The use of a metallothionein-like-proteins (MTLP) kinetic approach for metal bioavailability monitoring in dredged material

Ecotoxicological effects associated with contaminants present in dredged material from Spain were determined using a marine biotest based on the determination of metallothionein-like-protein concentrations (MTLPs) in the shore crab Carcinus maenas. Intermoult female C. maenas were exposed in the laboratory to sediments from three Spanish ports, Ría de Huelva (SW, Spain), La Coru?a (NW, Spain) and Bahía de Cádiz (SW, Spain) per replicate during 21 days. Hepatopancreas samples from crabs were taken for metallothioneins analysis on days 0, 7 and 21. Furthermore, chemical analysis was performed in the stations to determine the degree and nature of sediment contamination (Cr, Ni, Cu, Zn, Cd, Pb, Hg, As, PAHs and PCBs). A significant increase (p<0.05) in metallothionein concentration was observed over time in individuals exposed to sediment from the port Ría de Huelva characterized by high concentrations of metals. A toxicokinetic approach is proposed in this study related to the use of this biomarker in C. maenas to evaluate bioavailability associated with metals present in dredged material. As a first step, this toxicokinetic approach might reveal as a sensitive tool for evaluating bioavailability of contaminants present in dredged material.     

Determining sediment quality for regulatory proposes using fish chronic bioassays

Sediment quality assessments for regulatory purposes (i.e. dredged material disposal) are characterized by linking chemical and acute ecotoxicological data. The design of chronic bioassays that incorporate more sensible endpoints than acute tests is discussed to address sediment quality for environmental quality assessment and regulatory proposes. The chronic tests use juveniles of commercial species of fish Sparus aurata and Solea senegalensis, to assess sediment toxicity in samples collected along different littoral areas in the North and the South of Spain. The organisms were exposed during 60 days and sublethal endpoints were selected including biomarkers of exposure to metals (metallothioneins - MTs) and to organic contaminants (ethoxyresorufin-O-deethylase activity - EROD activity) and biomarkers of effect (histopathology in different tissues, gill and liver). A Multivariate Analysis Approach was conducted in order to associate these biological responses with sediment metal concentration from the ports and with chemical residues in biological tissues exposed to sediments under laboratory conditions.     

Availability and plant uptake of heavy metals from contaminated dredged material placed in flooded and upland disposal environments

The availability and plant uptake of heavy metals was evaluated from contaminated dredged material placed in flooded and upland disposal environments using a solid-phase plant bioassay. The objective of the study was to verify previous dredged material research results and to develop a plant bioassay procedure that could indicate phytotoxicity and bioaccumulation of heavy metals in contaminated dredged material. The plant bioassay indicated more uptake and bioaccumulations of cadmium and, to a lesser extent, zinc when contaminated dredged material was placed in an upland environment where the sediment was allowed to air-dry. Placing the contaminated dredged material in a flooded (reduced) environment lowered the availability and plant uptake of cadmium and, to a lesser extent, zinc. Factors that influenced the availability and plant uptake of heavy metals from contaminated sediments included sediment oxidation-reduction potential, organic matter content, total sulfur content, and pH. The plant bioassay showed phytotoxicity and bioaccumulation of arsenic under a flooded environment. Placing the arsenic-contaminated sediment in an upland environment reduced both the phytotoxicity and bioaccumulation of arsenic in the freshwater marsh plant Cyperus esculentus.     

Liquid versus solid phase bioassays for dredged material toxicity assessment

Since 1994 the results of the analyses of key chemical compounds (trace metals, polychlorinated biphenyls and polycyclic aromatic hydrocarbons) and the comparison with the corresponding sediment quality guidelines (SQGs) are used in decision-making for dredged material management in Spain. Nonetheless in the last decades a tiered testing approach is promoted for assessing the physical and chemical characteristics of dredged sediments and their potential biological effects in the environment. Bioassays have been used for sediment toxicity assessment in Spain but few or no experiences are reported on harbour sediments. We studied the incidence of toxicity in the 7 d bioassay using rotifers (Brachionus plicatilis) and the 48 h bioassay using sea urchin (Paracentrotus lividus) embryos over a series of experiments employing 22 different elutriates. The relative performance of this exposure phase was not comparable to data on the 10-d acute toxicity test using the burrowing amphipod Corophium volutator and the polychaete Arenicola marina, carried out on the whole sediments. These results evidence the importance of the exposure route and the test selected in decision-making, as the toxicity registered for the undiluted elutriates was largely due to the different solubility of sediment-bound contaminants. This work and other studies indicate that for many sediments, a complete battery of test is recommended together with physico-chemical analyses to decide whether dredged sediments are suitable for open water disposal or not.     

Hydrologic response to climate change and human activities in a subtropical coastal watershed of southeast China

It is essential to investigate hydrologic responses to climate change and human activities across different physiographic regions so as to formulate sound strategies for water resource management. Mann–Kendall, wavelet and geospatial analyses were coupled in this study, associated with ENSO indicators, flashiness index and baseflow index, in order to explore the hydrologic sensitivity to climate change and human activities in the Jiulong River Basin (JRB), a subtropical coastal watershed of southeast China. The results showed that the average annual precipitation presented an increasing trend (Z = 2.263, p = 0.024) and that this tendency has become weaker from estuary to inland in the JRB over the past 50 years. The annual frequency of rainstorm events increased from 3.4 to 5.2 days in the estuary and from 5.1 to 5.6 days in the West River, whereas it decreased from 6.0 to 5.5 days in the North River from 1954 to 2010. The 10-year average streamflow during 2001–2010 in the North River and West River decreased by 9.2 and 6.7 %, respectively, compared to the average annual streamflow during 1967–2000. Annual fluctuations were the most representative signals in streamflow variability for the North River and West River over the period 1967–2010. Human activities including dam construction, land change and socioeconomic development posed increasing influences on hydrologic conditions in the JRB. Seasonal variability of streamflow and sediment discharge changed significantly between the two periods divided by the jumping point (1992), identified when dams were constructed extensively in the North River and West River. This research provided important insights into the hydrologic consequences of climate change and human activities in a subtropical coastal watershed of southeast China.     

Contaminant mobility in diked containment areas

Nine dredged material land containment areas, located at upland, lowland, and island sites, were monitored during hydraulic dredging operations in fresh and brackish-water riverine, lake, and estuarine environments. Influent/effluent sampling at the diked disposal areas showed that, with proper retention of suspended solids, most chemical constituents could be removed to near background water levels. Most heavy metals, oil and grease, chlorinated pesticides, and PCBs were almost totally associated with solids in both the influent and effluent samples. The parameters that appear to have the greatest potential impact as a result of land disposal of dredged material are ammonia, soluble manganese, total mercury, and dissolved oxygen; soluble iron, zinc, and copper may occasionally exceed criteria or background levels.v However, none of these should present serious problems after dillution of the effluent discharge in the receiving waters. Actively growing vegetation in disposal areas appeared to be efficient in removing ammonium nitrogen to low levels and also for filtering out suspended solids. Dissolved oxygen in effluents ranged from 0.6 to 12.5 ppm. Geochemical phase partitioning of influent and effluent solids indicated that carbonate solids of several heavy metals tended to form during dredged slurry containment, promoted by high alkalinity and increased pH in site waters. Metal adsorption onto effluent suspended particles (exchangeable phase) increased slightly, along with a significant increase in cation exchange capacity.     

Release,distribution, and impacts of polychlorinated biphenyls (PCB) induced by dredged material disposal activities at a deep-water estuarine site

The aquatic disposal field investigation initiated in Elliott Bay, Puget Sound, WA, in February 1976, was designed to evaluate the ecological effects of open-water disposal of dredged material. The experimental disposal site was located at a depth of 60 m in marine estuary with generally weak circulation. Approximately 114,000 m³ of dredged material contaminated with polychlorinated biphenyls (PCBs) were dumped at the site from split-hull barges. The material presented in this paper is limited to a discussion of PCB impacts. It imcludes (a) a summary of results from the studies conducted between 1976 and 1977 to assess short-term impacts during and after the disposal of PCB contaminated sediments at the Elliott Bay disposal site; (b) a presentation of preliminary results from the continuation studies initiated in February 1979 to determine long-term impacts of the disposal operations. The preliminary data indicate that both dredged-material deposit and the associated PCBs appear to be stable. No major long-term impact on benthic organisms is apparent from this analysis.     

Laboratory study on sustainable use of cement–fly ash–polypropylene fiber-stabilized dredged material

The major problem associated with gravity dam was siltation of reservoir which reduced its effective water storage capacity. In order to maintain effective storage capacity of reservoir, dredging of deposits was required and dredged material was disposed of haphazardly causing damage to the sensitive environment. A better alternative could be the possibility of utilization of dredged deposits in construction works involving large quantities of material. The dredged material consisted of very fine sandy silt possessing poor geotechnical characteristics and was required to be stabilized with suitable additives before use as construction material. This laboratory investigation evaluated geotechnical properties of dredged reservoir material stabilized with cement, fly ash and fiber for its probable use as subbase in lightly trafficked roads. Compaction, unconfined compressive strength and tensile strength tests were performed on appropriate combinations of the constituent materials. The results of study revealed significant improvement in unconfined compressive strength and split tensile strength after stabilization with cement and fly ash. The unconfined compressive strength and split tensile strength of cement–fly ash-stabilized dredged reservoir material improved further upon addition of polypropylene fiber. The composite possessed the potential to be utilized as sustainable material in subbase of roads subject to further validation before application in the field. The dredging of sediments improved effective storage capacity of reservoir and increased its sustainable life period. The utilization of fly ash could diminish the environmental and economic concerns arising out of its haphazard disposal.     

Containment area sizing for disposal of dredged material

Procedures are given for containment area sizing for retention of suspended solids based on the settling characteristics of the dredged material. Separate sizing procedures for freshwater and saltwater sediments provide for determination of the respective surface area or detention time required to accomodate continuous dredged material disposal. Procedures are given for the laboratory testing required to obtain data for sediment characterization, containment area sizing, and estimates of storage capacity required. These procedures can also be used for designing containment areas for other slurries having high suspended solids concentrations. Settling tests performed in a 20-cm-diam column were found to be satisfactory for defining dredged material settling behavior. Settling behavior in the freshwater environment was best described by a flocculent settling test, while behavior in a saltwater environment was best described by a zone settling test. The same settling columns were used for both tests withonly minor procedural changes. Procedures are presented for designing new containment areas for suspended solids retention and for evaluating the suspended solids retention potential of existing containment areas during planned disposal activities.     

Policy,practice and decision making for zoonotic disease management: Water and Cryptosporidium

Decision making for zoonotic disease management should be based on many forms of appropriate data and sources of evidence. However, the criteria and timing for policy response and the resulting management decisions are often altered when a disease outbreak occurs and captures full media attention. In the case of waterborne disease, such as the robust protozoa, Cryptosporidium spp, exposure can cause significant human health risks and preventing exposure by maintaining high standards of biological and chemical water quality remains a priority for water companies in the UK. Little has been documented on how knowledge and information is translated between the many stakeholders involved in the management of Cryptosporidium, which is surprising given the different drivers that have shaped management decisions. Such information, coupled with the uncertainties that surround these data is essential for improving future management strategies that minimise disease outbreaks. Here, we examine the interplay between scientific information, the media, and emergent government and company policies to examine these issues using qualitative and quantitative data relating to Cryptosporidium management decisions by a water company in the North West of England. Our results show that political and media influences are powerful drivers of management decisions if fuelled by high profile outbreaks. Furthermore, the strength of the scientific evidence is often constrained by uncertainties in the data, and in the way knowledge is translated between policy levels during established risk management procedures. In particular, under or over-estimating risk during risk assessment procedures together with uncertainty regarding risk factors within the wider environment, was found to restrict the knowledge-base for decision-making in Cryptosporidium management. Our findings highlight some key current and future challenges facing the management of such diseases that are widely applicable to other risk management situations.     

Assessment of ecotoxicological risks related to depositing dredged materials from canals in northern France on soil

The implementation of an ecological risk assessment framework is presented for dredged material deposits on soil close to a canal and groundwater, and tested with sediment samples from canals in northern France. This framework includes two steps: a simplified risk assessment based on contaminant concentrations and a detailed risk assessment based on toxicity bioassays and column leaching tests. The tested framework includes three related assumptions: (a) effects on plants (Lolium perenne L.), (b) effects on aquatic organisms (Escherichia coli, Pseudokirchneriella subcapitata, Ceriodaphnia dubia, and Xenopus laevis) and (c) effects on groundwater contamination. Several exposure conditions were tested using standardised bioassays. According to the specific dredged material tested, the three assumptions were more or less discriminatory, soil and groundwater pollution being the most sensitive. Several aspects of the assessment procedure must now be improved, in particular assessment endpoint design for risks to ecosystems (e.g., integration of pollutant bioaccumulation), bioassay protocols and column leaching test design.     

Transhumant pastoralism,sustainable management of natural resources and endemic ruminant livestock in the sub-humid zone of West Africa

Transhumant pastoralism is one of the dominant livestock production systems in West Africa, and it is characterized by seasonal and cyclical movement of varying degrees between complementary ecological areas. The common pattern of transhumance is moving herds from areas with pasture and water scarcity such as the Sahelian zone to areas where the forage and water are found, often in the sub-humid zone. Whereas the transhumant herds from the Sahel are mainly Zebu breeds, endemic ruminant livestock (ERL) are the dominant breeds in sub-humid zone of West Africa because of their tolerance to tsetse-borne trypanosomosis disease. These livestock fulfill different functions in the livelihood of rural communities in the region. To identify potential areas of interventions for sustainable natural resource management to improve ERL productivity, a desk study that included spatial mapping was performed to review and document the existing knowledge on transhumance in West Africa. Additionally, group discussions were held to analyze the (actual or potential) effects of transhumant herds on natural resource management and ERL in the sub-humid zone. This study covered sub-humid zone in The Gambia, Guinea, Mali and Senegal. The key question we addressed in this study was as follows: What are the key trends and changes in transhumant pastoralism and how do these impact sustainable management of natural resources including endemic livestock? The results of the desk study and group discussions showed that there have been more southerly movements by transhumant pastoralists into the sub-humid zone over the past three decades and this has contributed to growing competition for grazing resources. The presence of transhumant herds in the sub-humid zone has a potential impact on management and conservation of ERL through crossbreeding with transhumant Zebu breeds from the Sahel but only study sites in Mali showed a high risk.     

长江口横沙附近河势变化与可利用港航资源分析

以1998/1999年长江流域洪水后奠定的河口河势为参照,利用四期大比例尺海图,数字化分析了1998/1999～2011年长江口北港河势与横沙东滩演变,讨论了北港和横沙东滩受河口重大工程影响产生的新变化。结果表明：青草沙水库工程稳定了北港河势;依托深水航道导堤工程和圈围工程,横沙东滩快速淤长,至2011年,-2 m、-5 m以上面积分别达到304 km2、522 km2,扣除深水航道坝田区面积,还有237 km2、450 km2;围绕横沙岛和横沙东滩,北岸可利用-10 m岸线达到16 km,在未来的7~23 a,可为上海的发展提供大量的新增岸线资源和土地资源。横沙北靠北港,南依长江口深水航道,东临东海;吹填成陆的横沙东滩土地资源丰富,经济地理位置优越,使得在横沙建设上海新港区成为可能     

Levels and trends of persistent organic pollutants in ringed seals (Phoca hispida) from Central West Greenland, with particular focus on polybrominated diphenyl ethers (PBDEs)

Polybrominated diphenyl ethers (PBDEs) and the organochlorine compounds polychlorinated biphenyls (PCBs), DDTs, HCB, chlordane-related pesticides, HCH and toxaphene were analysed in blubber of juvenile ringed seals from Central West Greenland collected between 1982 and 2006. The longest time series could be established for PBDEs, partly based on archived material, while PCBs and DDTs covered a study period from 1994-2006. All organochlorines showed decreasing trends, most pronounced for DDT and HCH with an annual change of 8%. BDE-47 had a significantly increasing trend of 5% annually. It was the only BDE congener consistently above the detection limit, with annual median concentrations between 0.78 ng/g lw to 3.54 ng/g lw, i.e. about 10 times lower than values from East Greenland observed in a similar time trend study on ringed seal blubber [Rigét F, Vorkamp K, Dietz R, Rastogi SC. Temporal trend studies on polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in ringed seals from East Greenland. J Environ Monit 2006; 8: 1000-5]. A clear East>West difference was also found for PCBs and DDTs, but not for chlordanes, toxaphene or HCHs. Sigma 10-PCB, Sigma DDT and Sigma Chlordanes had similar annual median concentrations, typically exceeding SigmaPBDE by two orders of magnitude. The concentrations of HCH and toxaphene were in an intermediate group, with highest annual median concentrations of 135 ng/g lw and 20 ng/g lw, respectively. For most compound groups, the circumpolar trend previously established under for example the Arctic Monitoring and Assessment Programme was confirmed, but apparently, more data are needed for chlordane-related compounds and toxaphene. Statistical analyses of the compound patterns in the ringed seal samples revealed significantly greater differences between seals from East and West than between different sampling years. Higher proportions of PCBs and DDTs and lower proportions of chlordanes and HCHs were found in seals from East Greenland than in those from West Greenland. Based on principal component analysis of individual congener and compounds, seals from East Greenland were found to contain higher proportions of the higher chlorinated CB congeners. Varying patterns between sampling locations may be caused by different exposure situations related to contaminant emissions and transport, but different feeding habits may also affect the contaminant composition.     

长江中下游干流港群空间结构的演化特征(1985～1997年)

以长江中下游干流沿岸为研究区域,探讨了１９８５年～１９９７年本区域港群的空间结构演化特征。统计分析表明,集中是和东或下注重港群空间结构演化的整体趋势,但同时伴随着较大的波动。整个港各和中下游各省地方港群赫佛因德指数的高低及其变化趋势说明中下游港群的集中状态处在低水平,而且这种低产集中和地方港群比较明显的分散趋势同时并存。此外,各地各不同水平的赫佛因德指数也表明了它们在集中程度上的明显差异。通过进一     

Conflicts between stakeholder groups affecting the ecology and economy of the Segara Anakan region

This study analyses how the conflict potential between different stakeholder groups is affecting the ecology and economy of the Segara Anakan region, a mangrove-fringed lagoon in central Java, Indonesia. The lagoon’s increasing sedimentation/silting up and the area’s expanding population has led to various interest groups conflicting with one another over how the resources of the lagoon and its surrounding area are to be utilized. Conflicts arise between occupational and ethnic groups in the lagoon’s bordering villages in the context of a transformation from fisheries to wetland agriculture. Land and mangrove use is therefore a cause for conflict between multiple groups, including Javanese fishermen, Sundanese farmers from Central and West Java and external shrimp farm owners. A result of the “Segara Anakan Development Project”—an 8-year undertaking that began in 1996—is that the lagoon was frequently dredged. Due to the dredging and resulting contamination of the land, a regional clash was triggered between Sundanese farmers and Javanese fishers. Our study reveals that the conflict potential between the various interest groups in the Segara Anakan Lagoon area could be reduced if the scarcity of natural resources were alleviated. Religious aspects also play a large role in marine resource utilization. Recognizing that the human utilization of natural resources is strongly symbolic and thereby culturally defined, we unravel the resource conflicts in our study area and offer some strategic approaches towards more sustainable outcomes.     

生态型港口综合评价指标体系初探——以上海港为例

基于上海市建设生态型城市的长期目标,将港口作为城市生态系统中重要的子系统,对如何建设生态型港口提出了综合评价指标体系.通过筛选得到45项单因素指标,针对不同类型的港区有所分异,整个评价体系分为5个准则层(生态环境、经济效率、污染控制、环境管理、社会评价)和10个因素层(大气/声环境、生物资源、基底质量、经济发展、生产效率、循环经济、污染排放、清洁生产、环保投入、社会参与),并采用AHP(层次分析)法确定了各层次的权重分配.进而根据2005年上海港年均生产状况和2006年上半年的港区环境-资源调查,尝试对上海港7种主要类型(集装箱、件杂货/成品、多用途、干散、粮食港区、液散、客运)的15个港区进行了现状评估.然而,生态港评价系统的指标选取、权重制定、评估级别等实践与完善仍需要多学科和政府职能部门的参与.最后,项目还提出了水生态健康、航道淤积、生态风险、水陆景观等非定量生态港评价因子.     

Exploring regional futures,tools and methodologies

The new English regional governance framework presents fresh opportunities to direct regional development in a more sustainable direction. However, for the North West region it is yet to be seen how these aspirations can be reconciled with the strong 'pro-growth' aims of the regional economic strategy. Within this context, the nature and findings of two interlinked projects which aimed to investigate and model regional development processes are presented. The first, 4-sight, is a resource flow audit for the promotion of sustainable resource management. Focusing on mineral flows, a mass balance methodology is used to facilitate a clearer connection between the use of resources and the generation of waste. Findings from 4-sight were then used in a second project, Atlas^NW, involving the development of a digital atlas and future scenario model. Both projects make a useful contribution to the regional sustainability agenda through providing data and tools to underpin decision-making. Electronic Publication     

1961～2017年中国不同长历时暴雨与总降雨事件的空间分异特征对比研究

长历时强降雨事件所导致的城市内涝已经成为当前中国城市安全建设和发展的严峻问题,因此,研究不同长历时强降雨事件空间演变特征具有重要的意义。采用1961~2017年中国545个日值气象站点降水数据,从雨量和雨日2个属性,分析不同长历时暴雨和总降雨事件的总量特征、变化趋势和年际变率空间分异格局。结果表明：(1)中国不同长历时暴雨和总降雨事件均呈东南高-西北低的空间分异格局,且随着降雨历时的增加,量级较高的不同长历时暴雨和总降雨事件在空间分布上逐渐向东南沿海地区集聚,且空间高低分异特征逐渐趋于减小。在华西秋雨的影响下,华西地区总降雨雨日相比同纬度其它地区较高。(2)中国不同长历时暴雨雨量和雨日主要在东南地区呈增加趋势,西北地区增减不明显。总降雨雨量变化趋势在东南和西北呈增加趋势,而在两者中间过渡带呈减少趋势,且随着降雨历时增加,减少趋势地带向东南和西北地区扩张。不同长历时总降雨雨日变化趋势则呈南方减少北方增加态势。(3)中国历时2 d的暴雨雨量和雨日年际变率在农牧交错带及其毗邻地区最大,而历时3 d以上的暴雨雨量和雨日年际变率则呈东南大-西北的分异格局。中国不同长历时总降雨雨量和雨日年际变率整体上呈南高-方低的分异格局,且随着降雨历时的增加,年际变率较大的地区向中国南部地区扩张。     

How changes in diet and trade patterns have shaped the N cycle at the national scale: Spain (1961–2009)

During the last five decades (1961–2009), Spain has experienced a considerable expansion in the nutrient cycle of its agricultural sector and, in particular, a threefold increase in anthropogenic reactive nitrogen inputs, from 536 Gg N year^?1 in 1961–1965 to 1673 Gg N year^?1 in 2005–2009. Import of feed (soybean, cereals, and cakes) from America and Europe to supply a growing livestock population constitutes the largest share of this increase, along with intensification of synthetic fertilizer use. While in the early 1960s, Spain was nearly self-sufficient in terms of food and feed supply, the net import of agricultural products presently equals domestic crop production, when expressed in terms of nitrogen content (ca. 650 Gg N year^?1). The most important driver of this shift appears to be the rapid change in domestic consumption patterns, which evolved from a typical Mediterranean diet to an animal-protein-rich diet similar to the North European and American diets. Besides livestock production mostly for national consumption, the Spanish agricultural system has specialized in vegetal products with low N content such as olive oil, wine, vegetables, and citrus fruit, which are for the most part exported. The nitrogen load exported outside the Spanish borders by rivers is very low (6.5 % of the total net N input). As a result of the high import and low export of reactive nitrogen, the Spanish mainland is suffering from considerable pollution by local emissions of reactive nitrogen forms to air and water.