Plutonium isotopes in the Hungarian environment

More than 50 soil samples were analysed from different parts of the country, the activity concentration of 239+240Pu was in the range of 0.01-0.84 Bq/kg dry soil with the average of 0.10 Bq/kg. 238Pu could be detected only in few moss samples and 238Pu/239+240Pu ratio determines the origin of plutonium. 241Pu was determined by liquid scintillation spectrometry. The activity concentration of this isotope in the soil is between 0.04 and 3.74 Bq/kg with the average of 0.82 Bq/kg, while in the moss is also similar 0.01-2.07 Bq/kg fresh mass with the average of 0.43 Bq/kg. Significant difference could not be observed between the different types of soils occurring in the country, but the results could be sorted according to the sampling carried out on undisturbed or cultivated area. The isotope ratios 241Pu/239+240Pu prove that the origin of the plutonium in Hungary is the global fallout determined by the atmospheric nuclear weapon tests.     

Plutonium isotopes concentration in seawater and bottom sediment off the Pacific coast of Aomori sea area during 1991-2005

A radioactivity survey was launched in 1991 to determine the background levels of ^239+240Pu in the marine environment off a commercial spent nuclear fuel reprocessing plant before full operation of the facility. Particular attention was focused on the ²⁴⁰Pu/²³⁹Pu atom ratio in seawater and bottom sediment to identify the origins of Pu isotopes. The concentration of ^239+240Pu was almost uniform in surface water, decreasing slowly over time. Conversely, the ^239+240Pu concentration varied markedly in the bottom water and was dependent upon the sampling point, with higher concentrations of ^239+240Pu observed in the bottom water sample at sampling points having greater depth. The ²⁴⁰Pu/²³⁹Pu atom ratio in the seawater and sediment samples was higher than that of global fallout Pu, and comparable with the data in the other sea area around Japan which has likely been affected by close-in fallout Pu originating from the Pacific Proving Grounds. The ²⁴⁰Pu/²³⁹Pu atom ratio in bottom sediment samples decreased with sea depth. The land-originated Pu is not considered as the reason of the increasing ^239+240Pu concentration and also decreasing the ²⁴⁰Pu/²³⁹Pu atom ratio with sea depth, and further study is required to clarify it.     

Distribution of uranium isotopes in surface water of the Llobregat river basin (Northeast Spain)

A study is presented on the distribution of ²³⁴U, ²³⁸U, ²³⁵U isotopes in surface water of the Llobregat river basin (Northeast Spain), from 2001 to 2006. Sixty-six superficial water samples were collected at 16 points distributed throughout the Llobregat river basin. Uranium isotopes were measured by alpha spectrometry (PIPS detectors). The test procedure was validated according to the quality requirements of the ISO17025 standard. The activity concentration for the total dissolved uranium ranges from 20 to 261 mBq L⁻¹. The highest concentrations of uranium were detected in an area with formations of sedimentary rock, limestone and lignite. A high degree of radioactive disequilibrium was noted among the uranium isotopes. The ²³⁴U/²³⁸U activity ratio varied between 1.1 and 1.9 and the waters with the lowest uranium activity registered the highest level of ²³⁴U/²³⁸U activity ratio. Correlations between uranium activity in the tested water and chemical and physical characteristics of the aquifer were found.     

Australian firefighters' exposure to air toxics during bushfire burns of autumn 2005 and 2006

Bushfire fighting is a hazardous occupation and control strategies are generally in place to minimize the hazards. However, little is known regarding firefighters' exposure to bushfire smoke, which is a complex mixture of toxic gases and particles. In Australia, during the prescribed burning season, firefighters are likely to be exposed on a regular basis to bushfire smoke, but whether these exposures affect health has yet to be determined. There are a number of factors that govern whether exposure to smoke will result in short-term and/or long-term health problems, including the concentrations of air pollutants within the breathing zone of the firefighter, the exposure duration, and health susceptibility of the individual, especially for pre-existing lung or heart disease. This paper presents measurements of firefighters' personal exposure to bushfire smoke, the first step within a risk management framework. It provides crucial information on the magnitude, extent and frequency of personal exposure to bushfire smoke for a range of typical scenarios. It is found that the primary air toxics of concern are carbon monoxide (CO), respirable particles and formaldehyde. Also, work activity is a major factor influencing exposure with exposure standards (both average and short-term limits) likely to be exceeded for activities such as suppression of spot fires, holding the fireline, and patrolling at the edge of a burn area in the urban-rural interface.     

Associations between PBDEs in office air,dust, and surface wipes

Increased use of flame-retardants in office furniture may increase exposure to PBDEs in the office environment. However, partitioning of PBDEs within the office environment is not well understood. Our objectives were to examine relationships between concurrent measures of PBDEs in office air, floor dust, and surface wipes.We collected air, dust, and surface wipe samples from 31 offices in Boston, MA. Correlation and linear regression were used to evaluate associations between variables. Geometric mean (GM) concentrations of individual BDE congeners in air and congener specific octanol–air partition coefficients (K_oa) were used to predict GM concentrations in dust and surface wipes and compared to the measured concentrations.GM concentrations of PentaBDEs in office air, dust, and surface wipes were 472 pg/m³, 2411 ng/g, and 77 pg/cm², respectively. BDE209 was detected in 100% of dust samples (GM = 4202 ng/g), 93% of surface wipes (GM = 125 pg/cm²), and 39% of air samples. PentaBDEs in dust and air were moderately correlated with each other (r = 0.60, p = 0.0003), as well as with PentaBDEs in surface wipes (r = 0.51, p = 0.003 for both dust and air). BDE209 in dust was correlated with BDE209 in surface wipes (r = 0.69, p = 0.007). Building (three categories) and PentaBDEs in dust were independent predictors of PentaBDEs in both air and surface wipes, together explaining 50% (p = 0.0009) and 48% (p = 0.001) of the variation respectively. Predicted and measured concentrations of individual BDE congeners were highly correlated in dust (r = 0.98, p < 0.0001) and surface wipes (r = 0.94, p = 002). BDE209 provided an interesting test of this equilibrium partitioning model as it is a low volatility compound.Associations between PentaBDEs in multiple sampling media suggest that collecting dust or surface wipes may be a convenient method of characterizing exposure in the indoor environment. The volatility of individual congeners, as well as physical characteristics of the indoor environment, influence relationships between PBDEs in air, dust, and surface wipes.     

Describing the annual cyclic behaviour of 7Be concentrations in surface air in Oceania

Surface air concentrations of (7)Be at a number of stations in Oceania show a distinct annual cycle. We apply a sinusoidal model to describe this cycle. The results show that peak (7)Be concentrations in surface air occur during early spring at tropical latitudes and during mid-to-late summer at middle latitudes. Comparison with available (90)Sr surface air data for the southern hemisphere indicates that stratosphere-to-troposphere exchange is an active atmospheric process controlling the (7)Be annual cycle throughout the Oceania region. Vertical transport of air within the troposphere also seems to influence the observed annual cycle. Seasonality in rainfall is not thought to control the annual cyclic behaviour of (7)Be in surface air.     

Inverse modeling of Asian Rn flux using surface air Rn concentration

When used with an atmospheric transport model, the ²²²Rn flux distribution estimated in our previous study using soil transport theory caused underestimation of atmospheric ²²²Rn concentrations as compared with measurements in East Asia. In this study, we applied a Bayesian synthesis inverse method to produce revised estimates of the annual ²²²Rn flux density in Asia by using atmospheric ²²²Rn concentrations measured at seven sites in East Asia. The Bayesian synthesis inverse method requires a prior estimate of the flux distribution and its uncertainties. The atmospheric transport model MM5/HIRAT and our previous estimate of the ²²²Rn flux distribution as the prior value were used to generate new flux estimates for the eastern half of the Eurasian continent dividing into 10 regions.The ²²²Rn flux densities estimated using the Bayesian inversion technique were generally higher than the prior flux densities. The area-weighted average ²²²Rn flux density for Asia was estimated to be 33.0 mBq m⁻² s⁻¹, which is substantially higher than the prior value (16.7 mBq m⁻² s⁻¹). The estimated ²²²Rn flux densities decrease with increasing latitude as follows: Southeast Asia (36.7 mBq m⁻² s⁻¹); East Asia (28.6 mBq m⁻² s⁻¹) including China, Korean Peninsula and Japan; and Siberia (14.1 mBq m⁻² s⁻¹). Increase of the newly estimated fluxes in Southeast Asia, China, Japan, and the southern part of Eastern Siberia from the prior ones contributed most significantly to improved agreement of the model-calculated concentrations with the atmospheric measurements. The sensitivity analysis of prior flux errors and effects of locally exhaled ²²²Rn showed that the estimated fluxes in Northern and Central China, Korea, Japan, and the southern part of Eastern Siberia were robust, but that in Central Asia had a large uncertainty.     

Plutonium in sheep faeces as an indicator of deposition on vegetation

In order to study the deposition on vegetation of plutonium arising from the testing of nuclear weapons and discharges from nuclear facilities, sheep faeces were collected from the South-west and North of England. The plutonium content of faeces has been shown to be a reproducible and sensitive indicator of deposition on herbage and, with this technique, plutonium discharged from the Sellafield Works of British Nuclear Fuels LImited can be detected 60 km from the site. On moorland pastures the concentration of ^239+240Pu in faeces, expressed as activity per gram of ash, is roughly equal numerically to the deposit of plutonium on 1 m² of vegetation.Some of the plutonium ingested by a grazing sheep is absorbed and the highest concentrations are found in liver. The liver of a sheep grazing on pasture where the ^239+240Pu concentration in faeces was about 2 pCi (74 mBq) g⁻¹ of ash, was found to contain <1% of the Generalised Derived Limit for mutton and offal, and the meat <0·001%.     

美国环保署战略计划(2006-2011)述评

美国作为当今世界上经济最发达的国家,在其发展过程中也曾经历过长时间的严重污染阶段,通过数十年的不断努力,目前美国已经成为生态环境质量最好的国家之一。深入研究美国的环境保护政策和工作计划,对于我国当前和今后一段时间内环境保护工作具有重要借鉴意义。2006年9月,美国国家环保署发布了"环保署战略计划(2006-2011)"(2006-2011 EPA Strategic Plan),结合美国环境现状和前期工作基础,提出了未来五年发展目标和实现这些目标的途径,用于指导美国环保署未来五年的工作。本文对美国环保署2006年发布的战略计划背景、内容及美国环保署的职能进行了简要介绍和分析,对其成功做法进行了初步归纳,总结了其在科学研究、标准制定、系统管理及全方位控制、新型污染物控制、合作伙伴关系建立等方面的成功经验,希望能够对我国环境保护政策和环保科技发展战略研究提供有益的参考。     

中国石油安全战略评价:1990-2006

为促进国民经济的健康持续发展和国家石油安全,本文试图对中国的石油安全状况进行系统评价,为国家的石油生产和合理利用提供参考。文章从石油供给稳定和使用安全两个角度出发,构建了中国石油安全的战略评价指标体系,利用灰色关联分析方法建立了中国石油安全战略评价模型,并对1990-2006年的时间序列数据进行了实证研究。研究结果表明,中国石油安全水平呈现波动性缓慢上升的趋势。这归因于石油生产效应、石油经济效应和能源技术效应的共同作用,以及其所产生的中国石油供给稳定水平的平稳提高。同时,以GDP节能所主导的环境保护效应的波动性缓慢增强,冲击了人文效应在石油使用安全中的稳定性作用,导致了石油使用安全以及中国石油安全水平的短期波动。从经济增长、石油供给、技术进步、环境保护和人文发展的角度综合考虑中国石油安全的影响因素与发展趋势,并促进其良性作用机制的形成,是保障中国石油安全的重要途径。     

Discharge of 137Cs and 90Sr by Finnish rivers to the Baltic Sea in 1986-1996

The total amounts of 137Cs and 90Sr transported from Finland by rivers into the Gulf of Finland, Gulf of Bothnia and Archipelago Sea since 1986 were estimated. The estimates were based on long-term monitoring of 137Cs and 90Sr in river and other surface waters and on the statistics of water discharges from Finnish rivers to the above sub-areas of the Baltic Sea. The total amounts of 137Cs and 90Sr removed from Finland into the Baltic Sea during 1986-1996 were estimated to be 65 and 10 TBq, respectively. The results show that, although the deposition of 137Cs was much higher than that of 90Sr after the Chernobyl accident, the amount of 137Cs removed from Finland is only six times as high as that of 90Sr. This emphasizes the importance of 90Sr while considering radiation doses from surface waters and 137Cs while estimating doses via pathways from catchment soil, lake sediments and biota after a fallout situation.     

Seasonal 7Be and 137Cs activities in surface air before and after the Chernobyl event

Seasonal fluctuations of cosmogenic (7)Be (T(1/2)=53.4 days) and anthropogenic (137)Cs (T(1/2)=30 years) activities in surface air (aerosols) have been extracted from a long data record (1972-2000) at high latitude (56 degrees N-68 degrees N, Sweden). Normalization to weekly average values was used to control long-term trends so that cyclical trends could be investigated. Enhanced (7)Be activity was observed in spring and summer seasons and likely relates to the seasonal thinning of the tropopause. Variations in the (137)Cs activity record seem to reflect how the isotope was injected in the atmosphere (stratospheric from bomb tests and tropospheric from the Chernobyl accident) and subsequent transport mechanisms. Accordingly, until 1986, the surface air (137)Cs activity was strongly related to nuclear weapons test fallout and exhibits temporal fluctuations resembling the (7)Be. Conversely, since 1986 the Chernobyl-produced (137)Cs dominates the long-term record that shows annual cycles that are strongly controlled by atmospheric boundary layer conditions. Additionally, short-term data within the post-Chernobyl period suggest subtle intrusion of air masses rich in (137)Cs that may occur throughout the year, and differences resulting from spatial occurrence at these latitudes. This is an important observation that may have to do with year-to-year variation and calls for caution when interpreting short-term data records.     

Time trends (1986-2003) of radiocesium transfer to roe deer and wild boar in two Austrian forest regions

Starting shortly after the Chernobyl accident, samples of roe deer and wild boar from two comparatively highly contaminated Austrian forest stands have been regularly analysed for (137)Cs. Until 1995 average (137)Cs concentrations exceeded 1000 Bq kg(-1) in both roe deer and wild boar. Long-term and seasonal trends are similar in both investigation sites. While (137)Cs aggregated transfer factor (T(ag)) values show a significant decreasing trend in roe deer (ecological half-time 8.6 and 7.2 years, respectively), T(ag)-values in wild boar are highly variable, but rather increasing values are observed over the last years. T(ag)-values for roe deer are between 0.04 and 0.008 m(2)kg(-1) fresh weight (1987-2003); values for wild boar are between 0.008 m(2)kg(-1) (1988) and 0.046 m(2)kg(-1) (1996) fresh weight. Seasonal trends for both species are in good agreement with observations from German forests: increased mushroom ingestion leads to higher (137)Cs T(ag)-values for roe deer in the second half of the year (August-December) compared to the first half (January-July). T(ag)-values for wild boar are highest in the first half of the year.     

行政问责与政策行为从众:“十一五”节能目标实施进度地区间差异考察

研究引入"政策行为从众"的概念,并通过实证证明,作为超常规政治激励手段的行政问责制,会在不同类型的政策执行主体中产生"政策行为从众"的行为模式,而不能在整体上提高所有政策执行主体的执行水平。具体的来说,政策实施初期执行进度较慢的省份将在行政问责的压力下强化政策实施力度以实现赶超,但初期执行进度较快的省份将在后期主动弱化实施力度。不同执行的主体的"从众"行为将在整体上减弱行政问责制的政策效果,并在客观上导致节能约束性指标打折扣。本文建议应在完善问责制的基础上,综合采用财政与税收奖励等激励性手段,提高地方对节能减排等国家政策的"自发性"实施意愿,构建自我强化的政策实施长效机制。     

Occurrence and distribution of organochlorine pesticides - lindane, p,p'-DDT, and heptachlor epoxide - in surface water of China

Persistent organochlorine pesticides pollutants (OCPs) have been reported to occur at relatively high concentrations in some Chinese waters. In order to map the distribution of organochlorine pesticides in the surface water throughout China, samples were collected from over 600 sites in seven major river basins and three main internal rivers drainage areas during 2003 and 2004. The surface water samples were analyzed for the representative organochlorine pesticides contaminants including lindane (gamma-HCH), p,p'-DDT and heptachlor epoxide. In general, the most frequently detected compound was lindane, being detected in 83.9% of samples (mean=31.3 ng/l; range <0.17-860 ng/l), and the highest concentration was present in the Yellow River basin. p,p'-DDT was detected in 63.1% of the samples collected (mean=14.6 ng/l; range <0.14-368 ng/l) with the highest concentration present in the Huaihe River basin. Heptachlor epoxide was detected in only 9.3% of water samples (range <0.11-10 ng/l). Measured concentrations for the three compounds were low and rarely exceed the environment quality standard for surface water of China. Lindane was more frequently detected at much higher concentrations in the rivers of northern China compared with those of southern China. The sites with higher concentration of lindane and p,p'-DDT mainly occurred in the Yellow River and Huaihe River basins, so the results of this investigation indicate that the organochlorine pesticide contamination of Yellow River and Huaihe River basins should be of particular concern relative to the other basins. When compared with other regions of the world, it appears that the Chinese surface water is moderately polluted by lindane and p,p'-DDT.     

Mutagenic properties of PM2.5 air pollution in the Padana Plain (Italy) before and in the course of XX Winter Olympic Games of "Torino 2006"

PM2.5 is one of the most important aspects of environmental health. This air pollutant is breathable and it is implicated in several chronic adverse health effects such as the decrease of respiratory functionality and cancer. Several in vitro bioassays are able to predict the mutagenic/carcinogenic activity of the environmental pollutants and mixtures of them. In this study PM2.5 air pollution was daily monitored in three cities located in the Northern part of Italy and the mutagenic properties of the PM2.5 organic extracts were also assessed. Samplings lasted 14 months and cover the period of the Winter Olympic Games of "Torino 2006". In this work, the levels of PM2.5, its mutagenic properties (detected with Salmonella typhimurium assay), the role of the Olympic Games as environmental factor and some meteorological data are discussed. The mean concentration of PM2.5 measured in Torino was 45.4 (+/-30.6) microg/m(3), in Pavia 37.6 (+/-25.6) microg/m(3), in Verona 43.1 (+/-28.5) microg/m(3). Findings of the monthly pool bioassay were in Torino 107 (+/-104) net revertans/m(3), in Pavia 108 (+/-89) net revertans/m(3), in Verona 128 (+/-109) net revertans/m(3). The Olympic Games period data show that PM2.5 pollution and its load of mutagenic potential are different and partially independent phenomena. The Olympic Games had not a great impact on the PM2.5 pollution. The exclusive PM2.5 gravimetric analysis shows a potential human risk if compared with the latest international guide values but it does not describe exhaustively the human health risk associated to the presence of this particular air pollutant. Moreover, the chemical and biological activity qualification of the PM organic extracts as a whole, can instead improve the knowledge.     

Detailed Ecological Footprint Accounting of Liaoning in 2006

Ecological footprint （EF） has received considerable attention as a useful indicator in the context of sustainable development. So far, EF has been used in numerous studies by academies, organizations and government authorities. However, the results of these studies failed to be comparable directly with each other due to imprecise data sets, unmodified accounting methods of pasture and fossil energy, ignored secondary products, undefined process Of calculating yield factors and improper biocapacity for biodiversity. In this paper, we elaborated on EF estimating methods from six categories of consumption in order to overcome the limitations above. We adopted precise data and revised methods, calculated EF of some secondary products, introduced weighted factor to calculate yield factors and adjusted biocapacity by an appropriate amount. Meanwhile, we investigated the resource consumption of Liaoning Province in 2006 to assess EF. Its results showed that Liaoning Province overused its natural capital and was in an unsustainable state. We concluded that two specific problems that had arisen in EF assessment and gave some suggestions for Liaoning Province to improve its unsustainable state.     

Detailed Ecological Footprint Accounting of Liaoning in 2006

Abstract

Ecological footprint (EF) has received considerable attention as a useful indicator in the context of sustainable development. So far, EF has been used in numerous studies by academies, organizations and government authorities. However, the results of these studies failed to be comparable directly with each other due to imprecise data sets, unmodified accounting methods of pasture and fossil energy, ignored secondary products, undefined process of calculating yield factors and improper biocapacity for biodiversity. In this paper, we elaborated on EF estimating methods from six categories of consumption in order to overcome the limitations above. We adopted precise data and revised methods, calculated EF of some secondary products, introduced weighted factor to calculate yield factors and adjusted biocapacity by an appropriate amount. Meanwhile, we investigated the resource consumption of Liaoning Province in 2006 to assess EF. Its results showed that Liaoning Province overused its natural capital and was in an unsustainable state. We concluded that two specific problems that had arisen in EF assessment and gave some suggestions for Liaoning Province to improve its unsustainable state.     

Spatial distribution of U isotopes in sea-water sediments, Red Sea, Egypt

Isotopes of uranium in the sea-water sediments collected from two different areas (El Hamraween harbour and Ras El Behar) on the Egyptian coast of the red sea have been studied using radiochemical separation procedures and alpha-particle spectrometry. Activity concentrations of ²³⁸U, ²³⁵U, ²³⁴U were calculated. The activities observed indicated enhanced radioactivity levels in sea-water sediments of El Hamraween harbour area due to the activities of phosphate shipment operation. Secular equilibrium between ²³⁴U and ²³⁸U was found in the analyzed samples. The average activity ratio of ²³⁵U/²³⁸U was close to the value 0.046 for uranium in nature.