,属晚侏罗世基默里奇阶;高坞组流纹质晶屑熔结凝灰岩SHRIMP锆石U-Pb年龄为131.6±2.7 Ma,两个火山机构的西山头组流纹质晶屑凝灰岩LAICP-MS锆石U-Pb加权平均年龄分别为128.6±1.7 Ma和139.5±2.5 Ma。认为浙南磨石山群火山岩时代:大爽组为晚侏罗世,高坞组、西山头组、茶湾组和九里坪组为早白垩世。     

江西修水县梅子坑钼矿床地质特征及成因初探

梅子坑钼矿位于九岭钨钼成矿带,为中型石英脉型钼矿床.矿区内地层和岩浆岩钼元素含量分别是克拉克值的43倍和21倍.矿体赋存于双桥山群修水组浅变质岩系中及北西向断裂控制的裂隙密集带中;矿石主要类型为石英脉型,矿石有益组分为辉钼矿,形成于石英-黄铁矿-辉钼矿-黄铜矿早期矿化阶段.矿床可能与隐伏的燕山期细粒花岗岩、花岗斑岩岩脉有成因关系,属与燕山期岩浆活动有关的中-高温热液矿床.北西向断裂密集带,硅化、云英岩化、黄铁矿化围岩蚀变,燕山期花岗岩类及双桥山群浅变质岩系,是其主要找矿标志.     

试论浙江建德群和磨石山群时代

根据 8 0年代以来对浙江中生代晚期火山岩同位素年代学的研究资料 ,浙江省建德群和磨石山群火山岩年龄在 135～ 117Ma之间 ,永康群、天台群和衢江群火山岩年龄在 111～90Ma。结合近年来中国东部侏罗—白垩系界线研究的新成果 ,提出浙江建德群和磨石山群时代应为早白垩世     

双桥山群的再讨论

通过对江西西北部及安徽南部地区大面积分布的变质岩的研究,双桥山群仅分布在扬子板块修水—祁门构造单元内,而且是一套史密斯地层。双桥山群可划分为横涌组、计林组、安乐林组及修水组。而不存在非史密斯地层障公山(岩)组。非史密斯地层仅发育于江南混杂岩带中。双桥山群既不同于溪口岩群,也不同于万年群,更不同于张村岩群。     

江苏白垩纪陆相层序地层研究

系统的探讨了区内白垩纪地层的划分与沉积相特征，深入研究了陆相地层的层序发育特征。指出，无论冲积扇、河流、三角洲或湖泊沉积的陆相地层层序均受地层基准面控制。地层基准面穿越旋回控制着陆相环境重大层序分布。根据不同时间间隔的基准面穿越旋回序次，将陆相层序划分为盆地充填层序、构造层序、层序、亚层序及小层序五个级别。每个层序根据基准面波动可划分为基准面上升沉积体系域和基准面下降沉积体系域，并可根据亚层序组的叠置特征进一步细分。根据上述陆相地层层序划分原理，作者将研究区白垩纪陆相地层划分为三个构造层序，并初步将葛村组划分为五个、浦口组四个、赤山组三个和泰州组三个沉积层序。     

浙江治岭头地区火山岩稀土元素地球化学特征及其定量模拟

<正> 研究区位于浙江省西南部,处于东南沿海海西—印支褶皱带绍兴—龙泉隆起带上。区内中、新生代构造活动强烈,岩浆活动频繁,广泛发育侏罗纪火山岩和侵入岩体。其中以侏罗纪磨石山群火山岩为主,它不整合地覆盖在陈     

宁波盆地白垩系古地磁特征兼论馆头组朝川组和方岩组的层位归属

浙东宁波盆地白垩纪陆相火山岩系,经古地磁研究表明,以往认为时代属于早白垩世早期的馆头组,晚期朝川组和晚白垩世早期的方岩组均呈正向磁化,平均磁化方向基本一致。据绝对年龄和古生物旁证,磁化时间属白垩纪中期正向极性超时。因此,馆头组的层位应作相应的提高,从白垩系下部上升到白垩系中部;朝川组随之位于其上。方岩组纳入白垩系中部,在馆头组之下还应有一套以正负极性交迭为特征的白垩纪早期沉积物。从而对以往所谓的上侏罗统磨石山群的时代提出疑问。从古地磁方向特征的规律,支持了白垩系三分说。     

地中海钕的质量平衡

通过测量流入地中海诸河流的微粒、洋底粘土和铁锰皮壳以及大气圈尘埃样品中Nd同位素比值,估价了地中海Nd的质量平衡。波河和罗讷河的∈_(Nd)值分别为-10.8和-9.7,尼罗河、塞伊汉河和塔尔苏斯河则分别为-3.3、-6.2和-6.3。海底粘土和铁锰皮壳的∈_(Nd)值从-2.0变化到-10.1,而尘埃样品为-8.2到-11.0。与大西洋相比(∈_(Nd)=-12),注入地中海海水中相对富放射成因的Nd同位素组成反映了注入海盆的是微粒钕的局部平衡,而不是溶解钕部分。     

东昆仑中段地层学研究的新进展

东昆仑中段是昆仑山地区基础研究的热点,区内地质构造复杂、地层类型多样.对构造混杂岩地层必须坚持活动论思想,采取以反序方法,有助于正确进行构造古地理的恢复.对成层有序的浅变质砂岩、板岩必须摒弃传统做法,即按一个岩系的自然成因单元结构进行.通过对东昆仑中段构造构混杂岩的万保沟岩群研究.获得了洋岛地层序列的新认识,识别了东昆仑中三叠世希里可特组的存在.对巴颜喀拉山群作了许多新研究,对中新世地层取得了重大发现,提出了青藏高原隆升的具体时间和一系列特点.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Removal of heavy metals from sewage sludge by low costing chemical method and recycling in agriculture

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Isolation and preliminary characterization of a 3-chlorobenzoate degrading bacteria

A study was conducted to compare the diversity of 2-, 3-, and 4-chlorobenzoate degraders in two pristine soils and one contaminated sewage sludge. These samples contained strikingly different populations of mono-chlorobenzoate degraders. Although fewer cultures were isolated in the uncontaminated soils than contaminated one, the ability of microbial populations to mineralize chlorobenzoate was widespread. The 3- and 4-chlorobenzoate degraders were more diverse than the 2-chlorobenzoate degraders. One of the strains isolated from the sewage sludge was obtained. Based on its phenotype, chemotaxonomic properties and 16S rRNA gene, the organism S-7 was classified as Rhodococcus erythropolis. The strain can grow at temperature from 4 to 37℃. It can utilize several （halo）aromatic compounds. Moreover, strain S-7 can grow and use 3-chlorobenzoate as sole carbon source in a temperatures range of 10-30℃ with stoichiometric release of chloride ions. The psychrotolerant ability was significant for bioremediation in low temperature regions. Catechol and chlorocatechol 1,2-dioxygenase activities were present in cell free extracts of the strain, but no （chloro）catechol 2,3- dioxygenase activities was detected. Spectral conversion assays with extracts from R. erythropolis S-7 showed accumulation of a compound with a similar UV spectrum as chloro-cis,cis-muconate from 3-chlorobenzoate. On the basis of these results, we proposed that S-7 degraded 3-chlorobenzoate through the modified ortho-cleave pathway.     

Single and joint effects of pesticides and mercury on soil urease

The influence of two pesticides including chlorimuron-ethyl and furadan and mercury （Hg） on urease activity in 4 soils （meadow burozem and phaeozem） was investigated. The soils were exposed to various concentrations of the two pesticides and Hg individually and simultaneously. Results showed that there was a close relationship between urease activity and organic matter content in soil. Chlorimuron-ethyl and furadan could both activate urease in the 4 soils. The maximum increment of urease activity by chlorimuronethyl was up to 14%-18%. There was almost an equal increase （up to 13%-21%） in the urease activity by furadan. On the contrary, Hg markedly inhibited soil urease activity. A logarithmic equation was used to describe the relationship （P〈0.05） between the concentration of Hg and the activity of soil urease in the 4 tested soils. Semi-effect dose （ED50） values by the stress of Hg based on the inhibition of soil urease in the 4 soils were 88, 5.5, 24 and 20 mg/kg, respectively, according to the calculation of the corresponding equations. The interactive effect of chlorimuron-ethyl or furadan with metal Hg on soil urease was mainly synergic at the highest tested concentrations.     

Organochlorine pesticides in soils under different land usage in the Taihu Lake region, China

A field study was conducted in the Taihu Lake region, China in 2004 to reveal the organochlorine pesticide concentrations in soils after the ban of these substances in the year 1983. Thirteen organochlorine pesticides (OCPs) were analyzed in soils from paddy field, tree land and fallow land. Total organochlorine pesticide residues were higher in agricultural soils than in uncultivated fallow land soils. Among all the pesticides, ΣDDX (DDD, DDE and DDT) had the highest concentration for all the soil samples, ranging from 3.10 ng/g to 166.55 ng/g with a mean value of 57.04 ng/g and followed by ΣHCH, ranging from 0.73 ng/g to 60.97 ng/g with a mean value of 24.06 ng/g. Dieldrin, endrin, HCB and α-endosulfan were also found in soils with less than 15 ng/g. Ratios of p,p'-(DDD DDE)/DDT in soils under three land usages were: paddy field ＞ tree land ＞ fallow land, indicating that land usage inlfuenced the degradation of DDT in soils. Ratios of p,p'-(DDD DDE)/DDT ＞1, showing aged residues of DDTs in soils of the Taihu Lake region. The results were discussed with data from a former study that showed very low actual concentrations of HCH and DDT in soils in the Taihu Lake region, but according to the chemical half-lives and their concentrations in soils in 1980s, the concentration of DDT in soils seemed to be underestimated. In any case our data show that the ban on the use of HCH and DDT resulted in a tremendous reduction of these pesticide residues in soils, but there are still high amounts of pesticide residues in soils, which need more remediation processes.     

Alterations of organ histopathology and metallolhionein mRNA expression in silver barb, Puntius gonionotus during subchronic cadmium exposure

Common silver barb,Puntius gonionotus,exposed to the nominal concentration of 0.06 mg/L Cd for 60 d,were assessed for histopathological alterations(gills,liver and kidney),metal accumulation,and metallothionein(MT)mRNA expression.Fish exhibited pathological symptoms such as hypertrophy and hyperplasia of primary and secondary gill lamellae,vacuolization in hepatocytes,and prominent tubular and glomerular damage in the kidney.In addition,kidney accumulated the highest content of cadmium,more than gills and liver.Expression of MT mRNA was increased in both liver and kidney of treated fish.Hepatic MT levels remained high after fish were removed to Cd-free water.In contrast,MT expression in kidney was peaked after 28 d of treatment and drastically dropped when fish were removed to Cd-free water.The high concentrations of Cd in hepatic tissues indicated an accumulation site or permanent damage on this tissue.