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1.
    
In this study, a stepwise oxidation system of potassium ferrate (K2FeO4) combined with ozone (O3) was used to degrade ciprofloxacin (CIP). The effects of pH and pre-oxidation time of K2FeO4 on the evolution of K2FeO4 reduction products (iron (hydr)oxides) and CIP degradation were investigated. It was found that in addition to its own oxidation capacity, K2FeO4 can also influence the treatment effect of CIP by changing the catalyst content. The presence of iron (hydr)oxides effectively enhanced the mineralization rate of CIP by catalyzing ozonation. The pH value can influence the content and types of the components with catalytic ozonation effect in iron (hydr)oxides. The K2FeO4 pre-oxidation stage can produce more iron (hydr)oxides with catalytic components for subsequent ozonation, but the evolution of iron (hydr)oxides components was influenced by O3 treatment. It can also avoid the waste of oxidation capacity owing to the oxidation of iron (hydr)oxides by O3 and free radicals. The intermediate degradation products were identified by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS). Besides, the degradation pathways were proposed. Among the degradation products of CIP, the product with broken quinolone ring structure only appeared in the stepwise oxidation system.  相似文献   

2.
    
There are good prospects for phosphorus recovery from excess sludge by vivianite crystallization while a large number of extracellular polymeric substances in sludge will have impact on vivianite precipitation. In this study, as a representative of extracellular polymeric substance, the effect of sodium alginate(SA) on phosphorus recovery by vivianite precipitation under different initial SA concentrations(0–800 mg/L), p H values(6.5–9.0) and Fe/P molar ratios(1:1–2.4:1) was investigated using s...  相似文献   

3.
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Anaerobic digestion (AD) with thermal hydrolysis (TH) pretreatment is a promising process for excess sludge treatment,while there lacks of the knowledge from full-scale process about the impact of sludge composition and characteristics on microbial community and performance.The sludge physiochemical indices,microbial community and performance data of four full-scale TH-AD plants were characterized,and their relationships was elucidated.The four plants were operated under almost similar total org...  相似文献   

4.
    
In recent years,volatile fatty acid(VFA) production through anaerobic fermentation of sewage sludge,instead of methane production,has been regarded as a high-value and promising roadmap for sludge stabilization and resource recovery.This review first presents the effects of some essential factors that influence VFA production and composition.In the second part,we present an extensive analysis of conventional pretreatment and co-fermentation strategies ultimately addressed to improving VFA produc...  相似文献   

5.
Anaerobic digestion(AD)is widely employed for sludge stabilization and waste reduction.However,the slow hydrolysis process hinders methane production and leads to prolonged sludge issues.In this study,an efficient and eco-friendly lysozyme pre-treatment method was utilized to address these challenges.By optimizing lysozyme dosage,hydrolysis and cell lysis were maximized.Furthermore,lysozyme combined with hydrothermal pretreat-ment enhanced overall efficiency.Results indicate that:(1)When lysozyme dosage reached 90 mg/g TS after 240 min of pretreatment,SCOD,soluble polysaccharides,and protein con-tent reached their maxima at 855.00,44.09,and 204.86 mg/L,respectively.This represented an increase of 85.87％,365.58％,and 259.21％compared to the untreated sludge.Three-dimensional fluorescence spectroscopy revealed the highest fluorescence intensity in theⅣ region(soluble microbial product),promoting microbial metabolic activity.(2)Lysozyme combined with hydrothermal pretreatment significantly increased SCOD,soluble proteins,and polysaccharide release from sludge,reducing SCOD release time.Orthogonal experi-ments identified Group 3 as the most effective for SCOD and soluble polysaccharide re-lease,while Group 9 released the most soluble proteins.The significance order of factors influencing SCOD,soluble proteins,and polysaccharide release is hydrothermal tempera-ture＞hydrothermal time＞enzymatic digestion time.(3)The lysozyme-assisted hydrother-mal pretreatment group exhibited the fastest release and the highest SCOD concentration of 8,135.00 mg/L during anaerobic digestion.Maximum SCOD consumption and cumula-tive gas production increased by 95.89％and 130.58％,respectively,compared to the control group,allowing gas production to conclude 3 days earlier.  相似文献   

6.
    
Ethanol-type sludge fermentation has recently attracted much attention because it can enhance direct interspecies electron transfer and thus improve the anaerobic digestion of waste activated sludge(WAS). In this paper, the enhancement of short-term ethanol-type fermentation of WAS via adding Saccharomyces was investigated. The experimental results show that the maximum ethanol production of 1030.8 ± 20.6 mg/L was achieved, with the optimum fermentation conditions of a p H of 5.1, temperature of...  相似文献   

7.
    
To improve methane production from sewage sludge(SS), co-digestion of SS and microalgae(MA) was studied and the application of thermo-alkaline pretreatment to MA was evaluated. The results showed that thermo-alkaline pretreatment at 90°C for 120 min on MA was the optimum pretreatment condition. Furthermore, when the volatile solids(VS) ratio of SS and MA was 1:2, the methane yield reached maximum(368.94 mL/g VS). Fourier transform infrared(FT-IR) and thermogravimetric analysis confirmed the syne...  相似文献   

8.
    
Evaluating anaerobic biodegradability of sludge and then identifying the stabilization of digestate is necessary in sludge treatment and disposal. 48 sludge samples from 24 typical waste water treatment plants (WWTPs) in 11 provinces in China were selected to investigate the relationship between Biochemical Acidogenic Potential (BAP) test and Biochemical Methane Potential (BMP) test. The volatile fatty acid (VFA) production obtained from BAP tests was found linearly related to the ultimate methane production from corresponding BMP tests. Satisfying results were obtained with Pearson correlation coefficient as 0.929 and R2 value as 0.76. Furthermore, the physio-chemical characteristics (FCI, SUVA254, E4/E6) of supernatant, which were associated with humic-like substances (HS), were investigated before and after BMP tests. Through which a new criterion (FCI>1.50, SUVA254>1.10, E4/E6<4.0) was proposed to evaluate the stabilization level of anaerobic digested sludge.  相似文献   

9.
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Ferrihydrite is an important sink for the toxic heavy metal ions, such as Cr(VI). As ferrihydrite is thermodynamically unstable and gradually transforms into hematite and goethite, the stability of Cr(VI)-adsorbed ferrihydrite is environmentally significant. This study investigated the phase transformation of Cr(VI)-adsorbed ferrihydrite at different pH in the presence of aqueous Mn(II), as well as the fate of Mn(II) and Cr(VI) in the transformation process of ferrihydrite. Among the ferrihydrite transformation products, hematite was dominant, and goethite was minor. The pre-adsorbed Cr(VI) inhibited the conversion of ferrihydrite to goethite at initial pH 3.0, whereas little amount of adsorbed Mn(II) favored the formation of goethite at initial pH 7.0. After the aging process, Cr species in solid phase existed primarily as Cr(III) in the presence of Mn(II) at initial pH 7.0 and 11.0. The aqueous Mn concentration was predominantly unchanged at initial pH 3.0, whereas the aqueous Mn(II) was adsorbed onto ferrihydrite or form Mn(OH)2 precipitates at initial pH 7.0 and 11.0, promoting the immobilization of Cr(VI). Moreover, the oxidation of Mn(II) occurred at initial pH 7.0 and 11.0, forming Mn(III/IV) (hydr)oxides.  相似文献   

10.
    
In groundwater, deep soil layer, sediment, the widespread of xenobiotic organic contaminants (XOCs) have been leading to the concern of human health and eco-environment safety, which calls for a better understanding on the fate and remediation of XOCs in anoxic matrices. In the absence of oxygen, bacteria utilize various oxidized substances, e.g. nitrate, sulphate, metallic (hydr)oxides, humic substance, as terminal electron acceptors (TEAs) to fuel anaerobic XOCs degradation. Although there have been increasing anaerobic biodegradation studies focusing on species identification, degrading pathways, community dynamics, systematic reviews on the underlying mechanism of anaerobic contaminants removal from the perspective of electron flow are limited. In this review, we provide the insight on anaerobic biodegradation from electrons aspect — electron production, transport, and consumption. The mechanism of the coupling between TEAs reduction and pollutants degradation is deconstructed in the level of community, pure culture, and cellular biochemistry. Hereby, relevant strategies to promote anaerobic biodegradation are proposed for guiding to an efficient XOCs bioremediation.  相似文献   

11.
    
Chemical speciation can fundamentally affect the potential toxicity and bioavailability of heavy metals. The transformation of heavy metal speciation and change of bioavailability were investigated in an anaerobic digestion (AD) system using four different substrates (pig manure (PM), cattle manure (CAM), chicken manure (CHM) and rice straw (RS)). The results obtained indicated that the total contents of heavy metals in PM, CHM and CAM were higher than in RS and decreased in the order Zn > Cu > Ni > Pb > As > Cd in all substrates. Moreover, the speciation with the largest proportion for each heavy metal was the same both in the different substrates and the biogas residues. Among them, Zn, Ni, Cd and As were mainly in the reducible fraction (F2), while Cu was mainly in the oxidizable fraction (F3) and Pb occurred predominantly in the residual fraction (F4). Our results further indicated that the AD process had a greater effect on the speciation of heavy metals in CHM and PM, but less on CAM and RS. The rates of change in bioavailability followed the order PM > CHM > CAM > RS. Changes in organic matter, humic acid or local metal ion environment as a result of AD were inferred as likely mechanisms leading to the transformation of heavy metal speciation. These results enhanced our understanding of the behavior of heavy metals in AD and provided a new perspective for the treatment and disposal of the substrates.  相似文献   

12.
Tannery sludge with high chromium content has been identified as hazardous solid waste due to its potential toxic effects.The safety disposal and valorization of the tannery sludge remains a challenge.In this study,the chromium stabilization mechanism was systematically investigated during chromium-rich tannery sludge was converted to biochar and the removal performance of the sludge biochar (SBC) for Cr(Ⅵ) from tannery wastewater was also investigated.The results showed that increase in pyrolys...  相似文献   

13.
    
Allelochemicals sustained-release microspheres (ACs-SMs) exhibited great inhibition effect on algae,however,few studies have focused on ACs-SMs toxicity on invertebrate.In this study,the effects of single high-concentration ACs (15 mg/L,SH-ACs),repeated low-concentration ACs (3×5 mg/L,RL-ACs) and ACs-SMs containing 15 mg/L ACs exposure on the ingestion,incorporation,and digestion of Daphnia magna Straus (DS) were investigated by stable isotope15N labeling method.Meanwhile,the diversit...  相似文献   

14.
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Heavy metal(loid)s contamination is a constant issue at smelting sites. It is essential to investigate the spatial distribution and migration characteristics of heavy metal(loid)s in the soil for environmental management and remediation strategies of non-ferrous smelting sites. In this study, 203 soil samples from 57 sites were collected in a typical lead smelting site. The findings demonstrated that there were significant Pb, Zn, Cd, and As contamination in soil samples. The spatial distribution of heavy metal(loid)s showed strong spatial heterogeneity, the contaminated soil areas of Pb, As, Cd, and Zn were 99.5%, 98.9%, 85.3%, and 72.4%, respectively. Pb, Cd, and As contamination of the soil reached a depth of 5 m, which migrated from the surface to deep soil layers. The leaching contents of Zn, Pb, and As decreased obviously in 3-4 m soil layer, but the leaching content of Cd was still high, which indicated the high migration of Cd. With the increase of depth, the proportion of acid soluble fraction of heavy metal(loid)s decreased, and the residual fraction increased. The acid soluble fraction of Cd accounted for a higher proportion, and As mainly existed in reducible and residual fractions in soil. According to the calculation of the migration factor, the migration of heavy metal(loid)s in soils were ordered as Cd > Zn > Pb > As. The outcomes are advantageous for risk reduction and site remediation for non-ferrous metal smelting sites.  相似文献   

15.
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Resource recycling from waste-water and sludge is an important part of the 14th Five-Year Plan in China. The emerging titanium-based coagulants have drawn growing attentions due to their strong coagulation capability in water purification and value-added Ti-loaded sludge production. Management and recovery of the high value-added sludge into functional nanomaterials is highly significant for both sludge reduction and environmental remediation.The present study was carried out to investigate the ...  相似文献   

16.
    
Phosphorus is a vital nutrient for algal growth, thus, a better understanding of phosphorus availability is essential to mitigate harmful algal blooms in lakes. Wind waves are a ubiquitous characteristic of lake ecosystems. However, its effects on the cycling of organic phosphorus and its usage by phytoplankton remain poorly elucidated in shallow eutrophic lakes. A mesocosm experiment was carried out to investigate the responses of alkaline phosphatase activity fractions to wind waves in large, shallow, eutrophic Lake Taihu. Results showed that wind-driven waves induced the release of alkaline phosphatase and phosphorus from the sediment, and dramatically enhanced phytoplanktonic alkaline phosphatase activity. However, compared to the calm conditions, bacterial and dissolved alkaline phosphatase activity decreased in wind-wave conditions. Consistently, the gene copies of Microcystis phoX increased but bacterial phoX decreased under wind-wave conditions. The ecological effects of these waves on phosphorus and phytoplankton likely accelerated the biogeochemical cycling of phosphorus and promoted phytoplankton production in Lake Taihu. This study provides an improved current understanding of phosphorus availability and the phosphorus strategies of plankton in shallow, eutrophic lakes.  相似文献   

17.
    
The migration mechanisms, sources, and environmental risks of 29 legacy and emerging perfluorinated and polyfluoroalkyl species present in an oxidation pond (Ya'Er Lake) were investigated for treating sewage based on the analysis of their occurrence and distribution. The concentration of per- and polyfluoroalkyl substances (PFAS) in pond area was between 0.30 and 63.2 ng/g dw (dry weight), with the overall average concentration of 8.00 ng/g dw. Notably, the PFAS concentrations in the surface sediments near the sewage outlet in Pond-1 (50.2 ng/g dw) and Pond-5 (average 15.1 ng/g dw) were 1–2 orders of magnitude higher than those in other areas. In general, the legacy PFAS, i.e., perfluorooctane sulfonic acid was considered to be the major pollutant in the polluted area, on average, accounting for 73.0% of the total concentration of PFAS pollutants. By evaluating the regional distribution of different PFAS homologs, the short-chain PFAS pollutants with lower Kow were found to migrate farther in both horizontal and vertical directions. The sewage outlets in Pond-1 and Pond-5 are the main pollution sources in polluted area and the emerging PFAS pollutants in Pond-5 have replaced the legacy PFAS pollutants as the main pollutants. Based on positive matrix factorization analysis, three main industrial sources of PFAS pollutants in the study area were identified: protective coating, fire-fighting, and food packaging sources. Moreover, the environmental risk assessment results showed that most study areas exhibited medium environmental risk (0.01 ≤ Risk quotient (RQ) < 1), indicating that the ecological environment risks in this area need further attention.  相似文献   

18.
    
Citrate (Ct) was chosen as a typical chelator used in the Fe2+-peroxydisulfate (PDS) process to improve sludge dewaterability.The PDS-Fe2+-Ct process exhibited better performance in sludge dewatering than PDS-Fe2+.Specifically,with a PDS dosage of 1.2 mmol/g VS,the molar ratio of PDS/Fe2+and Ct/Fe2+were 4:5 and 1:4,respectively,the capillary suction time decreased from 155.8 to 24.8sec,and the sludge cake water content decreased from 82.62%t...  相似文献   

19.
    
Lignin is a common soil organic matter that is present in soils, but its effect on the transformation of ferrihydrite (Fh) remains unclear. Organic matter is generally assumed to inhibit Fh transformation. However, lignin can reduce Fh to Fe(II), in which Fe(II)-catalyzed Fh transformation occurs. Herein, the effects of lignin on Fh transformation were investigated at 75°C as a function of the lignin/Fh mass ratio (0-0.2), pH (4-8) and aging time (0-96 hr). The results of Fh-lignin samples (mass ratios = 0.1) aged at different pH values showed that for Fh-lignin the time of Fh transformation into secondary crystalline minerals was significantly shortened at pH 6 when compared with pure Fh, and the Fe(II)-accelerated transformation of Fh was strongly dependent on pH. Under pH 6, at low lignin/Fh mass ratios (0.05-0.1), the time of secondary mineral formation decreased with increasing lignin content. For high lignosulfonate-content material (lignin:Fh = 0.2), Fh did not transform into secondary minerals, indicating that lignin content plays a major role in Fh transformation. In addition, lignin affected the pathway of Fh transformation by inhibiting goethite formation and facilitating hematite formation. The effect of coprecipitation of lignin on Fh transformation should be useful in understanding the complex iron and carbon cycles in a soil environment.  相似文献   

20.
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As a frequently used product with antimicrobial activity, consumed allicin might be discharged and concentrated in waste-activated sludge (WAS). However, the influence of allicin (as an exogenous pollutant) on WAS fermentation has not been clearly revealed. This study aimed to disclose the impacts of allicin on volatile fatty acid (VFA) generation during WAS fermentation. The results showed that the appropriate presence of allicin (10 mg/g TSS) significantly enhanced the VFA yield (1894 versus 575 mg COD/L in the control) with increased acetate proportion (24.3%). Further exploration found that allicin promoted WAS solubilization, hydrolysis and acidification simultaneously. Metagenomic analysis revealed that the key genes involved in extracellular hydrolysis metabolism (i.e., CAZymes), membrane transport (i.e., gtsA and ytfT), substrate metabolism (i.e., yhdR and pfkC) and fatty acid synthesis (i.e., accA and accD) were all highly expressed. Allicin also induced the bacteria to produce more signalling molecules and regulate cellular functions, thereby enhancing the microbial adaptive and regulatory capacity to the unfavourable environment. Moreover, the variations in fermentative microbes and their contributions to the upregulation of functional genes (i.e., ytfR, gltL, INV, iolD and pflD) for VFA generation were disclosed. Overall, the simultaneous stimulation of functional microbial abundances and metabolic activities contributed to VFA production in allicin-conditioned reactors.  相似文献   

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