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Robert Stottlemyer 《Journal of the American Water Resources Association》1997,33(4):767-779
ABSTRACT: Weekly precipitation and stream water samples were collected from small watersheds in Denali National Park, Alaska, the Fraser Experimental Forest, Colorado, Isle Royale National Park, Michigan, and the Calumet watershed on the south shore of Lake Superior, Michigan. The objective was to determine if stream water chemistry at the mouth and upstream stations reflected precipitation chemistry across a range of atmospheric inputs of H+, NH4+, NO3??, and SO42?. Volume-weighted precipitation H+, NH4+, NO3??, and SO42? concentrations varied 4 to 8 fold with concentrations highest at Calumet and lowest in Denali. Stream water chemistry varied among sites, but did not reflect precipitation chemistry. The Denali watershed, Rock Creek, had the lowest precipitation NO3?? and SO42? concentrations, but the highest stream water NO3?and SO42? concentrations. Among sites, the ratio of mean monthly upstream NO3?? concentration to precipitation NO3?- concentration declined (p < 0.001, R2= 0.47) as precipitation NO3?? concentration increased. The ratio of mean monthly upstream to precipitation SO42? concentration showed no significant relationship to change in precipitation SO42? concentration. Watersheds showed strong retention of inorganic N (> 90 percent inputs) across inputs ranging from 0.12 to > 6 kg N ha?1 y?1. Factors possibly accounting for the weak or non-existent signal between stream water and precipitation ion concentrations include rapid modification of meltwater and precipitation chemistry by soil processes, and the presence of unfrozen soils which permits winter mineralization and nitrification to occur. 相似文献
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Rameshwar S. Kanwar 《Journal of the American Water Resources Association》2006,42(6):1493-1501
Abstract: Diverse cropping systems can have significant impacts on nutrient losses through tile drain systems and to surface water bodies (rivers and streams). Increased transport of nitrogen to water bodies can reduce dissolved oxygen and enrich the supply of nutrients, resulting in hypoxic zones. With the objective of reducing the transport of nutrients from agricultural watersheds, long term studies (1990 to 1998) were conducted in Iowa to investigate the impact of tillage, crop rotation, and N-management practices on NO3 -N leaching losses to tile drain water. Results of these studies indicated that continuous corn production systems required higher input of nitrogen fertilizers and resulted in significantly higher NO3 -N leaching losses compared to rotated corn in plots either fertilized with manure or urea ammonium nitrate. Also, rotated corn gave higher corn yields, 8 megagrams per hectare (Mg/ha) versus 6 Mg/ha, than continuous corn. The higher N application rates resulted in increased NO3 -N concentrations in tile water. A strip cropping system with alfalfa lowered NO3 -N concentrations in tile water to less than 10 mg/l. These studies indicated that better land use practices can reduce NO3 -N leaching losses to surface and ground water systems and will help in mitigating environmental concerns of the production agriculture. 相似文献
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Mustafa Arslan Cihan Alkan Mehmet Cici Mehmet Kaya 《Resources, Conservation and Recycling》1994,10(4)
FeSO4·xH2O is generated in large amounts in galvanizing workshops. It can be reutilized by conversion to Fe2O3. In this study, the recovery of Fe2O3 from FeSO4·xH2O formed in the galvanizing process has been examined. The experimental work was carried out at various temperatures and times in the oxidizing medium. The reaction temperatures and times were selected as 450, 500, 550, 600, 650, 700, 800 and 900°C, and 15, 30, 45, 60, 90 and 120 minutes, respectively. In order to determine the amount of Fe2O3, a titrimetric method was applied. The reaction products were characterized by means of IR and XRD techniques.The extent of conversion is low at temperatures below 650°C. Almost all of the iron (II) sulfate in the original sample was converted to iron(III) oxide at 650°C (120 min), 700°C (90 min), 800°C (60 min) and 900°C (45 min). 相似文献
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Oak Ridge tank sludges that have been collected over several decades are being combined for treatment and disposal. Stabilization of the highly radioactive, mixed-waste sludges in the different tank sets has been evaluated prior to the proposed combination and treatment. This paper documents the testing of a Melton Valley Storage Tank (MVST)/Bethel Valley Evaporator Storage Tank set. Subsequent papers will discuss continued work on other tank sets and efforts to maximize the sludge loading. Grout formulations were tested in the laboratory both with a surrogate and with a sample of an actual mixed waste tank sludge from MVST W-25. Wet-sludge loadings of 50-60wt% resulted in strong wasteforms with no free water and gave a volume increase of about 40-50vol%. Resource Conservation and Recovery Act (RCRA) metals included in the surrogate testing were cadmium, chromium, lead, selenium, thallium, and mercury. The actual sludge sample was only characteristically hazardous for mercury by the Toxic Characteristic Leaching Procedure but exceeded the Universal Treatment Standard (UTS) limit for chromium. The grout formulations stabilized these two RCRA metals within UTS limits. In addition, a grout leachability index of about 9.0-10.0 was measured for both (85)Sr and (137)Cs, meeting the recommended requirement of >6.0. 相似文献
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本文着重解读了欧盟新EMC指令2004/108/EC的主要内容,包括本指令的基本规定、协调标准、符合性评定程序、标识和信息、公告机构等,并分析新指令时检测机构、企业的影响,为检测机构和客户提供一些必须了解的讯息. 相似文献
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Jenq-Tzong Shiau Hsin-Yi Wang Chang-Tai Tsai 《Journal of the American Water Resources Association》2006,42(6):1549-1564
Abstract: Bivariate flood frequency analysis offers improved understanding of the complex flood process and useful information in preparing flood mitigation measures. However, difficulties arise from limited bivariate distribution functions available to jointly model the correlated flood peak and volume that have different univariate marginal distributions. Copulas are functions that link univariate distribution functions to form bivariate distribution functions, which can overcome such difficulties. The objective of this study was to analyze bivariate frequency of flood peak and volume using copulas. Separate univariate distributions of flood peak and volume are first fitted from observed data. Copulas are then employed to model the dependence between flood peak and volume and join the predetermined univariate marginal distributions to construct the bivariate distribution. The bivariate probabilities and associated return periods are calculated in terms of univariate marginal distributions and copulas. The advantage of using copulas is that they can separate the effect of dependence from the effects of the marginal distributions. In addition, explicit relationships between joint and univariate return periods are made possible when copulas are employed to construct bivariate distribution of floods. The annual floods of Tongtou flow gauge station in the Jhuoshuei River, Taiwan, are used to illustrate bivariate flood frequency analysis. 相似文献
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