GROUNDWATER DISCHARGE AND ITS IMPACT ON SURFACE WATER QUALITY IN A CHESAPEAKE BAY INLET1

ABSTRACT: Surface water, groundwater, and groundwater discharge quality surveys were conducted in Cherrystone Inlet, on Virginia's Eastern Shore. Shallow groundwater below agricultural fields had nitrate concentrations significantly higher than inlet surface waters and shallow groundwater underlying forested land. This elevated nitrate groundwater discharged to adjacent surface waters. Nearshore discharge rates of water across the sediment-water interface ranged from 0.02 to 3.69 liters·m^?2·hr^?1 during the surveys. The discharge was greatest nearshore at low tide periods, and decreased markedly with increasing distance offshore. Vertical hydraulic heads, E_h, and inorganic nitrogen flux in the sediments followed similar patterns. Nitrate was the predominant nitrogen species discharged nearshore adjacent to agricultural land use, changing to ammonium farther offshore. Sediment nitrogen fluxes were sufficient to cause observable impacts on surface water quality; nitrate concentrations were up to 20 times greater in areas of groundwater discharge than in the main stem inlet water. Based on DIN:DIP ratios, nitrogen contributions from direct groundwater discharge and tidal creek inputs appear to be of significant ecological importance. This groundwater discharge links land use activity and the quality of surface water, and therefore must be considered in selection of best management practices and water quality management strategies.     

NONPOINT SOURCE POLLUTION POTENTIAL IN AN AGRICULTURAL WATERSHED IN NORTHWESTERN PENNSYLVANIA1

ABSTRACT: A 155,947 ha portion of the Shenango River watershed in western Pennsylvania was evaluated as to the potential impact of agriculture drainage on water quality. Approximately a third of the area is being used as either cropland or pasture with approximately an equal percentage in forest lands. Eleven subwatersheds were evaluated as to their potential for nonpoint source pollution according to the criteria established by the Pennsylvania Department of Environmental Resources for the Chesapeake Bay Pollution Abatement Program. The individual components and overall rating for each subwatershed were then evaluated as to their correlation with four water quality variables based on 104 samples collected at 26 sampling stations throughout the watershed. There was a significant correlation between the overall rating factor for each subwatershed and each of the four water quality variables. In general, the watershed delivery factor, animal nutrient factor, and management factors were correlated with fecal coliform and phosphorus in the receiving streams, whereas the ground water delivery factor appeared to be more important in determining nitrate concentrations in these streams. These results indicate that manure and nutrient management, along with the exclusion of livestock from streams and the enhancement and/or replacement of riparian wetlands, are important approaches in reducing agricultural impacts in fresh water ecosystems.     

EFFECTS OF LAND COVER AND GEOLOGY ON STREAM CHEMISTRY IN WATERSHEDS OF CHESAPEAKE BAY1

ABSTRACT: We measured the base‐flow stream chemistry in all the major physiographic provinces of the Chesapeake Bay drainage basin. The spatial variation of stream chemistry was closely related to differences in geology and land cover among the sampled watersheds. Some stream chemistry variables were strongly affected by geological settings in the watersheds while others were more influenced by land cover. The effects of land cover differed among chemical constituents and regions. Concentrations of Ca²⁺, Mg²⁺, pH, total alkalinity, and conductivity were mainly functions of carbonate bedrock, especially in the Great Valley. Nitrate‐N and total dissolved N were closely related to cropland and increased as the percentage of cropland increased. The rate of increase varied from region to region with the highest in the Piedmont. Na⁺ and Cl^? were mainly affected by the percentage of developed area in a watershed, especially in the Coastal Plain and Piedmont. We observed no significant effects of region or land cover on species of phosphorus because samples were collected under base flow conditions and only dissolved forms were measured. Dissolved silicate (DSi) was not related to any other water chemistry variables. DSi increased as developed area decreased and cropland increased in the Coastal Plain, but these patterns were reversed in the Piedmont. There was no consistent pattern in the spatial variation of land cover effects on the reduced forms of N, dissolved organic P, dissolved organic matter, and K⁺.     

PRIORITIZING NONPOINT SOURCE PHOSPHORUS LOADING USING A GRASS-MODELING SYSTEM1

ABSTRACT: A UNIX-based windows application was developed to integrate a phosphorus transport model with the Geographic Resources Analysis Support System (GRASS). The system prioritizes potential phosphorus loading from fields or cells in a watershed and can evaluate the effects of alternate management practices on phosphorus yield. The model simulates phosphorus loading by using a daily mass balance on a unit-area basis and incorporates the effects from rainfall, topography, soil properties, fertilizer and animal waste application, and management. Model predictions include dissolved and sediment-bound phosphorus yield, runoff volume, and sediment yield. Within the integrated GRASS-modeling system, the user can obtain model input data, execute the model using various options, rank model input and out. put data, and display them as GRASS-based maps or data tables. All functions are menu driven, developed using C language and X-window tools to run on a SUN workstation platform. The system provides a powerful and efficient tool for prioritizing phosphorus loading from nonpoint sources.     

PATTERNS OF PERIPHYTON CHLOROPHYLL α IN AN AGRICULTURAL NONPOINT SOURCE IMPACTED STREAM1

ABSTRACT: An agricultural nonpoint source polluted stream in northern Idaho was examined to determine seasonal and longitudinal patterns of periphyton chlorophyll α. Chlorophyll a was measured at eight sites along Lapwai Creek, a fifth order stream impacted by agricultural runoff containing nutrients and eroded soils. Seasonally, periphyton chlorophyll α was lowest in the spring (cumulative x?= 60.4 mg m^?2) and highest in the summer (cumulative x?= 222 mg m^?2). Winter concentrations were higher than expected (cumulative x?= 168.6 mg m^?2). The headwaters, flowing through an open grassy meadow, had the lowest concentrations of the study (two-year x?= 49.7 mg m^?2). Immediately below a small, eutrophic reservoir, periphyton chlorophyll α increased markedly (two-year x?= 155.8 mg m^?2) and remained high through a deep canyon (two year x?= 135.5 mg m^?2) and down to the mouth of the stream (two-year x?= 172.3 mg^?2). Periphyton chlorophyll α in Lapwai Creek was at least two times greater than values reported in the literature for comparable, undisturbed Idaho streams. We suggest that increased nutrient concentrations via agricultural nonpoint source pollution and increased light penetration from the removal of large, woody riparian vegetation have resulted in high periphyton chlorophyll α along the continuum of Lapwai Creek.     

IDENTIFICATION OF CRITICAL NONPOINT POLLUTION SOURCE AREAS USING GEOGRAPHIC INFORMATION SYSTEMS AND WATER QUALITY MODELING1

n integrated approach coupling water quality computer simulation modeling with a geographic information system (GIS) was used to delineate critical areas of nonpoint source (NPS) pollution at the watershed level. Two simplified pollutant export models were integrated with the Virginia Geographic Information System (VirGIS) to estimate soil erosion, sediment yield, and phosphorus (P) loading from the Nomini Creek watershed located in Westmoreland County, Virginia. On the basis of selected criteria for soil erosion rate, sediment yield, and P loading, model outputs were used to identily watershed areas which exhibit three categories (low, medium, high) of non-point source pollution potentials. The percentage of the watershed area in each category, and the land area with critical pollution problems were also identified. For the 1505-ha Nomini Creek watershed, about 15, 16, and 21 percent of the watershed area were delineated as sources of critical soil erosion, sediment, and phosphorus pollution problems, respectively. In general, the study demonstrated the usefulness of integrating GIS with simulation modeling for nonpoint source pollution control and planning. Such techniques can facilitate making priorities and targeting nonpoint source pollution control programs.     

RURAL NONPOINT SOURCE POLLUTION CONTROL IN WISCONSIN: THE LIMITS OF A VOLUNTARY PROGRAM?1

ABSTRACT: This paper examines the relationship between best-management practices, institutional needs, and improved water quality within the watersheds of Wisconsin's program for controlling rural nonpoint source pollution. The first section describes the federal requirements for state nonpoint source programs and the legislative and management methods the state of Wisconsin uses to put those requirements into practice. The emphasis of the paper, described in the second section, is the institutional difficulty in evaluating the success of a large, integrated water quality program. Measurements which are investigated include (1) watershed water quality before and after implementation of BMPs; (2) program participation as measured by eligible vs. participating landowners, BMPs considered necessary vs. BMPs implemented, or dollars allocated to the NPS program vs. dollars expended; and (3) institutional goal coordination and management effectiveness. It is found that, despite the size and sophistication of Wisconsin's NPS program, there is little if any improvement in ambient water quality in these watersheds, probably because of a general lack of adequate participation in this voluntary program.     

SUSCEPTIBILITY OF INDIANA WATERSHEDS TO HERBICIDE CONTAMINATION1

ABSTRACT: An index of watershed susceptibility to surface water contamination by herbicides could be used to improve source water assessments for public drinking water supplies, prioritize watershed restoration projects, and direct funding and educational efforts to areas where the greatest environmental benefit can be realized. The goal of this study is to use streamflow and herbicide concentration data to develop and evaluate a method for estimating comparative watershed susceptibility to herbicide loss. United States Geological Survey (USGS) concentration data for five relatively water soluble herbicides (alachlor, atrazine, cyanazine, metolachlor, and simazine) were analyzed for 16 Indiana watersheds. Correlation was assessed between observed herbicide losses and: (1) a herbicide runoff index using GIS‐based land use, soil type, SCS runoff curve number, tillage practice, herbicide use estimates, and combinations of these factors; and (2) predicted herbicide losses from a non‐point source pollution model (NAPRA‐Web, an Internet‐based interface for GLEAMS). The highest adjusted R²value was found between herbicide concentration and the runoff curve number alone, ranging from 0.25 to 0.56. Predictions from the simulation model showed a poorer correlation with observed herbicide loss. This indicates potential for using the runoff curve number as a simple herbicide contamination susceptibility index.     

INCENTIVE-BASED NONPOINT SOURCE POLLUTION ABATEMENT IN A REAUTHORIZED CLEAN WATER ACT1

ABSTRACT: This paper summarizes key provisions of the Clinton Administration's proposals for change in the Clean Water Act. Two of the important themes for change are tougher controls for non-point source pollution and the use of market-based instruments. A detailed analysis of market-based abatement suggests limited potential for reducing costs. The keys to nonpoint source pollution control are clearer definition of property rights combined with changes in government programs that encourage polluting activities.     

FOREST PRACTICES AS NONPOINT SOURCES OF POLLUTION IN NORTH AMERICA1

ABSTRACT: Forest management activities may substantially alter the quality of water draining forests, and are regulated as nonpoint sources of pollution. Important impacts have been documented, in some cases, for undesirable changes in stream temperature and concentrations of dissolved oxygen, nitrate-N, and suspended sediments. We present a comprehensive summary of North American studies that have examined the impacts of forest practices on each of these parameters of water quality. In most cases, retention of forested buffer strips along streams prevents unacceptable increases in stream temperatures. Current practices do not typically involve addition of large quantities of fine organic material to streams, and depletion of streamwater oxygen is not a problem; however, sedimentation of gravel streambeds may reduce oxygen diffusion into spawning beds in some cases. Concentrations of nitrate-N typically increase substantially after forest harvesting and fertilization, but only a few cases have resulted in concentrations approaching the drinking-water standard of 10 mg of nitrate-NIL. Road construction and harvesting increase suspended sediment concentrations in streamwater, with highly variable results among regions in North America. The use of best management practices usually prevents unacceptable increases in sediment concentrations, but exceptionally large responses (especially in relation to intense storms) are not unusual.     

ENHANCEMENTS OF NONPOINT SOURCE MONITORING OF VOLATILE ORGANIC COMPOUNDS IN GROUND WATER1

ABSTRACT: The U.S. Geological Survey (USGS) has compiled a national retrospective data set of analyses of volatile organic compounds (VOCs) in ground water of the United States. The data are from Federal, State, and local nonpoint‐source monitoring programs, collected between 1985–95. This data set is being used to augment data collected by the USGS National Water‐Quality Assessment (NAWQA) Program to ascertain the occurrence of VOCs in ground water nationwide. Eleven attributes of the retrospective data set were evaluated to determine the suitability of the data to augment NAWQA data in answering occurrence questions of varying complexity. These 11 attributes are the VOC analyte list and the associated reporting levels for each VOC, well type, well‐casing material, type of openings in the interval (screened interval or open hole), well depth, depth to the top and bottom of the open interval(s), depth to water level in the well, aquifer type (confined or unconfined), and aquifer lithology. VOCs frequently analyzed included solvents, industrial reagents, and refrigerants, but other VOCs of current interest were not frequently analyzed. About 70 percent of the sampled wells have the type of well documented in the data set, and about 74 percent have well depth documented. However, the data set generally lacks documentation of other characteristics, such as well‐casing material, information about the screened or open interval(s), depth to water level in the well, and aquifer type and lithology. For example, only about 20 percent of the wells include information on depth to water level in the well and only about 14 percent of the wells include information about aquifer type. The three most important enhancements to VOC data collected in nonpoint‐source monitoring programs for use in a national assessment of VOC occurrence in ground water would be an expanded VOC analyte list, recording the reporting level for each analyte for every analysis, and recording key ancillary information about each well. These enhancements would greatly increase the usefulness of VOC data in addressing complex occurrence questions, such as those that seek to explain the reasons for VOC occurrence and nonoccurrence in ground water of the United States.     

NUTRIENT CONTRIBUTION OF NONPOINT SOURCE RUNOFF IN THE LAS VEGAS VALLEY1

ABSTRACT: A Geographic Information System (GIS) based non‐point source runoff model is developed for the Las Vegas Valley, Nevada, to estimate the nutrient loads during the years 2000 and 2001. The estimated nonpoint source loads are compared with current wastewater treatment facilities loads to determine the non‐point source contribution of total phosphorus (TP), total nitrogen (TN), and total suspended solids (TSS) on a monthly and annual time scale. An innovative calibration procedure is used to estimate the pollutant concentrations for different land uses based on available water quality data at the outlet. Results indicate that the pollutant concentrations are higher for the Las Vegas Valley than previous published values for semi‐arid and arid regions. The total TP and TN loads from nonpoint sources are approximately 15 percent and 4 percent, respectively, of the total load to the receiving water body, Lake Mead. The TP loads during wet periods approach the permitted loads from the wastewater treatment plants that discharge into Las Vegas Wash. In addition, the GIS model is used to track pollutant loads in the stream channels for one of the subwatersheds. This is useful for planning the location of Best Management Practices to control nonpoint pollutant loads.     

ESTIMATING MARYLAND CRITICAL AREA ACVS IMPACT ON FUTURE NONPOINT POLLUTION ALONG THE RHODE RWER ESTUARY1

ABSTRACT: This paper presents the results of an investigation of the effects of the Maryland Critical Area Act on generation of non-point source loads of phosphorus, nitrogen, and sediment to the Rhode River estuary. The Simple Method model, the Marcus and Kearney regression model, and the CREAMS model were used to estimate annual loads under: (1) present conditions, (2) maximum land use development allowable under the Act, and (3) two sets of future land use conditions that might occur if the Act were not in place. Results indicate that the Critical Area Act can reduce the present generation of nonpoint nutrient and sediment loadings 20–30 percent from the regulated area. These reductions can occur while preserving agricultural lands and allowing limited residential and urban development. The decrease in nutrient loadings is primarily dependent upon implementation and enforcement of agricultural best management practices (BMPs). The BMPs could reduce present agricultural nutrient loadings by 90 percent to a level comparable to loadings from residential areas. The estimated effectiveness of the Critical Area Act is even greater when compared to potential future nutrient loadings if development in the area remains unregulated. Unrestricted residential and urban development could increase nutrient loadings by 200 percent to 1000 percent as compared to controlled development under Critical Area Act guidelines. The Critical Area Act primarily prevents these future increases by severely limiting woodland cutting, with lesser results obtained by requiring urban BMPs.     

MUNICIPAL POINT SOURCE AND AGRICULTURAL NONPOINT SOURCE CONTRIBUTIONS TO COASTAL EUTROPHICATION1

ABSTRACT: Tidally influenced reaches of several coastal rivers in eastern North Carolina are suffering from very serious water quality problems — massive surface blooms of noxious blue-green algae, major fish kills from anoxic water, epidemics of red sore disease among fish, fresh water intrusion into estuarine waters, and declining commercial and sports fisheries. An intensive investigation of point source and nonpoint source inputs of nutrients was conducted in one of the eutrophic rivers, the Chowan River. Nonpoint source loading dominated the estimated annual flu of nutrients from the river basin. Automated water quality samplers were utilized to record nutrient levels in stormflow and baseflow from several small agricultural watershed in the basin. Levels of nitrate nitrogen and total phosphorus were from five to 40 times greater in these agricultural watersheds than levels in mostly forested watersheds. Existing water quality data in these eutrophic river basins implicate agricultural activities – particularly animal operations and cropland in watersheds with extensive drainage improvements – as the major contributing factor to the water quality problems.     

EVALUATION OF BEST MANAGEMENT PRACTICES FOR CONTROLLING NONPOINT POLLUTION FROM SILVICULTURAL OPERATIONS1

ABSTRACT: Fifteen years of streamflow and water quality data were evaluated to determine the effectiveness of Best Management Practices (BMP's) in controlling nonpoint source pollution from an 110. acre commercial clearcut located in the Ridge and Valley Province of central Pennsylvania. The analyses addressed both short- and long-term changes in the physical and chemical properties and the hydro-logic regime of the stream draining this 257-acre watershed. Overall, the BMP's employed on this commercial clearcut were very effective in preventing serious deterioration of stream quality as a result of forest harvesting. Although statistically significant increases in nitrate and potassium concentrations and temperature and turbidity levels were measured the first two years following harvesting, the increases were relatively small and, with the exception of turbidity, within drinking water standards. Nevertheless, such increases may violate EPA's anti-degradation policy. Nitrate and potassium concentrations and turbidity levels remained above pre-harvesting levels for as long as nine years following harvesting. Clearcutting also significantly increased water yield, which in turn initially lowered the concentrations of most solutes because of dilution. Increased water yields returned to pro-harvesting levels within four years as a result of rapid regrowth. The export of some ions increased; however, the increased export appeared to be insufficient to affect site fertility. Implementation of periodic post-harvest inspections of harvested areas, increasing the width of the buffer zone, and utilizing buffer zones on all perennial and intermittent channels would reduce further impacts of silvi-cultural activities on water quality.     

MODELING PREVENTION ALTERNATWES FOR NONPOINT SOURCE POLLUTION AT A WELLFIELD IN FLORIDA1

ABSTRACT: Agricultural and urban activities in the West Wellfield Interim Protection Area (WWIPA), located in West Dade County in South Florida, have the potential to impact both the environmentally sensitive Everglades and the Biscayne Aquifer. The Hydrological Simulation Program-FORTRAN (HSPF) is used to simulate surface runoff, ground water recharge, and transport of sediments, nutrients, and pesticides in the WWIPA, as a basis to quantify impacts and evaluate alternatives. Presented are four model test runs that consider current conditions, the effect of future urbanization of the agricultural land, as well as two preventive actions to minimize pollution levels. Preventive actions include application of minimum required rates of fertilizers and replacement of fertilizers by sewage sludge. Model results show that under current practices, sediments, nutrients, and pesticides are present in surface runoff and nutrients enter the ground water, and that both urbanization and preventive actions result in pollutant reductions.     

IMPACT OF RIPARIAN FOREST BUFFERS ON AGRICULTURAL NONPOINT SOURCE POLLUTION1

ABSTRACT: A field monitoring study of a riparian forest buffer zone was conducted to determine the impact of the riparian ecosystem on reducing the concentration of agricultural nonpoint source pollutants. Groundwater samples were collected from 20 sampling locations between May 1993 and December 1994, and analyzed for NO₃-N, PO₄, and NH₄-N. Statistical analyses such as Friedman's test, cluster analysis, cross correlation analysis and Duncan's test were performed for the nutrient data. The study showed that the ripanan buffer zone was effective in reducing nitrate concentrations originating from upland agricultural fields. Instream nitrate concentrations were 48 percent less than those measured in the agricultural field. Reductions in concentrations in sampling locations at the wetland edge ranged from 16 to 70 percent. The mean nitrate concentrations in forested hill slope were 45 percent less than concentrations in a well located in an upland agricultural field. Meanwhile, the concentrations of phosphate and ammonia did not follow any specific spatial trend and were generally higher during the summer season for most sampling locations.     

REGULATING NONPOINT SOURCE POLLUTION IN SURFACE WATERS: A PROPOSAL1

ABSTRACT: Nonpoint sources (NPS) are an important and continuing source of toxic and conventional pollutants to surface waters. The Clean Water Act amendments of 1987 call for the regulation of these sources through the use of Best Management Practices (BMP). However, BMP implementation has generally occurred on a voluntary basis. This paper proposes a regulatory mechanism to control nonpoint source pollution. The regulatory mechanism involves the development of consortia, made up of all parties potentially responsible for NPS pollution, the development of wasteload allocations that coordinate the pollutant contributions from both point and nonpoint sources in a stream segment, and the issuance of permits to consortia to regulate the impacts of NPS pollution and ensure achievement of state or federal Water Quality Criteria and Standards.     

MODELING OF NONPOINT SOURCE POLLUTION OF NITROGEN AT THE WATERSHED SCALE1

ABSTRACT: The Watershed Nutrient Transport and Transformation (NTT-Watershed) model is a physically based, energy-driven, multiple land use, distributed model that is capable of simulating water and nutrient transport in a watershed. The topographic features and subsurface properties of the watershed are refined into uniform, homogeneous square grids. The vertical discretization includes vegetation, overland flow, soil water redistribution and groundwater zones. The chemical submodel simulates the nitrogen dynamics in terrestrial and aquatic systems. Three chemical state variables are considered (NO₃^-_-, NH₄⁺, and Org-N). The NTT-Watershed model was used to simulate the fate and transport of nitrogen in the Muddy Brook watershed in Connecticut. The model was shown to be capable of capturing the hydrologic and portions of the nitrogen dynamics in the watershed. Watershed planners could use this model in developing strategies of best management practices that could result in maximizing the reductions of nitrogen export from a watershed.     

COST‐EFFECTIVE POINT‐NONPOINT TRADING: AN APPLICATION TO THE SUSQUEHANNA RIVER BASIN1

ABSTRACT: Point‐nonpoint trading has been suggested as a relatively efficient approach for reducing nutrient pollution in the Chesapeake Bay and elsewhere. However, relatively little economic research has examined the design of trading programs involving nonpoint sources. The purpose of this paper is to investigate the economics of several fundamental design choices for point‐nonpoint trading programs. The Susquehanna River Basin (SRB) in Pennsylvania as an example, although many of the insights should generally apply to other regions as well.