DISTRIBUTION AND GRAIN-SIZE PARTITIONING OF METALS IN BOVFOM SEDIMENTS OF AN EXPERIMENTALLY ACIDIFIED WISCONSIN LAKE1

ABSTRACT: A study of concentrations and distribution of major and trace elements in surficial bottom sediments of Little Rock Lake in northern Wisconsin included examination of spatial variation and grain-size effects. No significant differences with respect to metal distribution in sediments were observed between the two basins of the lake, despite the experimental acidification of one of the basins from pH 6.1 to 4.6. The concentrations of most elements in the lake sediments were generally similar to soil concentrations in the area and were well below sediment quality criteria. Two exceptions were lead and zinc, whose concentrations in July 1990 exceeded the criteria of 50 μg/g and 100 μg/g, respectively, in both littoral and pelagic sediments. Concentrations of some elements, particularly Cu, Pb, and Zn, increased along transects from nearshore to midlake, following a similar gradient of sedimentary organic carbon. In contrast, Mn, Fe, and alkali/alkaline-earth elements were at maximum concentrations in nearshore sediments. These elements are less likely to partition to organic particles, and their distribution is more dependent on mineralogical composition, grain size, and other factors. Element concentrations varied among different sediment grain-size fractions, although a simple inverse relation to grain size was not observed. Fe, Mn, Pb, and Zn were more concentrated in a grain-size range 20–60 tm than in either the very fine or the coarse fractions, possibly because of the aggregation of smaller particles cemented together by organic and Fe/Mn hydrous-oxide coatings.     

LEAD AND CADMIUM ASSOCIATED WITH SALTWATER INTRUSION IN A NEW JERSEY AQUIFER SYSTEM1

ABSTRACT: The U.S. Geological Survey collected ground-water samples from the upper and middle aquifers of the Potomac-Raritan-Magothy aquifer system in a 400-square-mile area of New Jersey from 1984 through 1986. Concentrations of lead were greater than the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 50 micrograms per liter in water from 16 of 239 wells. The cencentrations of cadmium were greater than the MCL of 10 micrograms per liter in water from 10 to 241 wells. One-half of the wells that exceeded the lead MCL were in known areas of saltwater intrusion, as were all 10 wells that exceeded the cadmium MCL. The association of elevated concentrations of these metals with elevated concentrations of chloride indicates a mochanism related to saltwater intrusion.     

TRACE ELEMENTS IN NORTHERN GREAT PLAINS STRIP MINE AND LIVESTOCK IMPOUNDMENT WATER1

ABSTRACT: The water from 32 strip mine water impoundments and nine livestock watering ponds in North Dakota, South Dakota, and Wyoming were analyzed for trace elements. Because of the high concentrations of trace elements in coal and bentonite clay, the possibility exists for these elements to dissolve or be suspended in the water. Strip mine ponds were not significantly higher in trace element concentrations compared to livestock ponds. All but one of the 41 ponds sampled contained elemental concentrations that would be detrimental for livestock use or aquatic life use. Cadmium and lead were the elements most frequently in excess of water quality crieria. Lead was found in the study ponds about 35 times the median concentration of North American rivers. Manganese concentrations were found to exceed iron in many ponds, which is unusual in natural waters. The potential for detrimental concentrations of trace elements in pond water must be evaluated when designing land use management plans for ponds intended to be used by livestock or aquatic life.     

THE EFFECT OF FLOOD PLAIN LOCATION ON PROPERTY VALUES: THREE TOWNS IN NORTHEASTERN NEW JERSEY1

ABSTRACT: The persistence of development and settlement in flood plains and continued damages from flooding, raises the question of how property owners respond to flood plain location and whether property values reflect this response. Existing studies disagree on the significance of flood hazard for property values. This study evaluates the effect of flood plain location on assessed valuation and home value in three towns in New Jersey. A t-test on mean assessed value and value of owner-occupied units at block levels showed no statistically significant variation for flood prone and nonflood prone lands. Possible explanations are that homeowners do not know or perceive the risk of living in flood plains, assessors do not incorporate flooding into assessment criteria, and the National Flood Insurance Program subsidies and broadened financial markets may equalize property values.     

POTENTIAL EFFECTS OF DEVELOPMENT ON FLOW CHARACTERISTICS OF TWO NEW JERSEY STREAMS1

ABSTRACT: Parts of the Raritan River basin in central New Jersey have undergone increasing development over the last several decades. The increasing population relies on the region's ground water and surface water sources for its residential, commercial, and industrial water supply. Urbanization, regionalized wastewater-treatment facilities, stream channel alterations, and interbasin transfers of water can all affect water availability. This pilot study was conducted to determine whether significant trends exist in the base-flow and overland-runoff characteristics of streams in two subbasins with different percentages of urban/built-up land (Anderson et at., 1976). Changes in flow characteristics that could indicate future reductions in safe water yield of the Raritan River basin were examined. Flow and flow variability of the steams draining these two subbasins have increased over time. Many of the flow measures studied experienced pronounced trend shifts about 1960. The cause of these changes cannot be readily determined from the data, nor is it clear whether the increased flow variability lies outside the natural range of flow variability of the streams draining the subbasins.     

VARIABLES INDICATING NITRATE CONTAMINATION IN BEDROCK AQUIFERS,NEWARK BASIN,NEW JERSEY1

ABSTRACT: Variables that describe well construction, hydrogeology, and land use were evaluated for use as possible indicators of the susceptibility of ground water in bedrock aquifers in the Newark Basin, New Jersey, to contamination by nitrate from the land surface. Statistical analyses were performed on data for 132 wells located throughout the Newark Basin. Concentrations of nitrate (as nitrogen) did not exceed the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter (mg/L) in any of the water samples (U.S. Environmental Protection Agency, 1991). Variables that describe hydrogeology and well construction were found not to be statistically significant in relation to concentrations of nitrate. This finding can be attributed to the complex nature of flow in bedrock aquifers and mixing of water from shallow and deep water-bearing zones that occurs within these wells, which are constructed with long open intervals. Distributions of nitrate concentrations were significantly different among land-use groups on the basis of land use within both a 400 and an 800-m radius zone of the well. The median concentrations of nitrate (as N) in water from wells in predominantly urban-residential (2.5 mg/L) and agricultural areas (1.8 mg/L) were greater than the median concentration of nitrate in water from wells in predominantly undeveloped areas (0.5 mg/L).     

COMPARISON OF TRACE ELEMENT CONCENTRATIONS IN TISSUE OF COMMON CARP AND IMPLICATIONS FOR MONITORING1

Common carp (Cyprinus carpio) collected from four sites in the Red River of the North in 1994 were analyzed for arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), nickel (Ni), selenium (So), and zinc (Zn). Concentrations differed among liver, muscle, and whole body. Generally, trace element concentrations were the greatest in livers while concentrations in whole bodies were greater than those in muscle for Cd, Cu, Ni, Pb, and Zn, and concentrations in muscle were similar to whole body for As and Se. Concentrations of Cr were lower in liver than either muscle or whole body. Correlations between liver and whole body concentrations were stronger than those between liver and muscle concentrations, but the strongest correlations were between muscle and whole body concentrations. Examination of tissue concentrations by collection sites suggested that, for a general survey, the whole body may be the most effective matrix to analyze.     

MANAGEMENT MODEL FOR CONTROLLING NITRATE CONTAMINATION IN THE NEW JERSEY PINE BARRENS AQUIFER1

ABSTRACT: Land use planning in rapidly developing areas can serve as an effective tool for minimizing water quality impacts on ground water supplies. A land use management model applied to Jackson Township of the New Jersey Pine Barrens was developed. The management model consisted of a simulation model for the transport of nitrates from septic tank systems through the aquifer and a multiobjective, goal programming optimization model to determine population density restrictions using 208 areawide planning population projections. Results showed that growth may have to be curtailed in several areas of Jackson Township and that current population projections over the next 30 years may result in unacceptably high nitrate concentrations downgradient of Jackson Township. The management framework provides a flexible approach to land use planning.     

IMPACT OF DROUGHT ON QUALITY IN A NEW JERSEY WATER SUPPLY SYSTEM1

ABSTRACT. New Jersey, together with other states in the northeast, was stricken with drought during 1961-66. The effect of this drought was most severe in the northern part of the State. The water quality of the Passaic River, which drains the urban, industrialized northeast, perhaps deteriorated the most among the major drainage systems. This river system is used as a raw-water source by 10 water suppliers. The impact of the drought upon the water supply of the Passaic Valley Water Commission, the most downstream of the basin's suppliers, which supplies an average of about 90 million gallons a day to more than 650,000 persons, is evaluated herein. The drought's impact on the raw-water quality is appraised by the comparison of before-and-after qualities of dissolved solids, dissolved oxygen, biochemical-oxygen demand, turbidity, and hardness. For example, at the worst point during the drought, monthly average dissolved-solids content in the raw water were about 210 percent, hardness, about 167 percent, and biochemical-oxygen demand about 270 percent higher than antecedent values. In general, the study concludes that the drought produced a deterioration in both raw and finished water quality, and is estimated to have increased chemical-treatment costs during the drought by about $650,000.     

TRACE METALS IN SEDIMENT: SPATIAL TRENDS AND SORPTION PROCESSES1

ABSTRACT: Sediment bound trace metals are often examined for spatial trends such as downstream patterns or distance from a source. Spatial trends may indicate either differences in metal inputs, or, when considerable sediment variability exists, differences in sediment sorption processes. These two possibilities become important not only when sediment contamination is evaluated within an area, but also when regulatory agencies attempt to make equivalent among area decisions. Sediments from an urban watershed were examined for: (1) downstream trace metal trends and (2) sediment sorption relationships. Analyses determined that downstream trenda as related to metal inputs could not be recognized by analyzing the < 2mm (≤, sand) sediment size fraction. Conversely, the trace metal concentrations were found to be distinctly related to sediment characteristics. The watershed's metal concentrations are similar to those found in uncontaminated to slightly contaminated sediments in the United States.     

GEOCHEMICAL CHARACTERIZATION OF STREAMBED SEDIMENT IN THE UPPER ILLINOIS RWER BASIN1

ABSTRACT: Geochemistry of fine-fraction streambed sediments collected from the upper illinois River basin was surveyed in the fall of 1987 as part of the U.S. Geological Survey National Water-Quality Assessment pilot projects. The survey included 567 samples analyzed for 46 elements. Three distinctive distribution patterns were found for seven U.S. Environmental Protection Agency priority pollutants surveyed, as well as for boron and phosphorus: (1) enrichment of elements in the Chicago urban area and in streams draining the urban area relative to rural areas, (2) enrichment in main stems relative to tributaries, and (3) enrichment in low-order streams at high-population-density sites relative to low-population-density sites. Significant differences in background concentrations, as measured by samples from low-order streams, were observed among five subbasins in the study area. Uncertain geochemical correspondence between low-order, background sites and high-order, generally metal enriched sites prevented determination of background levels that would be appropriate for high-order sites. The within-sample ratio of enriched elements was variable within the Chicago area but was constant in the Illinois River downstream from Chicago. Element ratios imply a composite fine-fraction sediment in the Illinois River of 35–40 percent Des Plaines River origin and 60–65 percent Kankakee River origin.     

EFFECTS OF LAND USE AND TOPOGRAPHY ON SOME WATER QUALITY VARIABLES IN FORESTED EAST TEXAS1

ABSTRACT: Spatial variation of five water quality variables were analyzed using composite water samples collected periodically from eight small watersheds (11.4–71.6 km²) in forested East Texas during 1977 through 1980. Based on 31 observations during the four-year period the average yield of nitrate-nitrite nitrogen (NNN), total kjeldahl nitrogen (TKN), total phosphorus (PO4), chloride (CHL), and total suspended sediment (TSS) were 1.43, 21.96, 3.09, 50.11, and 90.39 ka/ha/yr, respectively. Compared to the water quality standards of the U.S. Environmental Protection Agency (1976) and the Texas Department of Water Resources (1976) for CHL, TSS, and NNN, none of the observations exceeded the limits for public water supplies. The study showed that forested watersheds normally yielded stream flow with better quality than that from agricultural watersheds. Watersheds of greater percent of pasture area, mean slope, stream segment frequency, and drainage density produced greater concentrations for these five chemical parameters in water samples. Meaningful equations were developed for estimating mean average yields for each chemical parameter for each watershed with R² ranging from 0.77 to 0.96 and standard error of estimates from 17 to 33 percent of the observed means.     

QUALITY OF WATER AND BOTTOM SEDIMENTS IN THE TRINITY RIVER1

ABSTRACT: Data were developed to determine the quality of water and bottom sediments in the Trinity River, and the mobility of various contaminants when bottom sediments were mixed with the river water under simulated dredging conditions. Thirteen sampling sites were selected. A number of chemical tests including heavy metals and pesticides were conducted on river water, elutriates, and bottom sediments. Statis bioassays using Daphnia magna were conducted on river water and elutriates. Results indicated that the river in the upper reach is grossly polluted due to discharge of waste water effluents from several large treatment plants. High concentrations of nitrogen, phosphorus, organic carbon, COD, heavy metals, and pesticides were found in water and bottom sediments. The concentrations of most of these pollutants exceeded the EPA recommended limits. Elutriation gave no consistent results, perhaps because of release or uptake of contaminants from the sediments. High mortality of D. magna were also recorded in the upper reach of the river. The quality of water and bottom sediments gradually improved in lower reaches.     

WETLAND BOUNDARIES IN THE NEW JERSEY PINELANDS: ECOLOGICAL RELATIONSHIPS AND DELINEATION1

Wetland protection regulations and guidelines often require the delineation of precise wetland boundaries on a case-by-case basis. In this study, conducted in the New Jersey Pinelands, an ecological characterization of vegetation composition, soil and hydrologic relationships along upland to wetland Pinus rigida - dominated transittions provided the basis for a multiparameter approach to wetland boundary delineation. The transitional data set was analyzed by direct gradient analysis, cluster analysis and ordination. It is concluded that vegetation composition can be a principal factor in delineating wetland boundaries along natural upland to wetland transitions. However, where distinct vegetation changes are not observed, a feature of our study sites, a multiparameter approach should be used.     

ACCUMULATION OF SELECTED TRACE METALS IN SOILS OF URBAN RUNOFF DETENTION BASINS1

ABSTRACT Field investigations were conducted at three sites in the Washington, D.C., area to detect accumulation patterns of the trace metals, cadmium, copper, lead, and zinc in the soils of urban stormwater detention basins. The research results seemed to indicate that the use of detention basins to control urban stormwater runoff had few harmful effects to fine textured soils with respect to the study trace metals. Although the trace metals, especially lead and zinc, were found to accumulate in the surface soils of the basins, little significant downward movement of metals in the soil profiles had occurred. Accumulations of metals in the surface soils appeared to be a function of microtopography and the resultant residence time of standing water. The fractions of trace metals that were present in a leachable form in surface soils and stormwater solids were small, with median values ranging from 7.7 percent of the total concentration for Cd to 0.01 percent for Pb.     

DISTRIBUTION OF NITRATE AND ORTHOPHOSPHATE IN SELECTED STREAMS IN CENTRAL NEBRASKA1

ABSTRACT: The Central Nebraska Basins is one of 60 study units in the National Water-Quality Assessment Program of the U.S. Geological Survey. The study unit includes the Platte River and two major tributaries, the Loup and Elkhorn Rivers. Agriculture is the predominant land use in the study unit, with only eight urbanized communities exceeding a population of 10,000. Water samples were collected from selected streams in the study unit during 1993–1995. The data were used to assess the distribution of nitrogen compounds and phosphorus in the streams and to relate the concentrations of these constituents to environmental settings. This article focuses on dissolved nitrate and orthophosphate. Dissolved nitrate concentrations were highest (90th percentiles were less than 7.0 milligrams per liter as nitrogen) in areas with extensive cropland and pasture, where chemical fertilizers are intensively applied. Synoptic measurements conducted in March and August 1994 indicate that relatively little residual fertilizer, as nitrate, applied during a single crop-growing season enters streams. Dissolved nitrate concentrations showed a seasonal pattern, being highest during winter months and lowest during the late spring and summer. Dissolved orthophosphate concentrations tended to be low across the study unit, 90 percent of all analyses did not exceed 1.7 milligrams per liter as phosphorus.     

LAND-USE AND WATER-QUALITY RELATIONSHIPS IN THE GEORGES CREEK BASIN,MARYLAND1

ABSTRACT: Models developed in Ohio to predict water quality conditions resulting from various land uses associated with the surface mining of coal are employed to ascertain their transferability to Maryland conditions. Discriminant analysis is employed to assess patterns of association between water quality and land use variables, and predictive models were then constructed with which to quantify changes in stream quality to be expected from the changing mosaic of upstream land uses in the Georges Greek basin of western Maryland. Data collected under procedures specified by the regulatory authority in Maryland may have accounted for the lack of statistically significant results from these models. Suggested changes in the collection of data are made for the coal region of Maryland.     

OCCURRENCE OF PESTICIDES IN GROUND WATER OF THE OZARK PLATEAUS PROVINCE1

ABSTRACT: Pesticides were detected in ground-water samples collected from 20 springs and nine wells in the Ozark Plateaus Province of Arkansas, Kansas, Missouri, and Oklahoma. From April through September 1993, water samples were collected from 50 shallow domestic wells and 50 springs in the Springfield Plateau and Ozark aquifers and analyzed for 47 pesticides and metabolites. Pesticides were detected in 17 water samples from the Springfield Plateau aquifer and 12 water samples from the Ozark aquifer. Fourteen pesticides were detected, with a maximum of four pesticides detected in any one sample. The most commonly detected pesticides were atrazine (14 detections), prometon (11 detections), and tebuthiuron (seven detections). P, P' DDE, a metabolite of DDT, was detected in water samples from three wells and one spring. The remaining pesticides were detected in three or less samples. The occurrence and distribution of pesticides probably are related to the local land use near a sampling site. Pesticide detections were significantly related to aquifer, site type, and discharge of springs.     

APPLICATION OF ROSGEN ANALYSIS TO THE NEW JERSEY PINE BARRENS1

ABSTRACT: Rosgen analysis, developed for assessing channel stability in streams from the western United States, is applied to the Oswego River watershed in the New Jersey Pine Barrens. The Rosgen method requires calibration to local conditions due to the impact of peat substrates on channel morphology. In particular, the presence of peat induces low width to depth ratios and greater channel confinement, reversing typical downstream morphologic trends observed in other rivers. Therefore peat is added to those substrates already evaluated by Rosgen. A consistent sequence of Rosgen stream types develops along the Oswego River and its tributaries created by spatially overlapping processes of water table emergence, peat development, and channel formation. This sequence delineates a “natural” transition of stream channel morphology downslope through the watershed. First, as the water table reaches the surface of dry sloughs, Sphagnum growth is stimulated and peat substrates result. These substrates have lower permeability than the underlying gravelly sands. Next, surface runoff, through braided pathways over the peat, eventually erodes mainly anastomosing channels into the peat. Finally, single‐thread channels develop in underlying gravelly sands further downslope. This downslope sequence, expressed as Rosgen stream types, begins generally with DA7 streams arising from dry sloughs. These pass to E7, C7 or DA5 stream types that in turn pass to B5c, C5 and C4 stream types. Departures from the “natural” stream type sequence occur along the course of the Oswego and its tributaries due to human activities such as the construction of dams, bridges and drainage ditches, stream bank erosion at streamside camping and picnic areas and the clear‐cutting of adjacent stands of Atlantic white cedar.