电厂温排水热污染防治对策初探

火、核电厂排放的循环冷却水是工业温排水中最大的热排放源。论述了火、核电厂温排水向其受纳环境水域释放的巨大热量，以及热排放对环境水域水体的理化性质及生态系统的热影响；提出采用热泵等高技术手段回收回用此余热使污源减排是治理受纳水域水生态环境，修复水域环境热容量最根本、最有效的措施；同时建议修订我国水质标准（规范）中对水温的规定，以切实加强水域热排放的有效管理。在新世纪和谐电力建设进程中，电厂循环冷却水余热高效利用不仅有明显的环境保护意义，而且在电厂节能提效，实现温排水资源化中也将有重大的经济和社会效益。     

Analysis of priority pollutants at a primary aluminum production facility

This paper investigated the source of priority pollutants, assessment of the wastewater treatment plant, and priority pollutant removal efficiency for a single Soderberg-type primary aluminum plant.Forty-eight hour composite samples were collected from the following streams: (1) plant intake water; (2) wastewater from the primary air pollution control system (gas stream cooling water and wet ESPs); (3) secondary air pollution control system (room ventilation wet scrubber liquor); (4) paste plant briquette cooling water; and (5) final effluent after the wastewater treatment plant.Wastewater from the primary air pollution control system entered a conventional chemical coagulation (using slacked lime) — clarification plant. Clarified water from the clarifier was combined with the other three wastewater streams and flowed into a settling lagoon with a 20-h hydraulic retention time. Clarified lagoon water was finally discharged to the river.The principal source of organic compounds in the wastewater was from the primary and secondary air pollution control systems and results from the volatilization of petroleum coke and pitch in the Soderberg anode. Wastewater treatment plant removal efficiencies of greater than 85% were achieved for the majority of the organic priority pollutant species detected.     

溪洛渡水电站叠梁门取水方式减缓下泄低温水的优化调度

大型水库常采用叠梁门取水方式作为改善春季下泄低温水的有效手段,但现有的叠梁门调度方式基本为全年使用,可能加剧水库冬季下泄高温水现象,且影响到春季的水温改善效果。提出根据下游鱼类对水温的需求时段来确定叠梁门的启用时段,对金沙江下游的溪洛渡电站水库水温进行了研究,结果表明,分时段采用叠梁门取水可有限程度地提高春季的下泄水温并避免冬季下泄水高温现象的进一步加剧。同时,也研究了河流梯级开发对叠梁门应用的影响,发现水库调节性能、梯级开发、人工调度等带来的下游入库水温平坦化,以及溪洛渡水库的过渡型水温结构,使叠梁门对水温的影响显著减弱.     

乌东德水库水温预测及低温水减缓措施

乌东德水库为季调节水库,采用宽度平均的立面二维水温数学模型对水库水温结构进行预测,结果表明:乌东德水库水温结构呈季节性分层特征,电站运行对下游水温过程有一定程度的春季低温水和冬季高温水影响。如果采用单层取水方案,在2~8月的下泄水温低于坝址现状水温,最大降幅为2.0℃,下泄低温水将对坝下鱼类产卵繁殖产生不利影响。乌东德水电站拟采取分层取水的措施,对低温水较为敏感的鱼类产卵期3~6月采用叠梁门取水。相比于单层取水,叠梁门方案对低温水的改善效果较明显,下泄水温提高了0.8~1.1℃,能一定程度地减缓升温期水温延迟效应。     

梯级水库叠梁门分层取水水温改善效果的衰减

分层取水是国内目前改善水库下泄低温水不利影响的重要工程措施。为明确叠梁门分层取水措施在梯级水库开发河段的衰减效果,以金沙江下游4个梯级水库为研究对象,采用宽度平均的立面二维水温数学模型,定量研究梯级水库联合调度条件下上游水库采取分层取水措施后对下游水库水温的影响。结果表明：乌东德水库采用叠梁门取水对改善低温水效果有限,白鹤滩水库采用叠梁门取水后下泄低温水现象得到明显缓解;对于白鹤滩下游溪洛渡和向家坝的下泄低温水,受白鹤滩分层取水影响的改善效果略有减弱,其中向家坝4、5月下泄水温可升高0.8℃和1.0℃。乌东德采用叠梁门取水对改善溪洛渡和向家坝下泄水温几乎没有影响;在梯级水电开发中,分层取水措施应尽可能实施在强调节能力水库上。     

南通市水污染控制与规划研究

南通市域内水环境形势恶化,未来有加剧趋势,其根本原因在于十分有限的水环境容量与逐年加重的水污染负荷之间的矛盾。针这一根本原因,提出南通市水污染控制规划的两点基本思路;一是消减污染负荷,是二是调整负荷的空间分布,确定了控制规划的基本思想;污水控制导流清污分开原则,采用生态工程与二级污水处理厂相结合而以生态为主导的污水多元集中处理原则,环境容量跨水域平衡原则。基于这一,构建了南通市水污染控制方案;南通     

向家坝水库水温时空特征及其成因分析

水温是水环境评价的重要因子之一,其对水生态系统中的物理、化学和生物过程起着重要作用。为了分析向家坝水库运行期内的水温分布特征及其成因,本文建立CE-QUAL-W2立面二维水温模型,并基于2014年野外原位监测水温数据对模型可靠性进行了验证,应用其对水温分布进行数值模拟。研究发现向家坝水库水温存在季节性垂向分层,4~6月中上层水体(水深0~60 m)受入流水温和气温回升影响迅速升温,表底温差达10℃,垂向分层加剧;7、8月水库泄洪加快了库区水体交换,底层水温迅速升高,中间等温层水体厚度增加,表底温差减小在2℃内,9月以后表底温差进一步缩小,垂向水温分层逐渐消失。通过分析发现:气象要素、入流水温、电站取水口高程、泄洪方式成为影响向家坝水温分布的主要因素。入流水温的变化只影响水库水温波动范围,对其垂向分层结构影响较低;表层水温受气象条件影响显著;取水口高程和泄洪方式决定了水温的垂向结构。     

A box model for calculation of collective dose commitment from radioactive waterborne releases to the baltic sea

To meet the new regulations of maximum yearly releases from Swedish nuclear power plants issued by the Swedish National Radiation Protection Institute, and to make realistic calculations of collective dose commitment derived from radionuclides discharged to the Baltic Sea, a box model AQUAPATH-BALTIC has been developed. The model calculates radionuclide concentrations in 25 boxes for discharges into given compartments and takes into consideration the dispersion rates of the water masses, the sediment-water interaction and radioactive decay. The calculated concentrations in water and sediment at steady state are then used to evaluate individual and collective intakes of activity and external exposures. The radiation doses to the global population following discharges to the Baltic Sea are also calculated.     

江苏淮河流域工业点源负荷空间分布特征研究

搞清流域工业点源的空间分异特征,可为水环境整治与工业规划提供参考依据。采用工业污染源普查数据建立污染源信息数据库,在GIS技术、密度分析法与ESDA方法支撑下,探析江苏淮河流域工业点源与工业污染负荷空间格局与特征。结果显示：工业点源集聚于城市、县城及专业乡镇,污染行业地域分异现象显著,其中,河流、港口及临湖地区成为高负荷工业点源集聚地区,化工、造纸、化纤与医药等行业的工业集中于临海、临河及临湖地区,饮料制造业、副食品加工业点源集中于工业化水平较低的北部流域的少数乡镇,工业氨氮多数来自化工业。在不同工业化水平下,工业污染负荷空间差异大,南部流域负荷整体水平高于北部,北部流域高负荷区分布于少数乡镇与城区     

Variation of nutrient and metal concentrations in aquatic macrophytes along the Rio Cachoeira in Bahia (Brazil)

The use of cuprous fungicides in cocoa production in the southern part of the state of Bahia (Brazil) for decades has caused an accumulation of copper in various components of the cocoa plantations, and a contamination of regional freshwater ecosystems is suspected. Urban and industrial sources are supposed to contribute to water pollution and eutrophication of the Rio Cachoeira, the main river in this region. In order to study the metal contamination and nutritional status of this freshwater ecosystem, samples of the aquatic macrophytes Eichhornia crassipes and Pistia stratiotes were collected at seven sites along the river course. The samples were analysed for their copper, aluminium, chromium, nitrogen and phosphorus concentrations. The levels of heavy metals increased in the downstream direction, particularly in the roots of water hyacinth. A dramatic increase of nitrogen and phosphorus concentrations in water as well as in plant tissues was found in samples collected downstream from the city of Itabuna. Metal input and eutrophication were attributed to agricultural, industrial and urban sources in the region. Biomonitoring of the water quality using aquatic macrophytes as accumulative indicator plants is recommended in addition to chemical water analyses.     

经济转型背景下工业污染时空格局演变及其驱动因素研究——以长江三角洲地区为例

合力打好污染防治攻坚战、强化区域生态环境共保是全面贯彻落实绿色发展理念,推动长三角地区更高质量一体化发展的重要内容。在中国区域经济转型发展背景下,利用城市工业污染物排放和经济社会发展统计数据,重点分析了2003～2015年长三角地区主要工业污染物排放相对规模和强度的时空格局演变规律,探讨了经济转型发展等因素对工业污染时空格局的动态影响机制。研究结果表明:(1)长三角地区主要工业污染物排放相对规模和强度总体呈下降趋势,2003～2015年工业废水、SO_2排放总量分别削减约13%和24%,每万亿元工业总产值的废水、SO_2和烟(粉)尘排放量分别削减87%、88%和71%左右。(2)工业污染排放仍主要集聚在沿沪宁、沿长江和沿沪杭甬等工业发达地区以及部分资源型城市,并呈现由核心区向皖江城市带、苏北等外围区转移扩散的态势,但不同污染物之间差异较为显著。(3)外围区工业污染物排放相对强度较高(多为1.0以上),但近年来南京、杭州等核心区的工业污染物(尤其是工业粉尘)排放相对强度有所上升。(4)经济转型是工业污染时空格局演变的重要驱动力,其中产业结构升级、创新与消费驱动转型增长等是抑制工业污染物排放规模扩张的重要因素;而创新投入及技术进步、企业质效提升、外资外贸结构优化等则有利于降低工业污染物排放相对强度;但由于各地经济转型阶段不同,上述因素对工业污染的影响机制存在显著的空间差异。该研究揭示了经济转型背景下工业污染时空格局演变及驱动因素,对于强化新时期长三角地区工业污染协同防治等具有一定政策参考价值。     

中国环境污染密集型产业脱钩的异质性及产业转型

根据现有文献,研究中国的经济增长与环境污染的脱钩,需要将不同环境密集型产业与经济增长的关系分别测算,然后进行比较。本文选取了工业污染的三大来源——废水、废气和固体废物,每种污染源对应着一类环境密集型产业。这三种产业密集排放的污染物的量与经济增长之间的脱钩关系及其内在机制,这是本文研究的重点。本文借鉴Tapio弹性分析模型构建了我国经济增长与不同环境密集型产业之间的脱钩状态的分析模型,并对脱钩状态和程度的判定标准做了规定。随后,对2001-2009年四个时期的经济增长与不同环境密集型产业集中排放的污染物的量之间的脱钩指数进行了测算,同时测算了各产业污染的工业产值弹性及其工业产值的GDP弹性,并对脱钩状态和程度做了判定。结果表明:三类产业的脱钩程度各不相同,其动力机制与发展前景也有所不同,因而需要有针对性地采取规制和治理措施。     

农业面源污染现状与防治进展

通过对国内外农业面源污染研究资料的分析,认为农业面源污染的形式主要有:化肥污染、农药污染、农膜污染、秸秆燃烧污染、养殖业污染及水土流失等。农业面源污染导致了土地退化,在全世界不同程度退化的12亿hm2耕地中,约12%由农业面源污染引起;是河流和湖泊的重要污染源,导致美国40%的河流和湖泊水质不合格;是引起地表水氮、磷富营养化的主要因素,欧洲国家由农业面源污染排放的磷为地表水污染总负荷的24%-71%;中国的农业面源污染造成的水体氮、磷富营养化也显著超过来自城市的生活点源污染和工业点源污染。提出目前比较好的防治措施有:最佳农田管理措施、植被过滤带和人工湿地。建议我国控制农业面源污染必须从政策和法律上对农业生产活动进行规范,采用先进的理论和技术实行源头控制,并辅助以过程控制和末端控制。     

长江三角洲地表水环境污染规律及调控对策

根据野外实地考察和定点观测数据 ,结合历年环境监测资料 ,初步揭示了长江三角洲地表水环境污染的现状与近十年来的时空演变规律 :河网干流水质基本良好 ,中小河流污染突出 ;城市河流有机污染严重 ,普遍出现水体黑臭现象 ;湖泊氮磷含量逐年增高 ,水体富营养化加剧 ;市郊小城镇河网水质急剧恶化 ,已成为新的水环境污染中心。造成长江三角洲地表水环境污染的主要物源包括工业废水和生活污水、畜禽粪便、农田化肥、底泥等。针对上述污染规律和成因机制 ,提出了相应的调控对策。     

Dynamics of snowmelt water composition in conifer forests exposed to airborne industrial pollution

An analysis is made of the spatial variability of snowmelt water composition (within and between biogeocenoses), with regard to its long-term dynamics, in pine and spruce forests exposed to airborne industrial pollution from the Europe’s largest Severonikel Copper–Nickel Smelter Complex. Snowmelt waters from under the tree canopy, compared to those from intercrown areas, contain higher concentrations of chemical elements due to their washing and leaching from tree crowns. This is especially true of spruce forests, since the crowns of spruce trees have a high sorption capacity. Distinct trends in the long-term dynamics of snowmelt water composition, related to reduction of industrial emissions, are observed in background forest areas and defoliating forests but not in the vicinity of pollution sources. It is shown that the main factors determining these dynamics in forests of the Kola Peninsula are edificator tree species, airborne industrial pollution, and, possibly, an increase in the number of days with above-zero temperatures in the period of snow accumulation, which facilitates washing and leaching of chemical compounds from tree crowns.     

“水十条”对工业水污染强度的影响及其机制

《水污染防治行动计划》(简称“水十条”)是国家为切实加大水污染防治力度,保障国家水安全而制定的法规。为检验“水十条”的政策影响效应,文章利用2012—2017年全国269个地级市的数据,结合工业化程度、对外开放水平、技术进步、人口规模、水资源禀赋等控制变量,运用双重差分法对“水十条”政策实施是否有助于减轻工业水污染强度进行研究。研究发现:我国中西部地区由于产业结构、技术水平等原因,工业水污染强度显著高于其他地区,“水十条”政策实施显著降低了中西部地区工业水污染强度。通过改变政策实施时间、剔除中心城市、增加控制变量以及剔除严重污染等方式进行重新回归,检验结果依然具有较强稳健性。进一步分析中,文章研究了产业结构以及技术创新的作用机制,发现第一产业比重显著降低,而第三产业显著提升,产业结构得到优化,并且技术创新效应显著加强。结果表明,产业结构升级以及技术创新均为“水十条”政策改善工业水污染强度的有效途径。在空间异质性方面,在环境规制强度较高的地区“水十条”政策对工业水污染强度的影响相对较小;而在环境规制强度较低地区却呈现出较强的抑制作用,主要原因在于环境规制强度高的地区水污染情况原本较好,因此污染强度降低幅度较小。因此,文章认为“水十条”政策能够显著改善工业水污染强度,并且加上环境规制、技术创新以及产业结构优化等手段的辅助能够更好地发挥政策效果。文章的发现为中国水污染防治行动提供了有益的政策启示。     

Regional industrial growth and environmental impacts in the Bohai Sea rim region of China: uncertainty in location choice

Regional industrial growth is facing the problems of no control and disorder in rapidly transitioning China, especially in mega-regional areas. These problems have significantly intensified the use of regional resources and the level of environmental stress. The integration of industrial development and the environmental pollution pressure simulation at the mega-regional level must be supported at the planning stage. In this study, a Computational System for Regional Industrial Distribution Simulation and Environmental Impact Assessment (RESEA) that combines a multi-nominal logit model and uncertainty analysis was developed. This system aimed to explore efficient industrial spatial distribution simulations and potential environmental pressures at the mega-regional level. This study also developed an uncertainty analysis framework to identify and apply a bottom-up system with aggregate and sparse data following the basic processes of an HSY algorithm and Global-Formed Regional Sensitivity Analysis, which is capable of considering both input uncertainty and parameter uncertainty. By applying the RESEA system, a process of model estimation and sensitivity analysis was implemented based on historic data from 2002 to 2008 for the Bohai Sea rim region in China. The future industry distribution for the year 2015 was later aggregated based on the chosen sizes and locations of newly added industrial plants. Finally, the pollution loads of surface water into every sub-region were calculated, and the potential environmental impacts of different strategies were discussed.     

Trace analysis for aromatic hydrocarbons in natural waters

A method for trace analysis of volatile aromatic hydrocarbons in natural water is described. The method is based on sparging water samples with nitrogen, adsorption of hydrocarbons on activated charcoal, followed by desorption into carbon disulfide and gas chromatographic analysis. The sensitivity of the method reaches into the 0.1 to 0.2 μg/L concentration range for individual aromatic hydrocarbons. The accuracy and reliability of the method was validated. The method was used in three field studies: dispersion of aromatic hydrocarbons discharged from the Trans-Alaska Pipeline southern terminal throughout Port Valdez; survey of the Atigun River Watershed after oil spill on June 10, 1979; and chemical characterization of treated effluents from offshore oil extraction platforms in the Gulf of Mexico.     

Assessment of the Antioxidant Potential of Plants in Urban Ecosystems under Conditions of Anthropogenic Pollution of Soils

The leaves of 22 woody and herbaceous plant species growing in urban ecosystems of Kalinigrad were analyzed for the total contents of water-soluble antioxidants (TAC) and polyphenol contents. The soils of test plots were assayed for lead contents in the accumulative horizon. A significant excess over the background Pb level was revealed in soil samples from residential and industrial/utility areas (42% of the city territory), and TAC in plant tissues was found to decrease with an increase in Pb concentration in the soil. The role of polyphenols in forming the antioxidant potential of urban plants growing under conditions of technogenic soil pollution was evaluated. Based on cluster analysis of the water-soluble antioxidant and polyphenol accumulation patterns, the plants were classified into four groups. The results of this study may be used for comprehensive assessment of the resilience of urban plants to anthropogenic impact and improvement of the approaches and methods for monitoring industrial pollution in urban areas.     

Exposure assessment of adult intake of bisphenol A (BPA) with emphasis on canned food dietary exposures

Bisphenol A (BPA) is a high-volume, synthetic compound found in epoxy resins and plastics used in food packaging. Food is believed to be a major source of BPA intake. In this study, we measured the concentration of BPA in convenience samplings of foodstuffs purchased in Dallas, Texas. Sampling entailed collection of 204 samples of fresh, frozen, and canned foods in two rounds in 2010. BPA was positive in 73% of the canned food samples, while it was found in only 7% of non-canned foods at low concentrations. The results of this food sampling program were used to calculate adult dietary intakes of BPA. A pathway approach combined food intakes, a “canned fraction” parameter which described what portion of total intake of that food came from canned products, and measured food concentrations. Dietary intakes were calculated as 12.6 ng/kg-day, of which 12.4 ng/kg-day was from canned foods. Canned vegetable intakes alone were 11.9 ng/kg-day. This dietary intake was compared to total intakes of BPA estimated from urine measurements of the National Health and Nutrition Examination Survey (NHANES). Total adult central tendency intakes ranged from 30 to 70 ng/kg-day for NHANES cycles between 2005 and 2010. Three possibilities were explored to explain the difference between these two approaches for intake estimation. Not all foods which may have been canned, particularly canned beverages such as soft drinks, were sampled in our food sampling program. Second, non-food pathways of exposure may be important for adults, including thermal paper exposures, and dust and air exposures. Finally, our canned food concentrations may not be adequately representative of canned foods in the United States; they were found to be generally lower compared to canned food concentrations measured in six other worldwide food surveys including three in North America. Our finding that canned food concentrations greatly exceeded non-canned concentrations was consistent with other studies, and underscores the importance of canned foods in the overall exposure of adults of BPA.