Determination of ozone in outdoor and indoor environments using nitrite-impregnated passive samplers followed by ion chromatography

An improved ion chromatographic (IC) method has been developed for the separation of nitrate in filter extracts in the presence of high concentrations of nitrite. This analytical method was successfully used for an indirect measurement of ozone (O3) in outdoor and indoor air, following its collection using a nitrite-impregnated passive sampler. The limit of detection and the limit of quantification, using the modified IC method, were 6 microg l(-1) (3sigma) and 20 microg l(-1) (10sigma), respectively. Improved detection limits and low baseline noise were obtained with the use of eluent generator and high-capacity ion exchange column. The optimized method was used for assessing O3 concentration in both indoor and outdoor environments of 28 child care centers (CCCs) located in different parts of Singapore. The O3 concentrations ranged from 0.1 to 11.95 parts per billion (ppb) in indoor and from 3.2 to 21.7 ppb in outdoor environments during the study period. It was found that, among the CCCs investigated in this study, air-conditioned CCCs and those located in close proximity to traffic emissions had significantly lower O3 concentrations indoors.     

Dependence of home outdoor particulate mass and number concentrations on residential and traffic features in urban areas

The associations between residential outdoor and ambient particle mass, fine particle absorbance, particle number (PN) concentrations, and residential and traffic determinants were investigated in four European urban areas (Helsinki, Athens, Amsterdam, and Birmingham). A total of 152 nonsmoking participants with respiratory diseases, not exposed to occupational pollution, were included in the study, which comprised a 7-day intensive exposure monitoring period of both indoor and home outdoor particle mass and number concentrations. The same pollutants were also continuously measured at ambient fixed sites centrally located to the studied areas (fixed ambient sites). Relationships between concentrations measured directly outside the homes (residential outdoor) and at the fixed ambient sites were pollutant-specific, with substantial variations among the urban areas. Differences were more pronounced for coarse particles due to resuspension of road dust and PN, which is strongly related to traffic emissions. Less significant outdoor-to-fixed variation for particle mass was observed for Amsterdam and Birmingham, predominantly due to regional secondary aerosol. On the contrary, a strong spatial variation was observed for Athens and to a lesser extent for Helsinki. This was attributed to the overwhelming and time-varied inputs from traffic and other local sources. The location of the residence and traffic volume and distance to street and traffic light were important determinants of residential outdoor particle concentrations. On average, particle mass levels in suburban areas were less than 30% of those measured for residences located in the city center. Residences located less than 10 m from a street experienced 133% higher PN concentrations than residences located further away. Overall, the findings of this multi-city study, indicated that (1) spatial variation was larger for PN than for fine particulate matter (PM) mass and varied between the cities, (2) vehicular emissions in the residential street and location in the center of the city were significant predictors of spatial variation, and (3) the impact of traffic and location in the city was much larger for PN than for fine particle mass.     

National estimates of outdoor air toxics concentrations

The Clean Air Act identifies 189 hazardous air pollutants (HAPs), or "air toxics," associated with a wide range of adverse human health effects. The U.S. Environmental Protection Agency has conducted a modeling study with the Assessment System for Population Exposure Nationwide (ASPEN) to gain a greater understanding of the spatial distribution of concentrations of these HAPs resulting from contributions of multiple emission sources. The study estimates year 1990 long-term outdoor concentrations of 148 air toxics for each census tract in the continental United States, utilizing a Gaussian air dispersion modeling approach. Ratios of median national modeled concentrations to estimated emissions indicate that emission totals without consideration of emission source type can be a misleading indicator of air quality. The results also indicate priorities for improvements in modeling methodology and emissions identification. Model performance evaluation suggests a tendency for underprediction of observed concentrations, which is likely due, at least in part, to a number of limitations of the Gaussian modeling formulation. Emissions estimates for HAPs have a high degree of uncertainty and contribute to discrepancies between modeled and monitored concentration estimates. The model's ranking of concentrations among monitoring sites is reasonably good for most of the gaseous HAPs evaluated, with ranking accuracy ranging from 66 to 100%.     

Indoor–outdoor concentrations of RSPM in classroom of a naturally ventilated school building near an urban traffic roadway

A study on indoor–outdoor RSPM (PM₁₀, PM_2.5 and PM_1.0) mass concentration monitoring has been carried out at a classroom of a naturally ventilated school building located near an urban roadway in Delhi City. The monitoring has been planned for a year starting from August 2006 till August 2007, including weekdays (Monday, Wednesday and Friday) and weekends (Saturday and Sunday) from 8:0 a.m. to 2:0 p.m., in order to take into account hourly, daily, weekly, monthly and seasonal variations in pollutant concentrations. Meteorological parameters, including temperature, rH, pressure, wind speed and direction, and traffic parameters, including its type and volume has been monitored simultaneously to relate the concentrations of indoor–outdoor RSPM with them. Ventilation rate has also been estimated to find out its relation with indoor particulate concentrations. The results of the study indicates that RSPM concentrations in classroom exceeds the permissible limits during all monitoring hours of weekdays and weekends in all seasons that may cause potential health hazards to occupants, when exposed. I/O for all sizes of particulates are greater than 1, which implies that building envelop does not provide protection from outdoor pollutants. Further, a significant influence of meteorological parameters, ventilation rate and of traffic has been observed on I/O. Higher I/O for PM₁₀ is indicating the presence of its indoor sources in classroom and their indoor concentrations are strongly influenced by activities of occupants during weekdays.     

Estimated long-term outdoor air pollution concentrations in a cohort study

Several recent studies associated long-term exposure to air pollution with increased mortality. An ongoing cohort study, the Netherlands Cohort Study on Diet and Cancer (NLCS), was used to study the association between long-term exposure to traffic-related air pollution and mortality. Following on a previous exposure assessment study in the NLCS, we improved the exposure assessment methods.Long-term exposure to nitrogen dioxide (NO₂), nitrogen oxide (NO), black smoke (BS), and sulphur dioxide (SO₂) was estimated. Exposure at each home address (N=21 868) was considered as a function of a regional, an urban and a local component. The regional component was estimated using inverse distance weighed interpolation of measurement data from regional background sites in a national monitoring network. Regression models with urban concentrations as dependent variables, and number of inhabitants in different buffers and land use variables, derived with a Geographic Information System (GIS), as predictor variables were used to estimate the urban component. The local component was assessed using a GIS and a digital road network with linked traffic intensities. Traffic intensity on the nearest road and on the nearest major road, and the sum of traffic intensity in a buffer of 100 m around each home address were assessed. Further, a quantitative estimate of the local component was estimated.The regression models to estimate the urban component explained 67%, 46%, 49% and 35% of the variances of NO₂, NO, BS, and SO₂ concentrations, respectively. Overall regression models which incorporated the regional, urban and local component explained 84%, 44%, 59% and 56% of the variability in concentrations for NO₂, NO, BS and SO₂, respectively.We were able to develop an exposure assessment model using GIS methods and traffic intensities that explained a large part of the variations in outdoor air pollution concentrations.     

An evaluation approach for livable urban environments

This study proposes a method for evaluating livable urban environments using the analytic hierarchy process, a survey of public opinions (n?=?1,075), and gray relational analysis with a pollutant standards index to estimate the weights of weather, air pollution, and environment aspects and each respective factor. This study investigates the positive or negative correlation of these factors and their effects on livable environment. A value of 100 was designated as the perfect living condition. Results show that the weights of weather, air pollution, and environment aspects were 0.288, 0.395, and 0.317, respectively. The weight ranges of three weather factors, five air pollution factors, and ten environmental factors were 0.311-0.358, 0.191-205, and 0.081-0.116, respectively. The monthly livable index of 28 districts in Taichung City and of 20 cities/counties in Taiwan ranged from 81.1 to 92.4 and from 83.1 to 90.8 in different months, respectively, showing that environmental aspect played a key role. These results demonstrate that the proposed method can provide a quantification index of living conditions in each region, thereby establishing the governmental improvement policy firmly. This study also presents a discussion on improvement strategies, especially on the apportionment rate of governmental construction funds for livable urban environments.     

Monitoring of heavy metal concentrations in home outdoor air using moss bags

One monitoring station is insufficient to characterize the high spatial variation of traffic-related heavy metals within cities. We tested moss bags (Hylocomium splendens), deployed in a dense network, for the monitoring of metals in outdoor air and characterized metals’ long-term spatial distribution and its determinants in Girona, Spain. Mosses were exposed outside 23 homes for two months; NO₂ was monitored for comparison. Metals were not highly correlated with NO₂ and showed higher spatial variation than NO₂. Regression models explained 61-85% of Cu, Cr, Mo, Pb, Sb, Sn, and Zn and 72% of NO₂ variability. Metals were strongly associated with the number of bus lines in the nearest street. Heavy metals are an alternative traffic-marker to NO₂ given their toxicological relevance, stronger association with local traffic and higher spatial variability. Monitoring heavy metals with mosses is appealing, particularly for long-term exposure assessment, as mosses can remain on site many months without maintenance.     

Vehicle wake factor for heterogeneous traffic in urban environments

Vehicles' 'wakes' are generated as a result of vehicular movements. They are one of the dominant factors in dispersing the pollutants in 'calm' meteorological conditions when wind velocity is <1 m/sec (Chock, 1978). They are used as a wind-speed-correction factor in several air quality models considering the effects of traffic movements on the pollutant dispersion. In this study, the vehicle wake factor (VWF) has been estimated using the inverse general finite line source model, GFLSM, (Luhar and Patil, 1989) for heterogeneous traffic conditions at one of the busiest traffic intersections of the Delhi city, near the Income Tax Office (ITO). The results show that in 'unstable' conditions, the VWF varies between 1.63 and 0.3 (for wind direction, θ = 90°) and 2.5 and 0.8 (for wind direction, θ = 180°). During 'neutral' and 'stable' conditions, it is in the range of 0.84–0.4, 1.91–0.85, (for wind direction θ = 270°) and 1.7–0.7, 3.1–0.3 for wind direction θ = 360°, respectively.     

Indoor/outdoor concentrations and indoor surface accumulations of ionic substances

The airborne concentrations of soluble ions in fine particles and coarse particles have been measured indoors and outdoors at telephone offices in Wichita, Kansas and Lubbock, Texas, These concentrations are compared with the mean annual indoor surface accumulations of these ions on zinc and aluminum structural surfaces. On average, the major soluble ions contained in fine airborne particles are ammonium, sulfate, and nitrate, while those contained in coarse particles are calcium and nitrate. In the fine mode, potassium and chloride have indoor/outdoor ratios that are larger than those observed for the other ionic species, indicating the existence of a significant indoor source. In the coarse mode, similar comparisons show that sodium, chloride, and sometimes sulfate have significant indoor sources. For chloride, a simple model has been used for apportioning surface accumulation at each location due to corrosive chlorine gases, coarse particles, and fine particles. For other ions where corrosive gases are not important, the accumulation has been apportioned between coarse and fine particles. From these data, experimental deposition velocities for fine mode sulfate ions and coarse mode calcium ions were calculated to be 0.003 and l.0 cms⁻¹, respectively, at Wichita, while those at Lubbock were 0.005 and 0.2 cms⁻.     

Time-resolved measurements of aerosol elemental concentrations in indoor working environments

We have measured the elemental concentrations in aerosols with a 2-h time resolution in two different types of working environment: a chemistry laboratory dealing with the processing of advanced nanoparticulate materials and a medium-sized machine workshop. Non-stop 10-day and 12-day samplings were performed at each location in order to determine the concentration trends during the non-working/working and weekday/weekend periods. Supplementary measurements of PM10 aerosols with a 2-day sample collection time were performed with a standard Gent PM10 sampler to compare the elemental concentrations with the time-averaged concentrations detected by the 2D step-sampler. The concentrations were determined a posteriori by analyzing the x-ray spectra of aerosol samples emitted after 3-MeV proton bombardment. The PM10 samples collected in the chemistry laboratory were additionally inspected by scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) to determine the chemical compositions of the individual particles. In the workshop, a total PM10 mass sampling was performed simultaneously with a minute resolution to compare the signal with typical outdoor PM10 concentration levels. A factor analysis of the time-resolved dataset points to six and eight factors in the chemistry laboratory and the machine workshop, respectively. These factors describe most of the data variance, and their composition in terms of different elements can be related to specific indoor activities and conditions. We were able to demonstrate that the elemental concentration sampling with hourly resolution is an excellent tool for studying the indoor air pollution. While sampling the total PM10 mass concentration with a minute resolution may lack the potential to identify the emission sources in a “noisy” environment, the time averaging on a day time scale is too coarse to cope with the working dynamics, even if elemental sensitivity is an option.     

Airborne concentrations of SARS-CoV-2 in indoor community environments in Italy

Environmental Science and Pollution Research - COVID-19 pandemic raised a debate regarding the role of airborne transmission. Information regarding virus-laden aerosol concentrations is still...     

Measurements of some potentially hazardous organic chemicals in urban environments

Three field studies were conducted in Los Angeles, California; Phoenix, Arizona; and Oakland, California, to better characterize the atmospheric abundance, fate and human exposure of selected organic chemicals that may be potentially hazardous. During field data collection, in-situ analysis using an instrumented mobile laboratory was performed for a total of 33 organics; a dozen of these are suspected carcinogens. The concentrations, variabilities and average daily dosages from exposure to these pollutants were determined. The diurnal behavior and the atmospheric fate of both primary and secondary pollutants were studied. Residence times for a typical polluted atmosphere were estimated. The atmospheric distributions and abundances of many species have been defined for the first time. Average daily-dose levels of all three sites for exposure to halomethanes (excluding fluorocarbons), haloethanes, chloroethylenes, chloroaromatics, aromatic hydrocarbons and secondary organics were determined to be 298, 142, 203, 21, 1880 and 257 μg d⁻¹ respectively. Exposure levels in Los Angeles were typically the highest and those in Oakland the lowest.     

Airborne PBDEs in specialized occupational settings, houses and outdoor urban areas in Greece

Airborne polybrominated diphenyl ethers (PBDEs) were measured in workplaces, homes and urban outdoor air in Greece. The geometric mean concentrations of total PBDEs (sum of 19 congeners) in offices (205pgm(-3)), internet cafes/computer rooms (127pgm(-3)) and computers/electronics shops (85pgm(-3)) were significantly higher than those in furniture stores (12pgm(-3)), homes (8pgm(-3)) and outdoor air (18pgm(-3)). The daily inhalation intake of PBDEs estimated for the employees of the four occupational settings ranged from 0.2 to 1.4ngday(-1) and it was significantly lower than the expected dietary intake ( approximately 77ngday(-1)). Although inhalation generally represented a small fraction of the overall daily exposure to PBDEs ( approximately 1%), the results from a heavily contaminated office (10 848pgm(-3) of total PBDEs) indicated that the intake from this route (65ngday(-1)) may, in some extreme cases, be as important as diet.     

Carbonaceous aerosol characteristics in outdoor and indoor environments of Nanchang, China, during summer 2009

A study of carbonaceous aerosol was initiated in Nanchang, a city in eastern China, for the first time. Daily and diurnal (daytime and nighttime) PM2.5 (particulate matter with aerodynamic diameter < or =2.5 microm) samples were collected at an outdoor site and in three different indoor environments (common office, special printing and copying office, and student dormitory) in a campus of Nanchang University during summer 2009 (5-20 June). Daily PM10 (particulate matter with aerodynamic diameter < or =10 microm) samples were collected only at the outdoor site, whereas PM2.5 samples were collected at both indoor and outdoor sites. Loaded PM2.5 and PM10 samples were analyzed for organic and elemental carbon (OC, EC) by thermal/optical reflectance following the Interagency Monitoring of Protected Visual Environments-Advanced (IMPROVE-A) protocol. Ambient mass concentrations of PM10 and PM2.5 in Nanchang were compared with the air quality standards in China and the United States, and revealed high air pollution levels in Nanchang. PM2.5 accounted for about 70% of PM10, but the ratio of OC and EC in PM2.5 to that in PM10 was higher than 80%, which indicated that OC and EC were mainly distributed in the fine particles. The variations of carbonaceous aerosol between daytime and nighttime indicated that OC was released and formed more rapidly in daytime than in nighttime. OC/EC ratios were used to quantify secondary organic carbon (SOC). The differences in SOC and SOC/OC between daytime and nighttime were useful in interpreting the secondary formation mechanism. The results of (1) OC and EC contributions to PM2.5 at indoor sites and the outdoor site; (2) indoor-outdoor correlation of OC and EC; (3) OC-EC correlation; and (4) relative contributions of indoor and outdoor sources to indoor carbonaceous aerosol indicated that OC indoor sources existed in indoor sites, with the highest OC emissions in I2 (the special printing and copying office), and that indoor EC originated from outdoor sources. The distributions of eight carbon fractions in emissions from the printer and copier showed obviously high OC1 (>20%) and OC2 (approximately 30%), and obviously low EC1-OP (a pyrolyzed carbon fraction) (<10%), when compared with other sources.     

Screening of organophosphorus compounds and their distribution in various indoor environments

Twelve organophosphorus compounds (OPs), which are used for diverse purposes (e.g. as plasticizers and flame retardants), were analysed in settled house dust from 15 indoor environments and in wipe test samples from computer screens and covers. Seven of the substances analysed dominated Swedish imports of OPs in 1999, six of these are also listed as EU High Production Volume Chemicals. Eight of the substances were found in all samples. Tris(2-butoxyethyl)phosphate was the most abundant in most of the samples, with levels ranging from 0.014 to 5.3 g/kg followed by tris(2-chloroethyl)phosphate, tris(chloropropyl)phosphate and tris(1,3-dichloropropyl)phosphate. In wipe test samples from computers, triphenyl phosphate proved to be the main component of the OPs analysed (4.0 microg/m2). Potential sources of these compounds include, inter alia, floor polish, polyvinylchloride floor coverings, upholstery and plastic products. The distribution patterns of the OPs differed between the sites and generally reflected the building materials and consumer products used in their vicinity.