福建省梅仙式块状硫化物矿床

梅仙式铅锌矿床是在大陆裂谷环境下形成的，有明显的块状硫化物矿床特征。矿化受震旦系龙北溪组绿片岩控制。矿体里似层状，与围岩产状一致。绿片岩原岩是一套含板内拉斑玄武岩的火山沉积建造。矿物组合和 Ｚｎ／Ｐｂ比值有分带性。层状矿体下盘有脉状、网脉状矿化和蚀变带。矿石有特征的结构构造。硫以幔源为主，铅是幔壳混合成因，矿液以海水成因为主．可能有少量雨水、岩浆水等渗入，反映物质的多来源和成矿受多种地质事件的叠加改造。本式矿床可与火山岩容矿型的加拿大新不伦瑞克省的块状硫化物矿床类比，也可作为广义华南型的一个亚型。     

江西省万载县野猫冲铜矿控矿构造特征及找矿意义

江西省万载县野猫冲铜矿床为中低温热液(成矿流体)沿构造破碎带蚀变-蚀变岩型铜矿床。在地表地质调查、钻孔岩芯考察及岩矿鉴定的基础上,对野猫冲铜矿控矿构造进行详细研究,表明北东东向大型叠瓦状推(滑)覆构造控制矿区内各地质单元的延深与展布,北东向韧性剪切变形带控制矿区铜金矿体的展布,矿体呈似层状赋存于韧性剪切断裂之间的次级层间破碎带和小断裂带内,带内发育较强的动热变质,硅化、绢云母化和绿泥石化发育。矿石以黄铜矿为主,贫硫,成矿流体具有多期次的活动、叠加改造的特点。上栗-潭埠-宜丰断裂带自西至东已发现20余处铜多金属矿床(点),显示该带具有巨大找矿潜力。     

西藏日土县弗野铁矿床地质特征及找矿意义

本文介绍了西藏日土县弗野铁矿的地质背景、矿床地质特征、成矿机制和找矿前景。该矿床矿体产出部位严格受石英闪长岩侵入体与碳酸盐岩层接触带、碳酸盐岩层位及其层间破碎带控制。矿体主要为似层状,容矿岩石主要为矽卡岩、矽卡岩化灰岩。矿石类型简单,主要为磁铁矿矿石。矿化富集与燕山早期石英闪长岩密切相关,矿床类型属矽卡岩型矿床。弗野铁矿床潜在资源量巨大,在其外围地区具有相同类型铁矿床的找矿远景。     

贵州独山锑矿田地质地球化学特征和构造动力热液成矿

独山锑矿田位于独山箱状背斜核部近倾伏端,矿床、矿体的产出严格受断裂控制,其半坡式锑矿呈脉状产于下泥盆统、志留系碎屑岩的陡倾斜断裂中;其巴年式的锑矿呈层状产于中泥盆统碎屑岩与碳酸盐岩之间的层间滑动带中。成矿温度低,矿石组分和围岩蚀变简单,锑主要来源于下伏地层,硫主要来源于赋矿地层．成矿流体主要为大气降水,构造动力成矿作用导致锑矿床的形成,矿床类型为一典型的构过动对热液矿床。     

安徽霍山石英岩玉矿床地质特征与地球物理找矿方法研究

安徽霍山石英岩玉主要呈脉状产于大别岩群英云闪长质片麻岩和燕山期二长花岗岩接触带附近的脆性断裂构造中,由于产出规模小,矿体连续性差,在野外地质勘查中利用电法直接寻找石英岩玉脉具有较大困难。通过勘查石英岩玉脉赋存的硅化构造破碎带,间接了解石英岩玉脉的空间分布,可使电法勘探发挥最大效果。文章分析霍山石英岩玉的矿床地质特征、矿体分布规律及其与围岩的电性差异,结合物探测试成果,认为利用电法勘探查明低阻硅化构造破碎带寻找高阻石英岩玉脉是一种较可行的地球物理找矿方法。     

石英-迪开石型汞矿化的矿物-地球化学特征

<正> 世界上大部分的汞储量和汞产量是来自石英-迪开石型汞矿床。石英-迪开石型汞矿床的特点是:围岩常为厚层陆源沉积岩(呈复合互层状或含有均匀的砂岩层);实际上完全没有喷出岩(辉绿玢岩岩脉除外);控矿构造是被断裂所复杂化的背斜褶皱;矿体为趋于产在褶曲穹部的钟状体、与褶皱弯曲部位破碎带有关的网脉状体以及柱状体、透镜体和细脉等;成矿溶     

广东省揭西金坑铜锡铅锌矿区矿床地质特征与远景预测

广东省揭西金坑矿区目前已初步查明的(333+334) 级矿石量为2245464.8吨,其中金属量Cu:17596.7吨、Sn:5945.3吨、Pb:31536.9吨、Zn:58095.2吨.矿区主要矿体为脉状,均受滑动破碎构造带控制,总体上可分为两种类型:一类分布于灰白色花岗闪长斑岩中,在空间分布上受滑动破碎构造带控制,矿体顶底板为片理化带,蚀变强,呈脉状、透镜状产于花岗闪长斑岩体内的片理化带所产生的滑动破碎带中.另一类则产于石英片岩、粉砂岩、炭质泥岩层间滑动破碎构造带中,主要由多个连续的或间断的扁豆状、透镜体状的矿脉组成.矿体赋存严格受岩层控制,矿脉与围岩界线清楚.本文旨在通过对矿体特征、成矿机理的深入分析,为矿区为进一步扩大资源量提供理论上的启示.     

江西省会昌县淘锡坝大型锡矿床构造控矿机制探讨

淘锡坝锡矿床是近年探明储量达大型的锡矿床,是一种新的锡矿类型-隐爆层间裂隙带型。文章介绍了该矿床的地质特征和矿化特征,对矿区的构造进行了重点解剖,对构造控矿机理进行了探讨,提出火山机构及北东向断裂是矿区的控岩构造,控制了白垩纪成矿花岗岩体的侵入就位。而火山岩中大范围的隐爆层间裂隙带是良好的容矿构造,矿体赋存其中呈似层状,局部膨大形成厚达数十米的"锡矿包"。通过研究构造与矿化富集的内在联系,总结了该矿床的成矿规律。     

呷村超大型银多金属矿床的地球化学特征及找矿远景

1概况呷村银多金属矿床位于松落一甘孜印支把皱系玉树一义效优地槽把皱带中段。矿区出露一套由上三叠统图姆沟组地层组成的近于直立的单判层，8个银多金属矿体呈层状、似层状或透镜状赋存于图姆沟组第二段流纹岩与结晶灰岩接触带及其附近岩石中。矿床规模巨大（银、铅、锌分别为大型矿床的5．44倍、4倍和6倍），有益组分多，多或次多阶段复合叠加成矿作用非常明显，矿床呈点型分布。对呷村矿区除进行了系统的地质研究和施工钻孔坑道外，还采集了521件地球化学分析样品（每件45个元素）。本文主要讨论呷村超大型矿床的地球化学特征。2沉积岩…     

安徽省霍山县东溪-南关岭金矿地质特征与成矿条件

东溪-南关岭金矿为北淮阳东段发现的第一个原生金矿,产于磨子潭-晓天中生代火山盆地边缘,容矿围岩为安山质-英安质火山岩,矿化和蚀变受桐柏-桐城深大断裂带的次级构造带控制。该金矿发育陡倾斜的脉状矿体和缓倾斜的似层状矿体,成因类型为冰长石-绢云母型浅成低温热液金矿。火山岩盆地之下的变质基底可能起到了初始矿源层作用,桐柏-桐城断裂带及其次级构造破碎带为重要的导岩导矿构造,早白垩世强烈的岩浆活动提供了热源、动力源和部分矿源。参照国内外类似金矿的特征,认为本区成矿地质条件良好,有可能隐伏着与石英正长岩体有关的细脉浸染型矿化,晓天火山盆地具有良好的找矿前景。     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

Removal of heavy metals from sewage sludge by low costing chemical method and recycling in agriculture

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Isolation and preliminary characterization of a 3-chlorobenzoate degrading bacteria

A study was conducted to compare the diversity of 2-, 3-, and 4-chlorobenzoate degraders in two pristine soils and one contaminated sewage sludge. These samples contained strikingly different populations of mono-chlorobenzoate degraders. Although fewer cultures were isolated in the uncontaminated soils than contaminated one, the ability of microbial populations to mineralize chlorobenzoate was widespread. The 3- and 4-chlorobenzoate degraders were more diverse than the 2-chlorobenzoate degraders. One of the strains isolated from the sewage sludge was obtained. Based on its phenotype, chemotaxonomic properties and 16S rRNA gene, the organism S-7 was classified as Rhodococcus erythropolis. The strain can grow at temperature from 4 to 37℃. It can utilize several （halo）aromatic compounds. Moreover, strain S-7 can grow and use 3-chlorobenzoate as sole carbon source in a temperatures range of 10-30℃ with stoichiometric release of chloride ions. The psychrotolerant ability was significant for bioremediation in low temperature regions. Catechol and chlorocatechol 1,2-dioxygenase activities were present in cell free extracts of the strain, but no （chloro）catechol 2,3- dioxygenase activities was detected. Spectral conversion assays with extracts from R. erythropolis S-7 showed accumulation of a compound with a similar UV spectrum as chloro-cis,cis-muconate from 3-chlorobenzoate. On the basis of these results, we proposed that S-7 degraded 3-chlorobenzoate through the modified ortho-cleave pathway.     

Single and joint effects of pesticides and mercury on soil urease

The influence of two pesticides including chlorimuron-ethyl and furadan and mercury （Hg） on urease activity in 4 soils （meadow burozem and phaeozem） was investigated. The soils were exposed to various concentrations of the two pesticides and Hg individually and simultaneously. Results showed that there was a close relationship between urease activity and organic matter content in soil. Chlorimuron-ethyl and furadan could both activate urease in the 4 soils. The maximum increment of urease activity by chlorimuronethyl was up to 14%-18%. There was almost an equal increase （up to 13%-21%） in the urease activity by furadan. On the contrary, Hg markedly inhibited soil urease activity. A logarithmic equation was used to describe the relationship （P〈0.05） between the concentration of Hg and the activity of soil urease in the 4 tested soils. Semi-effect dose （ED50） values by the stress of Hg based on the inhibition of soil urease in the 4 soils were 88, 5.5, 24 and 20 mg/kg, respectively, according to the calculation of the corresponding equations. The interactive effect of chlorimuron-ethyl or furadan with metal Hg on soil urease was mainly synergic at the highest tested concentrations.