Successful Deployment of an Innovative Environmental Technology: The Terra-Kleen Experience

The National Research Council's report, Innovations in Ground Water and Soil Cleanup: From Concept to Commercialization, reviewed the implementation of innovative remediation technologies and portrayed a bleak outlook for them. Conversely, Terra-Kleen has invented, patented, permitted, and profited through the use of an innovative technology in the current market. Terra-Kleen has implemented a solvent extraction technology for the removal of PCBs, PAHs, and chlorinated pesticides from soil, sediment, and debris. To date, Terra-Kleen has successfully processed over 23 million pounds of PCB-contaminated soil in Alaska, California, Florida, Ohio, and Oklahoma. The company has been profitable each year since its inception, and has averaged a revenue growth rate of 94 percent per year for the last four years. Corporate growth has been financed entirely through profits and conventional bank loans at favorable interest rates. This article reviews the factors that have led to Terra-Kleen's success, overviews the solvent extraction technology, and details specific projects that have implemented the technology.     

Sodium Persulfate Oxidation for the Remediation of Chlorinated Solvents (USEPA Superfund Innovative Technology Evaluation Program)

This study has been conducted at the University of Connecticut (UCONN) in connection with the USEPA Superfund Innovative Technology Evaluation (SITE) program to evaluate a chemical oxidation technology (sodium persulfate) developed at UCONN. A protocol to assess the efficacy of oxidation technologies has been used. This protocol, which consists of obtaining data from a treatability study, tested two in-situ chemical oxidation technologies that can be used on soil and groundwater at a site in Vernon, Connecticut. Based on the treatability report results and additional field data collected at the site, the design for the field implementation of the chemical oxidation remediation was completed. The results indicate that both sodium persulfate and potassium permanganate were able to effectively degrade the target VOCs (i.e., PCE, TCE and cis-DCE) in groundwater and soil-groundwater matrices. In the sodium persulfate tests (120 hrs), the extent of destruction of target VOCs was 74% for PCE, 86% for TCE and 84% for cis-DCE by Na₂S₂O₈ alone and 68% for PCE, 76% for TCE, and 69% for cis-DCE by Fe(II)-catalyzed Na₂S₂O₈. The results demonstrate the sodium persulfate's ability to degrade PCE, TCE and cis-DCE. It is expected that given sufficient dose and treatment time, a higher destruction rate of the dissolved phase contamination can be achieved. The data also indicates that the catalytic effect of the iron chelate on persulfate chemistry was much less pronounced in the soil-groundwater matrix. This indicates an interaction between the iron chelate solution and the soil, which may have resulted in a lower availability of the chelated iron for catalysis. The study showed that the remediation of the VOCs-contaminated soil and groundwater by in-situ chemical oxidation using sodium persulfate is feasible at the Roosevelt Mills site. As a result, the USEPA SITE program will evaluate this technology at this site.     

挥发性有机化合物气体泄漏检测与修复技术

介绍了一种先进的挥发性有机物(VOCs)排放控制技术,即设备管线组件泄漏检测与修复(LDAR)技术,详细分析了LDAR技术在国内外的实施经验,并探讨了该技术应用于我国石化行业VOCs排放控制的前景.     

Assessment of the cementitious and microstructural characteristics of an innovative waste-based eco-cement

Journal of Material Cycles and Waste Management - The cementitious and microstructural characteristics of an innovative waste-based eco-cement consisting of ground granulated blast-furnace slag...     

酸性高浓度含氟废水处理技术

介绍了对某化工厂排放的酸性高浓度含氟废水进行处理的试验,采用石灰中和沉淀,氯化钙（或聚丙烯酰胺）二级絮凝沉淀,砂滤工艺进行处理,操作控制条件如下：pH为8－9,Ca^2 与F^-的摩尔比为3．0,聚丙烯酰胺投加量为2mg/L,沉淀时间为1h,处理工程运行后的验收监测结果表明,出水中的残氟浓度可以达到国家规定的一级排放标准,且系统运行稳定,工艺简便。     

A Preliminary Risk Assessment Protocol for Renegade Nanoparticles Deployed During Nanoremediation

The NanoRem European research project aims to support and develop the appropriate use of nanotechnology for contaminated land remediation by facilitating practical, economic, and exploitable nanotechnology for in situ remediation. This can only be achieved in parallel with a comprehensive understanding of the environmental risk‐benefit balance for the use of the nanoparticles (NPs) being investigated. While the NanoRem NPs could have a significant toxicity this is likely to be less potent than NPs currently being released into the environment, such as those from a variety of antibacterial products. The NanoRem NPs are likely to interact with the aquifer matrix, each other, and groundwater chemistry to rapidly cease to be mobile and are unlikely to penetrate into the aquifer more than a few meters from the point of injection. In terms of the source‐pathway‐receptor paradigm, the NanoRem NPs are cautiously presumed to represent a hazard (i.e., source). At least one receptor, in the form of not yet polluted groundwater, is present at all the NanoRem case study sites. While there are considerable uncertainties particularly with regards to the transport of NanoRem NPs, the ability of NPs to penetrate far into the formation is likely to be very limited. The relatively short travel distances reported in the literature for a variety of NP types and geological conditions suggest that the pathways are at best very limited in extent. Overall, this means that in many cases the level of risk renegade NPs can pose to the environment or human health is at most minimal. A qualitative protocol developed for the NanoRem field trials can demonstrate that injecting NanoRem NPs into contaminated groundwater poses a minimal level of risk due to the reduced pathway. ©2016 Wiley Periodicals, Inc.     

Examination of a New Remedial Technology for Capping Contaminated Sediments: Large-Scale Laboratory Evaluation of Sediment Mixing and Cap Resistance to Erosive Forces

The potential effectiveness of a new composite-aggregate capping technology, AquaBlok^TM—in physically isolating contaminated, fine-grained sediments derived from an Ohio, Lake Erie tributary—was evaluated in the laboratory. In particular, large-scale settling-column studies were conducted to determine the degree to which composite-aggregate material penetrates into and/or mixes with the sediment, perhaps affecting the degree to which sediment could be physically isolated through capping. Additionally, large-scale flume studies were conducted to determine resistance of the composite-aggregate material to significant and long-term, fluvial-like erosive forces; the resistance of other potential capping materials was also evaluated for comparison. Experimental results indicate that the composite-aggregate material effectively isolates sediment through the formation of a continuous and relatively erosion-resistant, hydrated capping layer atop the sediments.     

从富氢干气中回收氢气技术

依据清洁生产审核、评估的结果,提出了从富氢干气中回收氢气的高费方案,并加以实施。富氢干气先用化学吸收法进行脱硫处理,再用高压吸附、低压抽真空解吸,从含粗氢的干气中提纯出99．9％(体积分数)的氢气。该装置负荷为35％的情况下,可回收氢气2500t/a,减排二氧化硫约100t／a,创经济效益约426．6万元／a。     

A Preliminary Laboratory Study of Initial Copper Release from Dredge Residuals

A preliminary laboratory study was conducted to investigate the impact of different residual types and sediment surface roughness on copper contaminant fluxes to the water column. Sediments from Torch Lake, Michigan served as the test samples. These sediments are mining by‐products with elevated Cu levels. Six experiments were run during which the sediments were conditioned to simulate different forms of residuals. During these experiments, the water column above the sediments was circulated via peristaltic pumping or orbital shaking and the total and dissolved Cu levels were monitored periodically for 15 days. Dissolved Cu levels indicated that during the first 48 hr the water column concentrations approached equilibrium for all six cases. Total Cu levels increased with time and did reach equilibrium but were more susceptible to fluctuations in water column suspended solids levels. Analysis of the resulting dissolved Cu data indicated that the resulting water column Cu concentrations differed with sediment surface and residual type. The highest dissolved Cu water column concentrations were observed for a roughened surface with a larger surface area. The lowest water column dissolved Cu levels were observed for the case with sediment slurry placed over clean sand. The dissolved Cu levels in the water column for all six simulated conditions were several orders higher than the USEPA ambient water quality criteria for protection of aquatic life. © 2014 Wiley Periodicals, Inc.*     

A Sensitive Electrochemical Impedance Spectroscopy Method for Detection of Polyimide Degradation by Microorganisms

An electrochemical impedance spectroscopy (EIS) technique was evaluated for monitoring microbial degradation of electronic packaging polyimides. The microbial inoculum was a mixed culture of fungi isolated previously from deteriorated polyimides. The active fungal consortium comprised Aspergillus versicolor, Cladosporium cladosporioides, and a Chaetomium species. After inoculation, fungal growth on the polyimides resulted in distinctive EIS spectra indicative of polymer insulation failure, which directly related to polymer integrity. Degradation appeared to occur in a number of steps and two distinctive stages in the decline of film resistance were observed in the inoculated EIS cells within the 2 and 10 weeks after inoculation. The early stage of resistance decrease may be related to the ingress of water molecules and ionic species into the polymeric materials, whereas the second stage probably resulted from partial degradation of the polymers by fungal growth on the polymer film. The relationship between changes of impedance spectra and microbial degradation of the polymer was further supported by scanning electron microscopy (SEM) observations of fungi growing on the surface of the inoculated polyimides. Our data indicate that the EIS can be used in detection of early degradation of resistant polymers and polyimides that are susceptible to biodeterioration.     

Assessment of the Water Balance of European Forests: A Model Study

As part of the UN-ECE Intensive Monitoring Program, data on precipitation, throughfall and soil solution concentrations are measured on a regular basis in approximately 300 forest stands. These data were used to construct element budgets for European forests. To construct such budgets drainage fluxes have to be modeled. In this paper, the research chain from model selection to data derivation and application of the selected model to 245 of the 300 sites is described. To select a suitable hydrological model the Cl^- balance method, two capacity models (a multi and a single layer version) and a Darcy model have been applied to two forest sites. The results indicate that drainage fluxes calculated with the Darcy model are more accurate than fluxes derived with the capacity model, in particular in situations where water availability is limited. The Darcy model was applied to the sites using a mixture of generic data and site data. Despite the use of generic data, the calculated drainage fluxes appear feasible. Median transpiration fluxes were 350 mm and the lowest values are found in northern Europe and highest values are found in central Europe. Median drainage fluxes were 150 mm yr^-1 with the highest values in areas with high rainfall. Uncertainty analyses indicate that the use of local instead of interpolated meteorological data leads to lower drainage fluxes at 70% of the sites. The median deviation in calculated drainage fluxes is 20 mm yr^-1. The use of local soil data had little impact on the calculated fluxes.     

The Assessment of Atmospheric Pollution using Satellite Remote Sensing Technology in Large Cities in the Vicinity of Airports

This paper investigates the potential of usingsatellite remotely sensed imagery for assessing atmosphericpollution. A novel approach, which comprised radiativetransfer calculations and pseudo-invariant targets fordetermining aerosol optical thickness has been developed.The key parameter for assessing atmospheric pollution inphotochemical air pollution studies is the aerosol opticalthickness. The need for identifying suitable pseudo-invariantobjects in satellite images of urban areas is of great interest for increasing the potential of earthobservation for monitoring air pollution in such areas. Theidentification of large water bodies and concrete apronsthat can serve as suitable dark and bright targetsrespectively in different geographical areas wasdemonstrated in this study. This study added evidence onthe correlation found between the visibility valuesmeasured at Heathrow Airport area during satellite overpassand aerosol optical thickness derived from Landsat-5 TMband 1 images.     

Assessment of biotechnological strategies for the valorization of metal bearing wastes

The present work deals with the application of biotechnology for the mobilization of metals from different solid wastes: end of life industrial catalysts, heavy metal contaminated marine sediments and fluorescent powders coming from a cathode ray tube glass recycling process. Performed experiments were aimed at assessing the performance of acidophilic chemoautotrophic Fe/S-oxidizing bacteria for such different solid matrices, also focusing on the effect of solid concentration and of different substrata. The achieved results have evidenced that metal solubilization seems to be strongly influenced by the metal speciation and partitioning in the solid matrix. No biological effect was observed for Ni, Zn, As, Cr mobilization from marine sediments (34%, 44%, 15%, 10% yields, respectively) due to metal partitioning. On the other hand, for spent refinery catalysts (Ni, V, Mo extractions of 83%, 90% and 40%, respectively) and fluorescent powders (Zn and Y extraction of 55% and 70%, respectively), the improvement in metal extraction observed in the presence of a microbial activity confirms the key role of Fe/S oxidizing bacteria and ferrous iron. A negative effect of solid concentration was in general observed on bioleaching performances, due to the toxicity of dissolved metals and/or to the solid organic component.     

Assessment of total urban metabolism and metabolic inefficiency in an Irish city-region

This paper aims to measure product and waste flows in an Irish city-region using the principles of metabolism and mass balance. An empirical indicator to measure resource efficiency, using a ratio of waste disposal as a function of product consumption, was developed and it was found that total materials metabolic inefficiency fell by 31% from 0.13 in 1996 to 0.09 in 2002. The paper concludes by analyzing the strengths and weaknesses of this indicator and its potential application in the field of sustainable consumption and resource efficiency as well as making suggestions to improve and strengthen the indicator.     

Assessment of compost quality for its environmentally safe use by means of an ecotoxicological test on a soil organism

A research project was carried out to evaluate toxicological effects of compost addition to agricultural soil using the earthworm Eisenia foetida (Annellida) as a representative organism of the soil fauna. Moreover, the correlation between compost biochemical stabilization and toxicity at different phases of the composting process was assessed. Samples were collected from three composting plants at three different maturation levels (beginning of the composting process, intermediate compost after bio-oxidation, and mature refined compost). Two tests were performed: a standard chronic solid-phase test and an acute solid-phase test (developed originally by the authors). In the first test, the measured end-points were mortality, growth and reproduction; while in the second test earthworms’ behavior was evaluated. The chosen compost concentrations in soil ranged from 2.5 to 100 %, with the aim of obtaining the toxicological parameters (LC50) and to mimic real agricultural dosages for the lower concentrations. Results indicated an increase in compost toxicity with greater compost concentrations; in particular, agricultural compost dosage below 10 % showed no toxicity. Moreover, toxicity did not decrease during composting; intermediate compost showed the highest LC50 values. As a consequence, no correlation was ascertained between the results of ecotoxicological analysis and waste biochemical stability parameters during the composting process.     

Laboratory scale studies on gaseous emissions generated by the incineration of an artificial automotive shredder residue presenting a critical composition

Car manufacturers must eliminate automotive shredder residues (ASR). Two ways of incineration are of interest: at 850°C in municipal waste incinerators or at higher temperatures, above 1100°C in cement plants. These processes reduce the mass and the volume of waste to be disposed of in landfills and energy recovery might be possible. Regulations govern the emission of gaseous effluents to control environmental risk. To determine gaseous effluents from a pilot sacle or an industrial incineration plant, an artificial ASR was made by mixing three representative organic polymers present in the real ASR, namely polyvinylchloride, polyurethane and rubber. This mixture was incinerated at 850 and 1100°C in laboratory experiments and the analyses of the principal gaseous effluents such as carbon oxides, nitrogen oxides, volatile organic compounds, hydrochloric and hydrocyanic acids and sulphur compounds are presented and discussed. Lastly, in order to simulate artificial ASR behaviour, the composition of the combustion gases at equilibrium was calculated using a Gibbs energy minimisation code.     

A Multiscale Approach for Assessing the Interactions of Environmental and Biological Systems in a Holistic Health Risk Assessment Framework

Advances in computing processing power and in availability of environmental and biological data have allowed the development and application of comprehensive modeling systems that utilize a holistic, integrated, approach for assessing the interactions of environmental and biological systems across multiple scales of spatiotemporal extent and biological organization. This approach allows mechanism-based environmental health risk assessments in a person-oriented framework, which accounts for simultaneous exposures to contaminants from multiple media, routes, and pathways. The conceptual basis and example applications of the Modeling ENvironment for TOtal Risk (MENTOR), and the DOse–Response Information ANalysis system (DORIAN) are presented.     

浅论区域开发环境影响评价的指标体系

论述了区域开发环境影响评价应建立能反映环境可持续性和跨边界性的指标体系，提出了建立该指标体系的原则与方法。     

Life Cycle Assessment of Polysaccharide Materials: A Review

Apart from conventional uses of polysaccharide materials, such as food, clothing, paper packaging and construction, new polysaccharide products and materials have been developed. This paper reviews life cycle assessment (LCA) studies in order to gain insight of the environmental profiles of polysaccharide products (e.g. viscose or natural fibre polymer composites) in comparison with their conventional counterparts (e.g. cotton or petrochemical polymers). The application areas covered are textiles, engineering materials and packing. It is found that for each stage of the life cycle (production, use phase and waste management) polysaccharide-based end products show better environmental profiles than their conventional counterparts in terms of non-renewable energy use (NREU) and greenhouse gas (GHG) emissions. Cotton is an exception, with high environmental impacts that are related to the use of fertilisers, herbicides, pesticides and high water consumption. The available literature for man-made cellulose fibres shows that they allow to reduce NREU and GHG emissions in the fibre production phase. No study has been found for the fabric production and the use phase of man-made cellulose textiles.